• Title/Summary/Keyword: 다황화 암모늄

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Electrochemical Properties of Lithium Batteries with Nickel Sulfide by Ammonium Polysulfide (다황화암모늄에 의해 제조된 황화니켈을 이용한 리튬전지의 전기 화학적 특성 평가)

  • RYU, HO SUK
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.612-617
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    • 2021
  • In the case of a metal sulfide electrode, it is used as an anode or cathode active material in a lithium battery. The reason is that the voltage exists between 0.8 and 2.0 V via lithium electrode and the discharge and charge capacity is high. In order to manufacture nickel sulfide for electrode, which are widely used, nano-nickel powder was sulfided using ammonium polysulfide, and single-phase NiS electrodes were manufactured through heat treatment. The prepared NiS electrode had a high initial capacity of 500 mAh/g or more, and was stabilized after 20 cycles to maintain a capacity of 400 mAh/g or more until 100 cycles.

Light-dependent Hydrogen Production in Chlorobium limicola f. thiosulfatophilum NCIB 8327: A Possibility of Regulation via Glutamine Synthetase (Chlorobium limicola f. thiosulfatophilum NCIB 8327에서의 광수소발생 조절 기작에 대하여)

  • 나종욱;강사욱
    • Korean Journal of Microbiology
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    • v.30 no.6
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    • pp.558-563
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    • 1992
  • Chlorobium liimicola f. thiosulfatophilum NCIB 8327 was grown on modified Pfennig's medium using ammonium chloride. glutamine. glutamate, or dinitrogen gas as nitrogen sources. Except for the case of dinitrogen gas. the extent of gro\\1h was almost the s~me. The specific activity of glutamine synthetase in crude extracts is the highest in the cells which were grown on the medium containing glutamate. hut that of glutamate synthase is uniform for all four nitrogen sources. When the concentration of ammonium ions increases in the reaction mixture. the specific activity of glutamine synthetase in crude extract from the cells grown on glutamate decreases. hut that of glutamate dehydrogenase increases. whereas that of glutamate synthase remains unchanged. When the concentration of methionine sulfoximine increases, the activity of glutamine synthetases decreases rapidly. On the other hand. when the concentration of ammonium ions increases in the reaction mixture gradually. the activity of glutamine synthetase from the cells grown on higher concentration of ammonium ions less decreases. In the presence of light. the activity of glutamine synthetase increases. hut in the dark it decreases gradually. The production of hydrogen in intact cells depends on light. It is inhihited by adding ammonium ions. hut restores immediately hy adding methionine sulfoximine. The produclion of hydrogen in this strain can he mediated by nitrogenase only. and regulated hy glutamine synthetase.

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