• Title/Summary/Keyword: 농도 측정

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Measurement of Surfactant Concentration Using Light Scattering Method (광 산란방법을 이용한 계면활성제 농도측정)

  • Jo, Young Hyeon;Jo, Gyeong Hyeon;Jung, Chi Sup
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.8
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    • pp.441-448
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    • 2017
  • A method for measuring the concentration of surfactant in water was developed. In this technique, microbubbles were used as light scatterers. The polarization change of light scattered by microbubbles was analyzed by Mueller matrix analysis. $M_{11}$, one of the Mueller matrix elements, was found to be a key parameter inferring the surfactant concentration within the concentration range of 0 ppm to 60 ppm. The best results for this measurement were obtained when the scattering angle was $150^{\circ}$ and the extinction ratio was 56.2. This experimental result shows that the EPLS can be effectively used as a real time inspection method for water quality monitoring in lakes or rivers.

On the Effect of Tube Attenuation on Measuring Water Vapor Flux Using a Closed-path Hygrometer (폐회로 습도계를 이용한 수증기 플럭스 관측시관의 감쇠 효과에 관하여)

  • Hong Jinkyu;Kim Joon;Choi Taejin;Yun Jin-il;Tanner Bert
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.2 no.3
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    • pp.80-86
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    • 2000
  • Eddy covariance method is widely used in measuring vertical fluxes of mass and energy between the atmosphere and the biosphere. In this method, scalar concentration is measured with either open-path or closed-path sensors. For the latter, fluctuations of scalar concentration are attenuated as the sample travels through a long tube, resulting in flux loss. To quantify this tube attenuation, water vapor concentrations measured with both closed-path and open-path sensors were analyzed. Our statistical analysis showed that the power spectral density obtained from the closed-path sensor was different from that from the open-path sensor in the frequency range of > 0.5 Hz. The loss of water vapor flux due to tube attenuation was < 5% during midday. At nighttime, however, the flux loss increased significantly because of the low wind speeds and the weak turbulence sources. Theoretical calculation for the tube attenuation showed a small bias in high frequency range probably because of the interaction of sticky water vapor with a tube wall.

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An Industrial Application for functional Materials and Polyphenols Isolated from the Korean Persimmon Leaves (감나무잎 폴리페놀의 기능성 소재로서 산업적 활용)

  • 안봉전
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2002.04a
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    • pp.29-40
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    • 2002
  • 감잎으로부터 통풍치료, 미백효과, 고혈압 억제효과의 개발목적으로 9종의 flavan-3-ol 화합물을 분리하였고 기기분석에 의해 화학구조를 자혔다. 각 화합물은 (+)-catechin (+)-gallocatechin procyanidinB-l, pyrocyanidin C-1, prodelphinidin B-3, gallocatechin-(4$\alpha$$\longrightarrow$8)-catechin과 감나무 잎에서 새로운물질인pocyanidin B-7-3-0-gallate, procyanidin C-1-3'-3" -3.'S _0-trigallate, (-)-epigallocatechin-(4 $\beta$ -18)-epigallocatechin-(4$\beta$-'8)-catechin 3종류를 발견하였다. 감잎으로부터 순수 분리한 polyphenol류의ACE 저해활성측정을 실험한 결과 pocyanidin B-7-3-0-gallate는 100rM농도에서 94%의 저해효과를 나타내었으며 epigallocatechin-(4$\beta$$\longrightarrow$8)-epigallo-catechin-(4$\beta$$\longrightarrow$8)-catechia procyanidin C-1-3'-3" -3f'.-0-trigallate는 각각 90.69, 80.90% 저해를 하였다. Xanthine oxidase 저해활성측정을 조사한 결과pocyanidin B-7-3-0-galtate와 pocyanidin C-1-3'-3" -3/'S _0-trigallate 즉, gallate가 붙은 호합물에서100rM의 농도에서 66%와 63%의 강한 저해효과를 나타났다. Tyrosinase 저해활성을 측정한 결과는pocyanidin C-1-3'-3" -3.'S _0-trigallate는 100rM에서 70%의 강한 저해효과를 나타냈으며,epigallocatechin-(4$\beta$$\longrightarrow$8)-epigallo-catechin-(4$\beta$$\longrightarrow$8)-catechin는 51%의 저해효과를 나타내었다. 산업적응용을 위해 분획한 폴리페놀군은 미백효과 검증실험인 tyrosinase 저해율 측정평가에서 폴리페놀 함량이 가장 높은 Fraction 111의 경우 Sooppm에서 74.2%의 높은 저해율을 나타내었다. 항산화력 실험에서는500pw1이상에서 강한 활성능을 보인 SOD 유사활성능을 제외한 나머지 DPPH와 xanthine oxidase 저해효과에서는 Fraction II와III 모두가50ppm이상에서 80% 이상의 높은 유리라디칼 소거능력을 나타내었다. 그리고 각 Fraction별 항균력 측정 결과 Fraction 르와 111이 우수하게 나타났고 항균활성은 그람음성균보다 그람양성균에서 효과적이었으며, 농도별 항균력시험 결과 농도가 증가할수록 비례하여 저해율도 증가함을 알 수 있었다. 첨가농도를 달리하여 미생물의 생육도를 측정한 결과, fraction II磎꼭\ulcorner경우 그람양성균에 대해 500 ppm 이상에서 뚜렷한 증식억제효과를 나타내었다.서 뚜렷한 증식억제효과를 나타내었다.

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Study on Porous Silicon Sensors to Measure Low Alcohol Concentration (저농도 알코올 측정을 위한 다공질 실리콘 센서에 관한 연구)

  • Kim Seong-Jeen
    • Journal of the Korean Electrochemical Society
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    • v.2 no.3
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    • pp.130-133
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    • 1999
  • In this work, a capacitance-type alcohol gas sensor using porous silicon layer is developed to apply for breath alcohol measurement and its characteristics are estimated at room temperature. Current alcohol sensors using metal oxides such as tin-oxide are not only difficult to measure low alcohol concentration, but also should heat at $200\;to\;400^{\circ}C$ to improve the sensitivity. But the sensor using porous silicon layer has good sensitivity even at room temperature by very large effective surface area and suitable structure to fabricate integrated micro sensors. In the experiment, the capacitance was measured for the range of 0 to $0.5\%$ alcohol concentration with the interval of $0.05\%$, in which alcohol solution was kept at 25, 36, and $45^{\circ}C$ by a heater. As the result, good linearity was observed and the capacitance increased about 1.1, 2.6 and $4.6\%$ per the increment of $0.1\%$ alcohol concentration each temperature, respectively, at the frequency of 120 Hz.

On-Road Investigation of PM Emissions of Passenger Vehicles Fuelled with Diesel and Gasoline Using Mobile Emission Laboratory (이동형 배출가스 측정시스템(MEL)을 이용한 디젤 및 가솔린 차량에서 배출되는 입자상 물질 평가)

  • Lee, Seok-Hwan;Kim, Hong-Suk;Park, Jun-Hyuk;Woo, Se-Jong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.7
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    • pp.737-744
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    • 2012
  • A mobile emission laboratory (MEL) was designed to measure the amount of traffic pollutants, with high temporal and spatial resolution under real conditions. Equipment for the gas-phase measurements of CO, NOx, $CO_2$, and THC and for the measurement of the number, concentration, and size distribution of fine and ultra-fine particles by an FMPS and CPC was placed in a minivan. The exhausts of different types of vehicles can be sampled by an MEL. This paper describes the technical details of the MEL and presents data from the experiment in which a car chases passenger vehicles fuelled by diesel and gasoline. The particle number concentration in the exhaust of the diesel vehicle was higher than that of the gasoline vehicle. However, the diesel vehicle with a DPF emitted fewer particles than the vehicle equipped with a gasoline direct injection engine, with particle diameters over 50 nm.

Real-time Highly Sensitive Measurement of Myocardial Infarction Biomarkers Using Silicon-based Ellipsometric Biosensors (실리콘 기반 타원편광계식 바이오센서를 이용한 심근경색 생체표지자의 실시간 초고감도 진단 농도 측정)

  • Min, Yoon Gi;Cho, Hyun Mo;Jo, Jae Heung
    • Korean Journal of Optics and Photonics
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    • v.30 no.2
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    • pp.59-66
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    • 2019
  • We report highly sensitive detection of myocardial infarction biomarkers, such as myoglobin and cTnI, within several hundred seconds using a rotating-analyzer ellipsometer and a biosensor with biochips fabricated on a $SiO_2$-coated tilted silicon substrate. We choose the running buffer to be pure phosphate-buffered saline (PBS) or 10% mixed human serum. When we choose the running buffer to be pure PBS, we obtain diagnostic densities of pure myocardial infarction biomarkers of up to 1 ng/ml and 5 pg/ml respectively. Meanwhile, when we use PBS with 10% human serum, the measured densities of myoglobin and cTnI were up to 1 ng/mL and 1 pg/mL respectively. The measured diagnostic densities are less than 1/15 and 1/80 (in cases of myoglobin and cTnI respectively) of those referenced by the World Health Organization.

Comparative Characterization on Bacterial Disinfection Using Trichloroisocyanuric Acid, Bromochlorodimethylhydantoin, and Calcium Hypochlorite (삼염화이소시아눌산, 브룸염화히단토인, 및 칼슘하이포클로라이트의 농도 및 접촉시간에 따른 미생물 사멸특성)

  • Oh, Se-Hyun;Yoo, Hyun-Duk;Lee, Han-Na;Kim, Eung-Soo
    • Microbiology and Biotechnology Letters
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    • v.35 no.4
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    • pp.334-338
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    • 2007
  • The disinfection effects of trichloroisocyanuric acid (TICA), calcium hypochlorite (CH), and Bromochlorodimethylhydantoin (BCDMH) on various bacteria in aqueous suspension were comparatively characterized at various concentrations and exposure times of each disinfectant. When various bacteria cells ($10^8\;CFU/ml$) including Escherichia coli, Pseudomonas aeroginosa, Enterococcus faecalis, Bacillus cereus, Legionella pneumophila, and Staphylococcus aureus were exposed with a solution containing 8 ppm each of TICA, a 99% of the initial cells were killed in 60 sec, 368 sec, 372 sec, 506 sec, 812 sec, and 909 sec, respectively. In addition, the minimum exposure time required to kill 99% of E. coli ($10^8\;CFU/ml$) with 8 ppm of each TICA, BCDMH and CH was measured at 60 sec, 114 sec, and 7,100 sec, respectively. These comparative studies demonstrate that disinfection efficacy is highly variable depending on microbial species as well as disinfectant type, concentration, and exposure time.

Measurement of Radon Daughters in Airborne Dust (공기부유진내(空氣浮游塵內)의 Radon 붕괴생성물(崩壞生成物)의 농도측정(濃度測定))

  • Kim, Pill-Soo;Min, Duck-Kee;Ro, Seung-Gy
    • Journal of Radiation Protection and Research
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    • v.2 no.1
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    • pp.9-16
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    • 1977
  • A simple method has been established for determining RaA, RaB and RaC concentrations in airborne dust. This is to evaluate the concentration from measurement of total alpha activities in three selected-time intervals after an air sample is taken from the membrane filter paper (mean pore size: $0.8{\mu}m$). As a preliminary trial, a time-variation of the concentrations has been determined using the single-filter method at the KAERI site (N. Lat. $37^{\circ}38'$ and E. Long $127^{\circ}15'$), Seoul, Korea. It appears that there is a large variation of the concentrations depending on the sampling time. Generally the highest value was observed in the morning that may coincide with the highest density of atmosphere in a day while the lowest value was obtained around fourteen o'clock.

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The Measurement Method Using Hydrogen Peroxide for Quantification of Phosphate Ion Poisoning of Pt Based Catalyst (과산화수소를 이용한 Pt계 촉매의 인산 이온 피독 특성 정량 평가 방법)

  • Yang, Seungwon;Park, Jeongjin;Chung, Yongjin;Kwon, Yongchai
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.438-443
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    • 2019
  • A new measurement method is suggested to quantify the phosphate poisoning of cathodic Pt catalyst for HT-PEMFC. To do that, hydrogen peroxide was used as an indicator to reduce the error which has been occurred in conventional electrochemical measurement such as CV or ORR RDE with high concentration of phosphate ions. As a result, the current density induced from the reaction of hydrogen peroxide decomposition increased proportionally to the concentration of phosphate ion while the conventional methods show has a significant error with high concentration of phosphate ion. Thus, it is confirmed that the suggested way is superior to the conventional measurement method for the quantification of phosphate ion poisoning in an atmosphere similar to the actual operation condition of HT-PEMFC.

Actinometry에 의한 CF4플라즈마에서의 F라디칼의 공간분포

  • Lee, U-Hyeon;Jeong, Jae-Cheol;Kim, Dong-Hyeon;Kim, Hyeok;Hwang, Gi-Ung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.217-217
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    • 2011
  • 플라즈마를 이용하는 식각 및 증착등의 반도체공정에 있어서 최근에는 기판의 크기가 점차 증가하는 추세에 있다. 이러한 대면적 플라즈마 발생장치 내에서 플라즈마 밀도와 라디칼 농도의 공간적인 특성을 이해하는 것에 대한 중요성이 더해지고 있다. 이를 위해 Langmuir probe와 같은 전기적 접근법에 의한 진단방법이나 광학적 접근법에 의한 진단방법에 대한 연구가 이루어 졌다. 전기적 접근법에 의한 플라즈마의 진단방법은 원리가 간단하고 정확도가 높다는 장점이 있지만 진단 장치에 의한 플라즈마의 간섭이 크고 식각가스의 경우 진단이 어렵다는 단점이 있다. 그에 비해 광학적 진단방법은 플라즈마에 간섭이 많지 않은 방법으로 알려져 있고 레이저 형광법(LIF), 원적외선 레이저 흡수 분광법(IR laser Absorption Spectroscopy), 광량측정법(Actinometry)등이 있다. 이 중 레이저 형광법, 원적외선 레이저 흡수 분광법의 경우, 진단장치가 매우 복잡하고 가격이 비싸다는 단점을 가지고 있다. 반면 광량측정법의 경우 다른 광학적 접근법에 의한 진단방법에 비해 원리와 실험장치가 간단하고 공간적인 라디칼 분포의 진단이 쉽다는 점에서 장점을 가지고 있다. Actinometry는 Ar과 같은 불활성 기체를 작은 비율을 넣어서 여기 된 불활성 기체의 파장세기와 여기 된 측정 라디칼의 파장세기의 비교를 통해 상대밀도를 측정하는 방법이다. 이 측정 방법에 Abel's inversion equation을 적용함으로 해서 대면적 M-ICP(Magnetized - Induced Coupled Plasma)에서 식각가스인 $CF_4$플라즈마에서 F 라디칼 농도의 공간적인 분포를 측정하고 분석하였다. 또한 플라즈마의 압력, 소스 전력 값과 기판 전력 값등의 조건의 변화에 따라 F 라디칼 농도의 분포가 어떻게 달라지는지에 대해 측정 분석하여 다루었다.

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