• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.438-449
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• 2020

This study is to improve the method of calculating the risk of liability that arise from release and dispersion of chemicals outside the plant in process industries such as chemical and petrochemical plants. To achieve this goal, the correlation factors with the risk of chemical release accident is derived by simulating release and dispersion of substances (14 types) designated by Ministry of Environment as preparation for accident, analyzing the cases of chemical release and effects of plant life damage. The method of calculating chemical liability risk was modified and supplemented based on the results obtained from the study. The correlation coefficient between the probit value of 14 chemical types and the liability risk by EURAM (European Union Risk Ranking Method) was -0.526, while the correlation coefficient with the modified chemical release accident risk was 0.319. Thus, the value from modified method shows that they appear to be correlated. According to modified calculating methodology, the correlation between ERPG-2 value and liability risk of 97 chemical types was -0.494 which is 19 times higher than existing liability risk correlation as absolute value. And the correlation coefficient of corrosion risk was 0.91. The standardized regression coefficients (β) value of correlation factors that affected the increase and decrease of risk were derived in order of Corrosion Index(0.713), ERPG-2 (0.400) and NFPA Health Index (0.0680) by values. It is expected that these findings this study result will also enable the calculation of reasonable chemical release liability risk for existing and new chemical, and will help use them as quantitative liability risk management indicators for chemical plant site.

• Korean Journal of Hazardous Materials
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• v.6 no.2
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• pp.39-46
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• 2018

최근 전자제품 생산업체에서 EPS를 직접생산하게 되면서 EPS 공정이 증가하고 있다. EPS에는 펜탄이 포함되어 있으며, 펜탄은 하이브리드 혼합물로 구분할 수 있어 높은 화재폭발의 위험성을 가지고 있다. 각 공정별 펜탄의 누출률은 발포기, 사일로실, 저장실 순이나 발포기의 경우 일반적으로 밀폐되어 있으므로 사일로 실이 가장 화재폭발 위험성이 높다고 판단하였다. 사일로실의 누출률 중 70%는 사일로 상단을 통해 누출되며, 사일로 상단을 통해 누출되는 펜탄의 거동을 분석하여 사일로실 위험성 완화대책을 수립하였다. 1. 폭발위험구역 2종으로 관리, 2. 사일로상단 50cm이내 환기설비 설치 또는 Push-Pull 구조의 환기설비설치, 3. 사일로 하단 1.4m이내에 가스감지기 설치, 4. 60%이상의 습도유지

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2003.05a
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• pp.185-190
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• 2003

산업체 등에서 사용되고 있는 가스들중에서 일반적인 가스들과는 달리 위험한 가스(heavy gas)들은 누출사고시에 이들 고유한 확산과 계층화(stratification)방식에 의해 높은 위험성을 유발시키고 있다. 이러한 가스의 누출확산사고들과 일반적인 가스누출사고들의 비교는 그 사실들을 증명해주고 있다. 이런 사실에 의해 위험한 가스확산에 대한 실험과 고유특성을 고려한 확산모델의 개발이 여러 관점에서 진행되고 있으며, 이들의 중요성은 이미 세계적으로 의미를 부여하고 있다.(중략)

• Journal of the Korean Society of Marine Environment & Safety
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• v.24 no.6
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• pp.825-833
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• 2018

In this study, one calculated the range of damage to the combustion characteristics according to the composition of LNG and the size of leaking holes, and analyzed the damage effect in case of leakage accidents caused by pipe damage in the re-gasification process for the LNG supply system. In order to confirm the combustion characteristics according to LNG composition, there was no significant difference in the result of risk analysis by LNG-producing areas. However, the higher the methane content of the components, the lower the risk of flash fire, hazardous areas of overpressure due to explosion, and thermal radiation damage caused by jet fire. In addition, one investigated the effect of leakage, holes, and ruptures on the risk range and explosions according to the size of the pipe-leakage hole. Also, the influence of overpressure and the range of damage from radiant heat could be predicted. One confirmed the effect of LNG composition and pipe-leakage size on fire and explosion.

• Journal of the Korean Institute of Gas
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• v.20 no.3
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• pp.59-65
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• 2016

It is imperative to use suitable explosion proof equipments to prevent explosion in different gas facilities. There is no technical standard for the classification of hazardous areas though standard of explosion proof is regulated. In this study, we have adopted Industrial Standard KS to develop the methodology for the prediction of the explosion risk in the natural gas facility with low pressure using the important factors including hole size, hypothetical volume, validation of ventilation effectiveness. The applicability of the developed methodology was evaluated by the comparison with the data obtained from experiments of natural gas explosion.

• Journal of the Korean Institute of Gas
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• v.21 no.3
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• pp.46-52
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• 2017

During the transportation of chemicals, quantitative risk assessment for chemical leakage accidents caused by traffic accidents was carried out and the appropriateness of chemical transportation route was evaluated. The quantitative risk assessment method applied to the chemical leakage accidents that may occur in the chemical handling equipments installed in the workplace was presented and applied to the chemical transportation. By analyzing the number of traffic accidents in transportation vehicles, the probability of chemical leakage accidents during chemical transportation was predicted and applied to the quantitative risk assessment of chlorine gas leakage accidents that may occur when transporting liquified chlorine bombe using vehicles. As a result, the most appropriate route of transporting the liquefied chlorine bombe was suggested on the basis of risk.

• Journal of the Korean Institute of Gas
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• v.8 no.4 s.25
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• pp.8-14
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• 2004

Accidental releases of toxic gases heavily affect to the risk of process facilities. In this research, consequence analysis for accidental releases of ammonia and chlorine gases was studied using the risk based inspection, based on API-581 BRD. It was found out that consequence areas (toxic areas) decrease as temperature increases and as the pipe diameter and pressure decrease. For the same release condition, the toxic area by the release of chlorine gas was larger than that by the release of ammonia gas.

• Journal of the Korean Institute of Gas
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• v.24 no.2
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• pp.15-21
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• 2020

Currently, in KS C IEC 60079-10-1, the leakage hole radius of secondary leakage is expressed as a recommendation. Underestimation of leak hole size can lead to underestimation of the calculated values for leak rates, and conservative calculations of leak hole sizes, which are considered for safety reasons, can be overestimated, resulting in an overestimated risk range. This too should be avoided. Therefore, a careful and balanced approach is necessary when estimating the size of leaking holes.Based on this logic, this study examines the stability by grasping the concentration inside the gas box when leaking dangerous substances as a result of experiments based on SEMI S6, an international safety standard applied in the semiconductor industry and The scope of explosion hazardous area was determined by applying the formula of KS C IEC 60079-10-1 according to SEMI F15 leak rate criteria and SEMI S6 leak rate criteria. Based on this, we will examine whether the exhaust performance needs to be improved as an alternative to FAB facilities that are difficult to apply to explosion hazards such as semiconductor industry.

• Journal of the Korean Institute of Gas
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• v.25 no.2
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• pp.42-51
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• 2021

Facilities that supply specialty gases used in semiconductor manufacturing mainly handles with hazardous and dangerous substances with flammable, toxic, and corrosive properties, and gas cabinets are mainly used as such supply facilities. The effects of the supply facilities were analyzed for each leak through the rupture disk in the gas cabinet and a leak where the leak hole. In this case, gas leaked to the outside depending on the leak area. It is a factor that creates a risk depending on the concentration of the leaked gas. Depending on the risk of leakage, all measures such as safe operation procedures should be reviewed again.

• Fire Science and Engineering
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• v.17 no.3
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• pp.61-73
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• 2003

Most of the accidents occurred from the chemical plants are related to the catastrophic gas release events when the large amount of toxic materials is leaked from its storage tank or transmitting pipe lines. In this case, the greatest concerns are how the spreading behaviors of leakages are depended on the ambient conditions such as air stability and other environmental factors. Hence, we have focused on the risk assessments and consequential analysis for chlorine as an illustrative example. As appeared in the result, Fire & Explosion Index depicted it a bit dangerous with presenting the comprehensive degrees of hazard 90.7. And as a result of Phast6.0/ALOHA, the trends of each scenario appeared considerably identical although there are some differences in the resulting effects according to the input data for the Gas Model. The consequence analysis is performed numerically based on the dense gas mode. In the future, using more correct input data, material properties, and topographical configuration, the method of this research will be useful for the guideline of the risk assessment when the release of toxicants breaks out.