• Title/Summary/Keyword: 다공층

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Production of Erythromycin Using a Carrier-Spported Mycelial Growth in a Fluidized-Bed Bioreactor (균사 증식 담체를 이용한 유동층 생물반응기에서 Erythromycin의 생산)

  • 김성환;배신규김정희
    • KSBB Journal
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    • v.4 no.3
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    • pp.241-245
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    • 1989
  • A carriersupported mycelial growth of Sreptomyces erythreus was applied to erythromycin fermentation sistem using celite as a support material. Hyphal growth through the pore matrices of the materials showed anchorages and provided a stable biofilm growth. When the phospate concentration was limited to 0.8g corn steep liquor/L(corresponding to 40mg KH2PO4/L), the specific production rate of erythromycin was increased from 557$\mu$g/g-cell.hr under unlimited condition to 2, 898 $\mu$g/g-cell.hr. A fluidized-bed bioreactor was operated for erythromycin production by a repeated fed-batch mode. The control of free mycelial concentration and the extension of production phase were considered important to maintain the reactor productivity at a desired level. The erythromycin production under phosphate-limited condition could be maintained for at least 600hrs.

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저온에서 Hydropolymer를 이용한 ZnO 나노입자 염료감응형 태양전지

  • Gwon, Byeong-Uk;Son, Dong-Ik;Park, Dong-Hui;Hong, Tae-U;Choe, Heon-Jin;Choe, Won-Guk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.439-439
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    • 2011
  • 기존의 고온에서 제작되는 TiO2 나노 입자를 이용한 염료감응형 태양전지를 저온에서 제작하기 위해 전자 이동층으로 ZnO 나노 입자를 사용하여, 저온($200^{\circ}C$)에서 염료감응태양전지(DSSC)를 제작하였다[1,2]. 상대전극(counter electrode)으로는 RF magnetron sputtering을 사용하여 ITO/glass위에 Pt를 증착하여 태양전지의 특성을 측정하였다. $180^{\circ}C$ 이상에서 hydropolymer가 증발되는 것을 이용하여, ZnO 나노입자와 hydropolymer 혼합한 paste 제작하여 소결 후 ZnO 나노입자 사이에 다공성을 생성시켜 Dye가 잘 침투하여 ZnO 나노입자 표면에 잘 흡착 되도록 하였다[3]. 20 nm 및 60 nm 크기의 ZnO 나노 입자를 사용하여 실험 해본 결과, 20 nm에 비하여 60 nm ZnO 나노입자의 경우 IPCE 값이 약 7% 정도로 높은 전환효율 값을 보였다. 60 nm ZnO 나노입자를 전자 수송층으로 사용한 DSSC 소자에서 단위면적당 흐르는 전류(Jsc), 전압 (Voc), fill factor (ff), 그리고 효율(${\eta}$)의 최대값은 4.93 mA/$cm^2$, 0.56V, 0.40, and 1.12%, 로 보였다.

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A Performance characteristics of Pt/C Electrode prepared by Hot Pressing Method (Hot Pressing법에 의해 제조된 Pt/C 전극의 성능특성)

  • 김진수;서동우;설용건;이태희
    • Journal of Energy Engineering
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    • v.1 no.1
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    • pp.58-65
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    • 1992
  • Pt loaded porous carbon Pt/C electrode was prepared by hot pressing process to enhance the electrode performance in PAFC (phosphoric acid fuel cell). By changing the hot pressing conditions and PTFE contents, Pt/C electrodes were prepared and the electrochemical characteristics of oxygen reduction and unit-cell performance were evaluated. The optimum condition of hot press to make electrode is 360$^{\circ}C$ and 10 kg/$\textrm{cm}^2$. Maximum performance was obtained at 30 wt% PTFE content in the catalyst layer with 80% utilization of platinum clusters. Unit-cell performance of hot pressed Pt/C electrode was 200 mA/$\textrm{cm}^2$ at 700 ㎷ and stable performance was maintained more than 200 hr.

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Revealing the Paleo-ocean Environment of OSM-XX in the Western Pacific Magellan Seamount with Mineralogical and Geochemical Properties of Ferromanganese Crust (서태평양 마젤란해산군 OSM-XX 해저산 망간각의 광물학적, 지화학적 특성과 고해양 고환경 복원 연구)

  • Jinsub Park;Kiho Yang
    • Economic and Environmental Geology
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    • v.56 no.1
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    • pp.55-63
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    • 2023
  • Variations in geochemical and mineralogical properties of the ferromanganese(Fe-Mn) crust reflect environmental changes. In the present study, geochemical and mineralogical analyses, including micro X-ray fluorescence and X-ray diffraction, were utilized to reconstruct the paleo-ocean environment of western Pacific Magellan seamount cluster. Samples of the Fe-Mn crust were collected using an epibenthic sledge from the open seamount XX (151° 51.12' 7.2" E and 16° 8.16' 9.6" N, 1557 meters below sea level) in the Western Pacific Magellan Seamount. According to the structure and phosphating status, the Fe-Mn crust of the OSM-XX can be divided into the following: phosphatizated (L4-L5), massive non-phosphatizated (L3), and porous non-phosphatizated (L1-L2) portions. All ferromanganese layers contain vernadite, and owing to the presence of carbonate fluorapatite (CFA), the phosphatizated portion (L4-L5) is rich in Ca and P. The massive non-phosphatizated section (L3) contains high Mn, Ni, and Co, whereas the porous non-phosphatizated portion (L1-L2), which comprises detrital quartz and feldspar, is rich in Fe. Variations in properties of the Fe-Mn crust from the OSM-XX reflect changes in the nearby marine environment. The formation of this crust started at approximately 51.87 Ma, and precipitation of the CFA during the global phosphatization event that occurred at approximately 36-32 Ma highlights an elevated sea level and low temperature during the associated period. The high Mn, Ni, and Co concentrations and elevated Mn/Fe ratios of samples from the massive phosphatizated portion indicate that the oxygen minimum zone (OMZ) was enhanced, and reducing conditions prevailed during the crust formation. The high Fe and low Mn/Fe ratios in the porous portion indicate a weak OMZ and dominantly oxidizing conditions. These data reflect environmental changes following the end of the Mi-1 glacial period in the Miocene-Oligocene boundary. Subsequently, Mn/Fe and Co/Mn ratios increased slightly in the outermost part of Fe-Mn crust because of the enhanced bottom current and OMZ associated with the continued cooling from approximately 9 Ma. However, the reduced carbonate dissolution rate in the Pacific Ocean from approximately 6 Ma decreased the growth rate of the Fe-Mn crust.

Printability of coating layer with nano silica sol for inkjet printing high-end photo paper (나노 실리카 졸을 이용한 잉크젯 프린팅용 고품질 인쇄용지 도공층의 인쇄적성)

  • Kim, Hye-Jin;Nahm, Sahn;Han, Kyu-Sung;Hwang, Kwang-Taek;Kim, Jin-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.352-358
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    • 2019
  • In recent years, printing paper with a function of information delivery and aesthetic value has attracted a great attention with increasing market demand for coated paper that is capable of high quality printing. The coated paper for inkjet printing with high-quality of photorealistic grades requires the coating layer with a good wettability and porous surface structure in order to improve the printability of ink. In this study, the coated paper was prepared using polyvinyl alcohol (PVA) and surface treated nano silica sol with silane coupling agent. It was confirmed that the coating layer with surface treated nano silica sol showed a uniform pore distribution and flat surface roughness. Glossiness of the prepared printing paper was similar to that of commercial high quality photo paper. Especially, the coated paper with surface treated nano silica sol showed improved printability with excellent roundness of the printed dot of ink. These results indicates that the coating layer with excellent wettability and uniform pore distribution can be formed by using the nano-silica particles with improved dispersibility through the surface treatment of the silane coupling agent.

Assesment of the Characteristics of Hydraulic Storage in Volcanic Region for Applying the Artificial Hydraulic Fracturing - Ulleungdo Site (인공수압파쇄 적용을 위한 울릉도 화산암류 저류특성 평가)

  • Kim Man-Il;Chang Kwang-Soo;Suk Hee-Jun;Kim Hyoung-Soo
    • The Journal of Engineering Geology
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    • v.16 no.2 s.48
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    • pp.125-134
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    • 2006
  • In order to establish the in-situ application of the artificial storage and recovery (ASR) technology which is used the property of the aquifer storage of groundwater. We carried out to the in-situ experiments such as borehole TV logging, pumping test and artificial hydraulic fracturing in volcanic island, Ulleungdo. In-situ experiments were conducted to divide the before- and after-hydraulic fracturing. Pumping test was achieved to confirm the two fracture zones, GL-13m and GL-21m, which are determined by the borehole TV logging. From the results of the before- and after-pumping tests, the hydraulic connectivity was confirmed to locate at GL-13m in the residual deposit zone of pumice media as alluvium. However, in the bedrock tone at GL-21m the hydraulic connectivity could be considered to faulty. Consequently, in this study area the artificial recharge has a little unsatisfied to geo-structural condition and desired to more detail investigation works.

Preparation and Water Quality Purification of Permeable Concrete Pavement Filled with Microbial-Soil Sheet (미생물토양시트를 충진한 도로포장용 다공성 콘크리트의 제조 및 수질정화특성)

  • Kang, Young-Heoun;Hwang, Pil-Gi;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.6
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    • pp.727-733
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    • 2009
  • This study was performed to investigate the physical characteristics like compressive strength, permeability, porosity and the water quality removal characteristics of permeable concrete pavement filled with microbial-soil sheet to remove SS, organic matter and nutrients in artificial rainfall. As a result, it can show the removal efficiency is SS 90~95%, COD 85~93%, BOD 80~83%, T-N 61~75%, T-P 71~78% on WAPS I(W1) and WAPS II(W2). Therefore, permeable concrete pavement filled with microbial-soil sheet shows higher removal efficiency(SS 10%, organic matter and nutrients 30%) than a conventional porous concrete(W3). By filling microbial-soil sheet to permeable concrete pavement, we confirm that the function and efficiency are improved significantly and that a naturally-friendly facility can be developed and applied to treat non-point sources.

Preparation of wire-mesh honeycomb coated with Al/Al$_2$O$_3$ composite for catalytic combustion of volatile organic compounds(VOCs) (다공성 Al/Al$_2$O$_3$ 복합층이 피복된 휘발성 유기화합물 촉매산화용 금속 monolith 반응기의 개발)

  • 양경식;최진성;정종식
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.377-378
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    • 2003
  • 휘발성유기화합물(volatile organic compounds, 이하 'VOCs')은 대기 중에서 태양광선에 의해 질소산화물과 광화학적 산화반응을 일으켜 그 결과 지표면의 오존농도를 증가시켜 스모그(Smog) 현상을 초래시키는 모든 유기화합물을 일컫는다. 이러한 VOCs를 제거하기 위하여 여러 방법이 제시되고 있는데, 촉매를 이용하여 VOCs를 산화시켜 제거하는 촉매 산화법은 촉매사용으로 인하여 소각법에 비하여 조업온도를 많이 떨어뜨릴 수 있으므로, 에너지 소비의 절감과 이에 따른 제2의 오염물질의 배출이 거의 없다는 점에서 유리한 면을 갖고 있어 VOCs 제거에 가장 적합한 방법이라고 할 수 있다. (중략)

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Performance Analysis of Fuel Cell by Controlling Active Layer Thickness of Catalyst (촉매 활성층 두께 제어를 통한 연료전지 성능 해석)

  • Kim, H.G.
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.3
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    • pp.133-140
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    • 2007
  • A 2-D model of fluid flow, mass transport and electrochemistry is analysed to examine the effect of current density at the current collector depending on active layer thickness of catlyst in polymer elecrolyte fuel cells. The finite element method is used to solve the continuity, potential and Maxwell-Stefan equations in the flow channel and gas diffusion electrode regions. For the material behavior of electrode reactions in the active catalyst layers, the agglomerate model is implemented to solve the diffusion-reaction problem. The calculated model results are described and compared with the different thickness of active catalyst layers. The significance of the results is discussed in the viewpoint of the current collecting capabilities as well as mass transportation phenomena, which is inferred that the mass transport of reactants dictates the efficiency of the electrode in the present analysis.

Numerical Study on the Production of Methane Hydrate by Depressurization Method (감압법을 이용한 메탄하이드레이트 생산에 대한 수치적 연구)

  • Kim, Jin-Hong;Chun, Won-Gee;Kim, Nam-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.519-523
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    • 2007
  • Gas(or methane) hydrates are solid solutions when water molecules are linked through hydrogen bonding and create host lattice cavities that can enclose a large variety of guest gas molecules. The natural gas hydrate crystal may exist at low temperature above the normal freezing point of water and high pressure greater than about 30 bars. A lot of quantities of natural gas hydrates exists in the earth and many production schemes are being studied. In the present investigation, depressurization method was considered to predict the production of gas and the simulation of the two phase flow - gas and water - in porous media is being carried out. The simulation show about the fluid flow in porous media have a variety of applications in industry. Results provide the appearance of gas and water production, the pressure profile, the saturation of gas/ water/ hydrates profiles and the location of the pressure front.

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