• Membrane Journal
• /
• v.6 no.2
• /
• pp.96-100
• /
• 1996

In order to improve the permeability of the homogenous membrane of poly(carbobenzoxy-L-lysin)(PCLL), which has very high selectivity of helium gas to nitrogen gas, asymmetric porous membranes of PCLL were prepared by casting from 20% solutions in dioxane and dimethylformamide(DMF), respectively. The membranes were characterized by measuring the number of the pores, the pore size distribution of the surface(the skin layer) and the thickness of the skin layer by scanning electron microscope and transmission electron microscope. The mean pore size and the pore density were lower for the membrane cast from dioxane than that from DMF, which was explained by the mechanism of the formation of the pores in the asymmetric porous membrane. The permeability coefficient observed could be roughly explained by the viscous flow through the skin layer. However, the selectivity observed was against the theory of the viscous flow.

• Journal of Korea Water Resources Association
• /
• v.54 no.11
• /
• pp.863-873
• /
• 2021

The mechanical dispersion which dominates solute transport in porous media is caused by the difference in flow velocity within pores. Longitudinal dispersion coefficient and longitudinal dispersivity that are hydro-dispersive parameters of advection-dispersion equation can only be obtained by experiment. Hydraulic mean radius that represents the amount and intensity of flowing water within pores can be obtained by the formula using the factors for physical properties. A slug injection test was conducted and a power type empirical formula for obtaining a longitudinal dispersivity using a hydraulic mean radius in rockfill porous media was derived. It is possible to obtain the longitudinal dispersivity depending on transport distance because it contains a formula for a scale constant, and expected to be applicable to waterways filled with homogeneous gravel and small flow rate.

• Journal of Korea Water Resources Association
• /
• v.53 no.10
• /
• pp.861-870
• /
• 2020

As the flow velocity and Reynolds number increase in rockfill porous media, the flow deviates from Darcy conditions. In this study, the permeability tests of rock column specimen and laboratory gabion weir model were carried out to investigate a head loss behaviour of flow through rockfill deposition in small river artificial recharge. Through column test, the nonlinear relationships between flow velocity and hydraulic gradient and coefficients were determined and the correlation formula of hydraulic mean radius and coefficients was proposed. The flow velocities and discharges in voids estimated by proposed equations were well matched with the measured values of laboratory gabion weir model.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2005.04a
• /
• pp.312-315
• /
• 2005

Visual MODFLOW 프로그램 내 MT3D 패키지를 이용하여 다공 추적자 시험 해석 모델을 제시하였으며, 개념모델을 설정하여 추적자 해석 모델 모사 시 입력상수인 수리전도도(K), 비산출률$(S_y)$, 유효공극률$(n_e)$, 종분산지수$({\alpha}_L)$ 및 횡분산지수$({\alpha}_T)$ 등에 따른 민감도를 분석하였다. 또한, 이를 이용하여 부산과 이천지역의 현장 추적자 시험 자료를 해석하였다. 민감도 분석 결과, 유효공극률과 종분산지수의 민감도가 가장 크게 나타났으며, 비산출률의 민감도가 가장 작게 나타났다. 유효공극률은 관측정에서 측정되는 추적자의 최고농도를 결정하는 인자이며, 종분산지수는 추적자 최고농도가 되는 경과시간과 관계가 깊은 것으로 나타났다. 재순환 추적자 시험 해석 모델을 적용한 부산지역의 경우 유효공극률은 0.15, 종분산지수는 5m인 것으로 모사되었으며, 수렴 흐름 추적자 시험 해석 모델을 적용한 이천지역의 경우 유효공극률은 0.01, 종분산지수는 13m로 산정되었다.

• Journal of Korea Water Resources Association
• /
• v.31 no.5
• /
• pp.613-620
• /
• 1998

Field and laboratory studies of the near field behavior of the San Francisco ocean outfall were reported. The data sets cover broad ranges of discharge conditions and oceanic conditions, and are associated with a typical type of outfall discharges with multiport diffusers. The laboratory data sets were obtained in density-stratified towing tanks to replicate the field tests. Model studies of wastefield behavior using these data sets were predicted by the mathematical models UM, UDKHDEN, RSB, and CORMIX2 for minimum dilution, the height to top of wastefield, and wastefield thickness. In this paper, the results are discussed and compared measurements with mathematical model predictions. The hydraulic model studies reproduced the major features observed in the field. It also afforded considerable insight into the mechanics of mixing of multiport risers which could have been obtained neither from the field test nor the mathematical models.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2004.11a
• /
• pp.71-78
• /
• 2004

Most of member parts have experienced severe springback problems because of their open shape Now it becomes imperative to develop an effective method, which can resolve these problems. However, there remain several obstacles to get accurate estimation of shape error. In analysis, we have to analyze the total process including forming, trimming and flanging. Furthermore, it is another challenge to compare the computed result with the real shape. In this study we developed an analysis program for the springback analysis. We could achive a big enhancement in computation time in springback analysis by using latest equation solving technique and could get a more robust solution conversence by contination method. We have approached this problem in two steps. In the first step, we analyzed forming stage to solve tearing and wrinkling problems. In the second step, we have analyzed full process and have done springback analysis with the same boundary condition as field measuring conditions. We have investigated the accuracy of springback analysis in terms of gap and flush used for insfection of real autobody panels. We found good and effective agreement with the observed results.

• Journal of ILASS-Korea
• /
• v.22 no.2
• /
• pp.69-79
• /
• 2017

When designing a redox flow battery system, compression of battery stack is required to prevent leakage of electrolyte and to reduce contact resistance between cell components. In addition, stack compression leads to deformation of the porous carbon electrode, which results in lower porosity and smaller cross-sectional area for electrolyte flow. In this paper, we investigate the effects of electrode compression on the cell performance by applying multi-dimensional, transient model of all-vanadium redox flow battery (VRFB). Simulation result reveals that large compression leads to greater pressure drop throughout the electrodes, which requires large pumping power to circulate electrolyte while lowered ohmic resistance results in better power capability of the battery. Also, cell compression results in imbalance between anolyte and catholyte and convective crossover of vanadium ions through the separator due to large pressure difference between negative and positive electrodes. Although it is predicted that the battery power is quickly improved due to the reduced ohmic resistance, the capacity decay of the battery is accelerated in the long term operation when the battery cell is compressed. Therefore, it is important to optimize the battery performance by taking trade-off between power and capacity when designing VRFB system.

• The Journal of Engineering Geology
• /
• v.32 no.4
• /
• pp.643-659
• /
• 2022

Geologic sequestration technologies such as CCS (carbon capture and storage), EGS (enhanced geothermal systems), and EOR (enhanced oil recovery) have been widely implemented in recent years, prompting evaluation of the mechanical stability of storage sites. As fluid injection can stimulate mechanical instability in storage layers by perturbing the stress state and pore pressure, poroelastic models considering various injection scenarios are required. In this study, we calculate the pore pressure, stress distribution, and vertical displacement along a surface using commercial finite element software (COMSOL); fault slips are subsequently simulated using PyLith, an open-source finite element software. The displacement fields, are obtained from PyLith is transferred back to COMSOL to determine changes in coseismic stresses and surface displacements. Our sequential use of COMSOL-PyLith-COMSOL for poroelastic modeling of fluid-injection and induced-earthquakes reveals large variations of pore pressure, vertical displacement, and Coulomb failure stress change during injection periods. On the other hand, the residual stress diffuses into the remote field after injection stops. This flow pattern suggests the necessity of numerical modeling and long-term monitoring, even after injection has stopped. We found that the time at which the Coulomb failure stress reaches the critical point greatly varies with the hydraulic and poroelastic properties (e.g., permeability and Biot-Willis coefficient) of the fault and injection layer. We suggest that an understanding of the detailed physical properties of the surrounding layer is important in selecting the injection site. Our numerical results showing the surface displacement and deviatoric stress distribution with different amounts of fault slip highlight the need to test more variable fault slip scenarios.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.4 no.4
• /
• pp.363-370
• /
• 2016

Lightweight geopolymers are more readily produced and give higher fire resistant performance than foam cement concrete. Lowering the density of solid geopolymers can be achieved by inducing chemical reactions that entrain gases to foam the geopolymer structure. This paper reports on the effects of adding different concentrations of aluminum powder on the properties of cellular structured geopolymers. The apparent density of lightweight geopolymers has a range from 0.7 to $1.2g/m^3$ with 0.025, 0.05 and 0.10 wt% of a foaming agent concentration, which corresponds to about 37~60 % of the apparent density, $1.96g/cm^3$, of solid geopolymers. The compressive strength of cellular structured geopolymers decreased to 6~18 % of the compressive strength, 45 MPa of solid geopolymers. The microstructure of geopolymers gel was equivalent for both solid and cellular structured geopolymers. The workability of geopolymers with polyprophylene fibers needs to be improved as in fiber-reinforced cement concrete. The lightweight geopolymers could be used as indoor wall tile or board due to fire resistance and incombustibility of geopolymers.

• Resources Recycling
• /
• v.22 no.4
• /
• pp.38-45
• /
• 2013

The porous ceramic beads using mine tailing were prepared and applied to catalytic converter for NOx/SOx removal. Catalytic support was used synthesized mesoporous silica (SBA-15) which coated on surface. Internal structure for porous ceramic beads was composed of three-dimensional network structure and porosity was about 80%. In addition, the specific surface area for mesoporous silica(SBA-15) coated on converter was significantly increased 55 $m^2/g$ compared with 0.8 $m^2/g$ before coating. NOx/SOx removal experiment was performed using $V_2O_5$ and $V_2O_5$/CuO converter. NOx conversion ratio for $V_2O_5$/CuO converter was approximately increased 10% compared to $V_2O_5$ converter. In addition, catalytic converter of $V_2O_5$/CuO was shown to remove 95% of NOx and 90% of SOx at reaction temperature of $350^{\circ}C$, space velocity of 10000 $h^{-1}$ and $O_2$ concentrations of 5%, respectively.