• Title/Summary/Keyword: 단기시험

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Degradation evaluation of paint films on surface treated steel by electrochemical impedance spectroscopy (전기화학적 임피던스 분광법에 의한 표면처리한 강재 도장의 부식-도막 열화도 평가)

  • Park, Jun-Mu;Park, Jae-Hyeok;Kim, Sun-Ho;U, Sang-Gyun;Gwon, Yong-Min;Mun, Gyeong-Man;Lee, Myeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.95-95
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    • 2018
  • 강재의 방식법 중 도장은 부식을 억제하는데 효과적이고 편리한 방법으로 선박 및 해양 강 구조물의 방식법으로 사용되고 있다. 한편, 강 구조물의 효율적인 유지관리를 위해서는 방식 도장의 도막 열화도를 평가하고 잔존 수명을 예측하여 최적 시기에 보수도장 혹은 재도장하는 것이 필요하다. 일반적으로 선박 및 해양구조물에 적용되는 도막의 방식 성능 평가 방법으로 해수 침지 시험, 염수 분무 시험, 옥외 폭로 시험 등이 있다. 그러나 이러한 시험들은 그 시험 방법에 따라서 정량적인 평가에 한계가 있음은 물론 장기간 소요되는 등 곤란한 문제점이 있다. 그러므로 선박 및 해양구조물을 비롯하여 교량, 각종 강 구조물의 도장 방식에 사용되는 방식용 도료의 성능을 단기간에 적절하게 평가할 수 있는 가속시험법이 제시되며 연구-사용되고 있다. 그 중 도막 방식 성능을 보다 효율적, 비파괴적, 정량적으로 평가할 수 있는 임피던스 분광법(EIS)과 같은 전기화학적 방법은 상대적으로 시험 기간을 크게 단축시킬 수 있고, 대상 방식 도장의 미세한 성능 차이도 분별 가능하다는 장점이 있다[1]. 따라서 본 연구에서는 선박 및 해양구조물 등 가혹한 부식환경에서 강력한 내구성을 가질 수 있도록 다양한 종류의 표면처리 도장 시편을 제작하여 자외선 조사-염수분무-침지환경 등의 열악한 환경조건 하에서 부식-열화 촉진 시험을 실시하였다. 그리고 그 촉진 열화 과정에서 도막의 외관 상태를 관찰 분석함은 물론 전기화학적 임피던스 분광법을 병행 측정하며 그 표면막의 부식 및 도막 열화도를 비교-종합 평가하였다.본 연구에 사용된 시편은 Al 및 Zn 도금 강판에 에폭시, 에폭시-실리콘 우레탄, 에폭시-우레탄 도장 시편으로 Scribe, No Scribe 및 비교재 Al 및 Zn 도금 시편으로 분류하여 각각 실험을 진행하였다. 즉, 도막 열화 시험은 복합 노화 시험법으로 UV 조사 36 시간(ASTM G53), 염수분무 32 시간(ISO 7253), 수분 응축 10 시간을 1 Cycle로 100 Cycle(7800 시간) 동안 실험을 진행하였다. 이때 도막 열화도 평가는 전기화학적 임피던스 분광법을 이용하여 각 실험 조건별로 주파수에 따른 임피던스(Z) 값을 평가하였다. 즉, 상온 $25^{\circ}C$의 3.5% NaCl 100 ml 수용액에 작동 전극(Working Electrode)과 구리 도선을 통해 연결하였고, 노출 면적은 $1cm^2$로 일정하게 유지 하였으며, 상대 전극(Counter Electrode)은 탄소봉, 기준 전극(Reference Electrode)으로 포화카로멜전극(Saturated Calomel Electrode)을 사용하여 측정하였다. No Scribe 시편의 경우에는 Al 기판 에폭시-실리콘 우레탄 도장 시편이 우수한 도막 저항성을 나타내었으며, 에폭시-우레탄 도장시편은 23사이클 이후의 저항값이 가장 낮게 나타났다. Zn 기판의 경우는 에폭시, 에폭시-실리콘 우레탄, 에폭시-우레탄 도장 시편 모두 저항 값이 유사하였으며, Al 및 Zn 도금 시편은 도장 처리된 시편에 비해 훨씬 낮은 저항 값을 보였다. 또한 Scribe 시편의 경우에는 Al 기판 에폭시-실리콘 우레탄 도장 시편에서 높은 초기 저항 값을 보였으며, 23 사이클 후의 저항 값은 세 종류의 도막에서 약 1~0.1 Gohm 으로 나타났다. 그리고 Zn 기판 에폭시-실리콘 우레탄 도장 시편에서 가장 낮은 도막 저항 값이 나타났다. 이상의 실험을 통해서 본 연구 내용은 실내촉진시험으로 선박 및 해양 강 구조물에 사용되는 다양한 종류의 도막의 열화도를 평가하는 기초 설계 지침으로 응용될 수 있을 것으로 사료된다. 한편, 도막은 노출 환경에 따라 방식 성능이 다르므로 실제 도막의 사용환경을 고려하여 도장 사양별 적용 부위에 따른 적정 가속 실험 방법을 선정할 필요가 있다고 사료된다.

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Hydration Characteristics according to First Curing Condition in Solid Hydrated by Hydro-Thermal Synthesis Reaction (수열합성경화체의 1차 양생조건에 따른 수화특성)

  • Kim, Jin-Man;Jung, Eun-Hye;Park, Sun-Gyu
    • Journal of the Korea Concrete Institute
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    • v.20 no.5
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    • pp.543-548
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    • 2008
  • Solid hydrated by hydro-thermal synthesis reaction is cured two times, the first curing is the steam curing at atmospheric pressure and the second one is a high-pressure steam curing, that is autoclaving. Steam curing is to acquire the proper strength for the resistance of treatment in the first curing process, it was not evaluated properly so far. Because of ignorance about curing, some engineers even think that the dry curing is better than the steam curing. The relation between compressive strength of solid hydrated by hydrothermal synthesis reaction and curing condition are presented in this paper. In order to investigate the effect of curing on the strength properties of specimen, the hydration behavior of solid hydrated by hydro-thermal synthesis reaction has been studied over curing condition using XRD, DT-TGA and porosimeter, SEM analysis technique. The results show that the specimens which are cured with blended method of dry and steam curing appear to have better strength properties than that of dry curing and steam curing. Also, there are significant difference of hydration behavior among curing condition in the solid hydrated by hydro-thermal synthesis reaction.

Field Pullout Tests and Stability Evaluation of the Pretension Soil Nailing System (프리텐션 쏘일네일링 시스템의 현장인발시험 및 안정성 평가)

  • Kim, Hong-Taek;Choi, Young-Geun;Park, Si-Sam;Kim, Berm-Suk
    • Journal of the Korean GEO-environmental Society
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    • v.4 no.3
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    • pp.27-40
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    • 2003
  • In the present study, a newly modified soil nailing technology named as the PSN(Pretension Soil Nailing) system is proposed. Effects of various factors related to the design of the pretension soil nailing system, such as the length of a sheathing pipe and the fixed cone, are examined throughout a series of the displacement-controlled field pull-out tests. 9 displacement-controlled field pull-out tests are performed in the present study and the pretension forces are also evaluated based on the measurements. In addition, both short-term and long-term characteristics of pull-out deformations of the newly proposed PSN system are analyzed and compared with those of the general soil nailing system by carrying out the stress-controlled field pull-out tests. A numerical approach is further made to determine a postulated failure surface as well as a minimum safety factors of the proposed PSN system using the shear strength reduction technique and the $FLAC^{2D}$ program. Global minimum safety factors and local safety factors at various excavation stages computed in case of the PSN system are analyzed throughout comparisons with the results expected in case of the general soil nailing system. An efficiency of the PSN system is also dealt with by analyzing the wall-facing deformations and the adjacent ground surface settlements.

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Evaluation of Dynamic Modulus based on Aged Asphalt Binder (아스팔트 바인더의 노화특성을 고려한 동탄성계수 평가)

  • Lee, Kwan-Ho;Cho, Kyung-Rae;Lee, Byung-Sik;Song, Yong-Seon
    • Journal of the Korean Society of Hazard Mitigation
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    • v.8 no.3
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    • pp.51-58
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    • 2008
  • Development of a new design guide which is based on empirical-mechanistic concept for pavement design is in action. It is called AASHTO 2002 Design Guide in USA and the KPRP(Korean Pavement Research Project) in Korea. The material characteristic of hot mix asphalt is a key role in the design guide. Therefore it is urgent to get a proper materials database, especially the dynamic modulus of hot mix asphalt. In this research, dynamic modulus test, which is based on aged asphalt binder, has been carried out and proposed the predicted equation of dynamic modulus. Nine different hot mix asphalt with three different asphalt binder have been used for the dynamic modulus test. Short-term aging, which is covers the time for the production of asphalt plant, transportation, lay-down, and compaction, can be simulated at $135^{\circ}C$ with 2 hour curing. Long-term aging has been carried out for a performance period of asphalt pavement. The dynamic modulus of asphalt pavement increases with aging time. As the nominal aggregate size increases, the change of dynamic modulus is not big.

Studies on The Reduced Pressure Storage of Fruits (II) -Preservation of Jonathan under Various Pressures of Storage Chamber- (과실의 감압저장법에 관한 연구 ( II ) -감압도에 따른 저장성 비교(홍옥)-)

  • Kim, K.S.;Lee, K.L.;Hong, S.Y.;Sohn, T.H.
    • Applied Biological Chemistry
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    • v.11
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    • pp.77-82
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    • 1969
  • In order to determine an optimum pressure condition of the storage chamber of apples, several reduced pressure were examined for the Jonathan. The results obtained checking various storage conditions are as follows. 1. The optimum pressure of chamber atmosphere for apple storage was 10 cmHg. 2. Under the pressure of 10 cmHg, the normal (room) temperature storage was better than the cold storage. 3. Under reduced pressure, poly-ethylene film wrapping of apple showed a good result in a short-term (less than one and half month) experiment. 4. No noticeable effect was observed by O.E.D (Oxy-ethylene doxanole) or sodium dehydro acetate treatment. 5. Change of the components (total sugar, reduced sugar, acid and vitamin C) of apples according to the storage methods showed similar results to our previous report, Studies on The Reduced Pressure Storage of Fruits (I)

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A Study on the Impermeability of Ground using N.D.S and S.M.I methods (N.D.S공법과 S.M.I공법을 이용한 지반차수 방법에 관한 연구)

  • Kim, Ji-Hwan;Kim, Joon-Jeong;Cho, Kook-Hwan
    • Journal of the Korean Society of Hazard Mitigation
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    • v.11 no.2
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    • pp.87-92
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    • 2011
  • This paper describes a study on the permeability reduction of the riverbed ground during urban railway tunnel construction. The research is mainly concentrated on the study of the grouting or injection methods among permeability reduction methods which can be adapted in the riverbed ground. The design technology of grouting methods considering the long term hydro-geological behaviour in the riverbed, was suggested. Two injection methods namely, Natural Durable Stabilizer (N.D.S) and Space-Multi Injection Grouting (S.M.I) methods, were introduced as new approach methods which could be adapted to modify the riverbed ground. In order to evaluate the performance of the improved ground by the N.D.S and S.M.I method, a series of pilot tests including the field and laboratory permeability tests, were carried out in the river crossing tunnel construction sites. The results obtained from pilot test program, were also reviewed. The results, the grouting efficiency of the S.M.I method using the non-alkalimeter silica sol is better than that of N.D.S method using cement. In addition, it is anticipated that the current research results are contributed to develop the grouting design technology.

Short-term Effects of Cultivars and Compost on Soil Microbial Activities and Diversities in Red Pepper Field (토양 미생물 활성과 다양성에 미치는 고추 품종과 퇴비의 단기적 효과)

  • Park, Kee-Choon;Kwon, Tae-Ryong;Jang, Kil-Soo;Kim, Yeong-Suk
    • Korean Journal of Environmental Agriculture
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    • v.27 no.2
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    • pp.139-144
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    • 2008
  • A field experiment was conducted to investigate the influence of cultivars and compost on soil microbial activities and diversities in a red pepper-grown field. Compost was applied with 0, 30, and 60M/T $ha^{-1}$ in April and then red pepper seedlings of "Yong-go 4" and "Koeun" were transplanted in May 2007. Soil samples were collected in early August 2007. Measurement of microbial activities was based on a dehydrogenase assay and a fluorescein diacetate hydrolysis. Soil microbial community was characterized with Biolog $EcoPlate^{TM}$ and phospholipid fatty acid(PLFA). Red pepper cultivars did not differentiate the selected soil chemical and microbial properties. Soil pH and soil microbial community changed by amending the soil with 30 and 60 M/T $ha^{-1}$ of compost, and the soil organic matter and potassium content, and soil microbial activities increased in soils amended with 60 M/T $ha^{-1}$ of compost. Red pepper cultivar induced a little different soil chemical properties and microbial activity in soils amended with 60 M/T $ha^{-1}$ of compost even though significant differences were not found in those properties. In conclusion the effects of compost on soil chemical and microbial properties were much higher than red pepper cultivars in short-term period but the effects of red pepper cultivars should be investigated in long-term field test.

Varietal Differences of Leaf Senescence and Photosynthate Translocation Rate During Grain Filling Period in Barley (대맥의 등숙기간중 엽신의 노화와 동화산물전류의 품종간 차이)

  • 남윤일;구본철;연규복
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.36 no.2
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    • pp.166-173
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    • 1991
  • In order to determine the relationships between the rates of leaf senescence and photosynthate translocation during the grain filling periods in barley, field experiments were conducted through 1989/1990 crop year. Thirty barley varieties and lines having different leaf senescence were used for the experiments. Varieties differed significantly in the rate of leaf senescence and rate of grain filling. The rate of leaf senescence at early (10-20days after heading) and late period (20-30days after heading) during of grain filling were positively correlated with the rate of grain filling in same period, respectively. But the rate of leaf senescence at 10-20 days after heading negatively correlated with the rate of grain filling during the whole grain filling period (10-35 days after heading). Whereas, the rate of leaf senescence at late period was positively associated with the rate of grain filling during the whole grain filling period. Rates of grain filling at the late and whole periods have positively influence on grain weight(r=0.62**~-0.93**), but rate of leaf senescence at early period and duration of grain filling negatively correlated with the grain weight (r=-0.33~ -0.15). The patterns of leaf senescence index for the varieties tested were grouped by four. Among these patterns, the most ideal pattern was IV type.

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Effect of fuel injection timing and pressure on the combustion and spray behavior characteristics of diesel fuel for naval vessel (연료분사시기와 압력이 함정용 디젤연료의 분무 및 연소특성에 미치는 영향)

  • Lee, Hyung-min
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.9
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    • pp.911-917
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    • 2015
  • The objective of this work focuses on the analysis of injection rate and macroscopic spray behavior characteristics with injection pressures as well as combustion and exhaust emission characteristics with injection timing and injection pressure by using a common rail single-cylinder diesel engine. The injection rate was measured by applying the Bosch method, and macroscopic spray behavior characteristics were analyzed with a constant-volume vessel and a high-speed camera. In addition, combustion and emission characteristics were analyzed in a common-rail single-cylinder diesel engine with precise control of fuel injection timing and pressure. For injection pressures of 30MPa and 50MPa, the injection rate was higher at 50 MPa, and the spray development (penetration) was also higher in the same elapsed time. The peak in-cylinder pressure and rate of heat release showed a tendency to decline as injection timing was delayed, and the peak in-cylinder pressure and rate of heat release were slightly higher for higher injection pressures. Higher injection pressures also reduced the mean effective pressure, while the indicated mean effective pressure and torque increased as injection timing was delayed to TDC. Nitrogen oxides had a peak level at injection timings of $BTDC20^{\circ}$(30MPa) and $BTDC15^{\circ}$(50MPa); carbon monoxide emissions were reduced by delaying injection timing from $BTDC30^{\circ}$.

Suggestion for the Enhancement of Military Supplies via Segregation of Defense Quality Management System (국방 분야 품질경영시스템 세분화를 통한 군수품 품질향상 방안)

  • Ju, Jin-Chun;Kim, Sung-kon;Lee, Jong-chan;Ahn, Nam-Su
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.8
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    • pp.251-261
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    • 2016
  • Recently, many weapon related quality issues have arisen in the armed forces, such as failures of K-21 Infantry Fighting Vehicles, K-9 self-propelled mounts, and grenade explosion during boot training. Since all of the issues are repetitive phenomena, we examined the defense quality management system and identified the possible solutions for it. Since the government quality assurance agency performs their quality assurance activity using the system evaluation technique, we first reviewed the regulations related to the defense quality management system. Then, we benchmarked some other advanced quality management systems. We suggested two types of defense quality management system, one for small (in terms of the amount of the contract) competitive contracts and the other for large private contracts. For the first one, we adopted the framework of MIL-I-45208 (Inspection System Requirement), while for the second one, we adopted the framework of NATO AQAP 2310 (Quality Management System Requirements for Aviation, Space and Defense Suppliers).