• Title/Summary/Keyword: 녹색화학

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Environment Control for Photosynthesis Measurement (광합성 계측과 계측환경제어)

  • 이변우;최일선
    • Proceedings of the Korean Society for Bio-Environment Control Conference
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    • 1999.11a
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    • pp.13-24
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    • 1999
  • 식물이 생장하고 발육하며 자신의 생명을 유지해 나가기 위해서는 끊임없이 에너지를 공급받아야 하는데, 이 에너지의 공급원은 태양으로부터 오는 광에너지이다. 이러한 광에너지는 엽록소(chlorophyll)를 함유한 녹색식물의 잎이나 줄기 등에서 기공(stomata)을 통하여 흡수되는 이산화탄소($CO_2$)와 뿌리에서 주로 흡수되는 물($H_2O$)로부터 당류ㆍ전분과 같은 탄수화물을 합성하고 산소를 방출하는데 이러한 광에너지가 화학에너지로 변환되는 과정을 광합성(photosynthesis) 또는 탄소동화작용(carbon assimilation)이라고 한다. (중략)

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High-resolution Patterning of Colloidal Quantum Dots via Non-destructive, Light-driven Ligand Crosslinking (양자점용 가교제를 이용한 고해상도 양자점 광패터닝 기술)

  • Yang, Jeehye;Kang, Moon Sung
    • Prospectives of Industrial Chemistry
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    • v.23 no.6
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    • pp.14-24
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    • 2020
  • 최근 우수한 발광 특성을 갖는 양자점을 고해상도 디스플레이의 발광 소재로 도입하고자 하는 노력이 활발하다. 양자점을 활용한 디스플레이의 실현을 위해서는 콜로이드 상태인 다색의 양자점을 고해상도로 패터닝하는 기술의 확립이 필요하다. 본 연구에서는 ethane-1,2-diyl bis(4-azido-2,3,5,6-tetrafluorobenzoate)를 양자점용 가교제로 활용하여 용액공정을 기반으로 형성된 양자점 박막을 고해상도로 패터닝한 기술을 소개하고자 한다. 위 양자점용 가교제의 양 말단에는 아지드 그룹을 포함한 작용기가 존재한다. 아지드 기는 자외선에 의해 광 활성화되어 양자점 표면의 알킬 리간드와 가교 결합을 형성함으로써, 양자점 박막에 화학적 내구성을 부여한다. 본 기술을 기반으로, 적색, 녹색, 청색의 카드뮴 기반 양자점을 고해상도로 패터닝하고 정밀하게 배열하여 인치 당 화소 수 1400 이상의 픽셀 형성에 성공하였다. 또한 가교 반응 후에도 성능 저하가 없는 양자점 박막 및 자발광 양자점 다이오드를 개발하였다.

Low-Carbon, Green-Growth and Empirical Analysis on Potential for Accomplishment by Industries (저탄소 녹색성장과 산업의 잠재성과에 관한 실증분석)

  • Lee, Myunghun
    • Environmental and Resource Economics Review
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    • v.20 no.1
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    • pp.99-118
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    • 2011
  • 'Low Carbon, Green Growth' may be the achievable target in industry section, depending on whether less reliance on fossil-fuels use can bring higher productivity growth in the long run. This paper tests for the short-run and long-run effects of investment on energy-saving equipments on productivity growth in the Korean manufacturing industries. The investment in energy efficiency causes an increase in costs (measurement effect) in the short-run, but in the long-run likely improve energy intensity and reduce costs (positive real effect) despite the delay in new other investment for technical innovation (negative real effect). A 2SLS regression was attempted to deal with endogeneity of energy-saving investment. The productivity effects were tested for five manufacturing sub-industries showing relatively high energy intensity with annual time series data from 1982 through 2006. No productivity effects were accepted for all five sub-industries except Chemical products. Positive real effect was considered to be exceeded by negative real effect, resulting in decreased productivity growth for Chemical products.

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Atom-efficient Preparation of 9, 9'-Bis[4-(2'-hydroxy-3'-acryloyloxypropoxy)phenyl]fluorene (9, 9'-비스[4-(2'-하이드록시-3'-아크릴로일옥시프로폭시) 페닐]플루오렌의 원자효율적 합성)

  • Jung, Hyeok-Jin;Hong, Seong-Jae;Seo, Kwang-Beom;Shim, Jae-Jin;Ra, Choon-Sup
    • Clean Technology
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    • v.17 no.4
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    • pp.325-328
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    • 2011
  • Atom-efficient preparation of 9, 9'-bis[4-(2'-hydroxy-3'-acryloyloxypropoxy) phenyl]fluorene (3), the extensively used building block for fluorene-containing acrylic epoxy polymers has been described. The epoxide ring opening esterification of 9, 9-bis[4-(glycidyloxy)phenyl]fluorene (1) with acrylic acid was catalyzed by some onium salts such as quaternary ammonium and phosphonium salts. While the coupling reactions depend greatly on the kind of the onium salts, the reaction of 9, 9-bis[4-(glycidyloxy)phenyl]fluorene (1) with acrylic acid proceed most efficiently in the presence of a catalytic amount of tetrabutylphosphonium bromide at $110^{\circ}C$ with 90% yield. This reaction is a cleaner reaction that minimizes the use of reactants and the production of chemical wastes.

U.S.'s Patent Network Analysis and Technology Trends on Underground Water for the Response of Climate Change (기후변화 대응을 위한 미국 지하수 기술 특허네트워크 분석과 주요 특허 기술 동향)

  • Yoon, Soon-Uk;Choi, Hanna;Kim, Minchul
    • Journal of Energy Engineering
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    • v.28 no.3
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    • pp.55-64
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    • 2019
  • This study identified key patents on U.S. underground water technology through patent network analysis. As a result, there were many technologies that used the technology to remove heavy metals to prevent contamination of groundwater. While patents between groundwater technology patents were in charge of intermediaries, the connectivity between groundwater technologies is not high. The patented technologies related to groundwater were largely distinguishable by pumping, monitoring, and decontamination. Monitoring includes techniques that enable identification of physical and biological properties, such as the type of contaminants, as well as geographic characteristics for analysis of groundwater flow, flow or water quality. Pollution purification technology refers to the process of physiochemical and biological purification for soil and groundwater. U.S. technology cases showed that the U.S. had high technology in water treatment area. And patent protection were also needed to cope with water shortages caused by climate change.

Mössbauer and Infrared Absorption Spectroscopy of Tourmaline Minerals (전기석 광물의 뫼스바우어 및 적외선 흡수 분광학)

  • Kim, Hee Jong;Kim, Soo Jin
    • Journal of the Mineralogical Society of Korea
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    • v.6 no.2
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    • pp.105-115
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    • 1993
  • $M{\ddot{o}}ssbauer$ and Infrared absorption spectra of the iron-bearing tourmaline minerals show that the ferrous and ferric ions occupy the Y and Z octahedral sites. The Fe ions are almost ferrous, predominantly partitioning into Y site and partly take in Z site. The $Fe^{2+}$ content of the Z sites in brownish black tourmaline minerals are higher than that in blue/green tourmaline minerals. Therefore, 720 nm peak of brownish black samples is broader than that of blue/green samples in optical spectra. All of the blue/green tourmaline minerals used in experiment have only $Fe^{2+}$ ion. The IR spectra of tourmaline depend on the cation environments around OH groups, as also evidenced by their chemical analyses. There appear no difference in IR spectrum between O(1)H and O(3)H binding characters in the heat-treated samples. But the characteristic $3565cm^{-1}$ peak appears in the ferrous hydroxyl bearing silicates, where dehydroxylation temperature for OH coordinated to $Fe^{2+}$ is $700{\sim}800^{\circ}C$.

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A Study of Greenish Pigments from Rhodopseudomonas viridis by Acetone Extraction: Characteristics of Potential Food Colorant (Acetone 추출한 Rhodopseudomonas viridis 녹색색소에 대한 연구: 식용색소로서의 일반적 성질)

  • Kim, Yong-Hwan;Lee, Sang-Seob
    • Korean Journal of Food Science and Technology
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    • v.26 no.1
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    • pp.93-97
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    • 1994
  • A study of physical and chemical characteristics of pigments from Rhodopseudomonas viridis DSM 133 was carried out for development of natural greenish colorant. Through visible absorption scanning, it showed three main absorption peaks at 378, 414 and 677 nm with three minor peaks at 510, 540 and 618nm, and it was shown to be greenish color. These pigments were more stabilized in alkaline solutions than in acid of between pH 6 and 9, and it was shown to be stabilized at the temperature below $40^{\circ}C$. In the presence of light and oxygen, the stability of pigments rapidly degraded, and it became unstable in the presence of metal ion such as $Fe^{3+}$ and $Al^{3+}$. But in the presence of $Cu^{2+}$ were very stable. On the result of TLC analysis, pigments were shown to be composed of four color fractions and main color fractions were F-4 and F-2.

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An Experimental Study on the Flowability and Compressive Strength of Color Concrete Mixed with Pigments (안료를 첨가한 칼라콘크리트의 유동성 및 강도에 대한 실험적 연구)

  • Choi, Jae Jin;Hwang, Eui Hwan;Moon, Dae Joong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.3A
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    • pp.547-553
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    • 2006
  • To know the effect of pigments on the material properties of color concrete, mortar and concrete tests were carried out by the using 5 kinds of pigment. The major component of red, yellow and black pigments was iron oxide and coloring component of blue and green pigments was copper phthalocyanine. Properties of mortar and concrete were some of difference according to adding ratio and kind of pigments. In case of using red, yellow and black pigments, setting time of concrete speeded a little and compressive strength was tendency to increase and slump or air content of concrete was same or decreased. On the other hand, in case of using green and blue pigments, compressive strength of concrete decreased largely because of the excessive air entrainment of surfactant and sump or air content of concrete increased highly. When the antifoaming agent was added to the color concrete mixed with green and blue pigments, compressive strength of concrete was improved and similar to that of concrete without pigment.

Synthesis of 6-Alkyl-3-Chromonealdehyde(2,2-dialkyl)hydrazone Derivatives for Green Light Emitting Materials (녹색발광 6-알킬-3-크로몬알데히드(2,2-디알킬)하이드라존 유도체의 합성)

  • Chung, Pyung-Jin;Chang, Hong-Joon
    • Applied Chemistry for Engineering
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    • v.21 no.4
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    • pp.424-429
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    • 2010
  • 6-Alkyl-3-chromonealdehyde (2,2-dialkyl)hydrazone derivatives were synthesized by dehydration condensation. They are green-emitting materials for organic light emitting device (OLED) composed of electron acceptor of 6-alkyl-3-chromonealdehydes and electron donor of 2,2-dialkylhydrazones in a conjugated structure. The structural properties of reaction products were analyzed by FT-IR and $^1H$-NMR spectroscopy. The thermal stabilities and reactivities were measured by melting points and yields. The UV-visibles and PL properties were also determined by excitation spectra and emission spectra, respectively.

Synthesis of 3-Chromonealdehyde(2,2-disubstituted)hydrazone Derivatives for Green Light Emitting Materials (녹색발광 3-크로몬알데히드(2,2-이치환)하이드라존 유도체의 합성)

  • Chung, Pyung Jin;Chang, Hong Joon
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.670-674
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    • 2009
  • 3-Chromonealdehyde(2,2-disubstituted)hydrazone derivatives were synthesized by dehydration condensation. They are green-emitting materials for organic light emitting device (OLED) composed of electron acceptor of 3-chromonealdehydes and electron donor of 2,2-disubstituted hydrazones by a conjugated structure. The structural properties of reaction products were analyzed FT-IR and $^1H-NMR$ spectroscopy. The thermal stabilities and reactivities were measured by melting points and yields. The UV-visibles and PL properties can be determined by excitation spectra and emission spectra, respectively.