• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.6
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• pp.2189-2205
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• 1991

Thermodynamic properties of binary nonazeotropic refrigerant mixtures are estimated by using a modified Carnhan-Starling equation of state. In this study, pure component refrigerants such as R14, R23, R13, R13 B1, R22, R12, R134a, R152a, R142b, RC318, R114, R11, R123 and R113 are chosen and the thermodynamic properties of enthalpy and entropy are calculated in terms of relevant variables. The modified Carnahan-Starling equation of state is compared with the carnahan-Staring-De Santis equation of sate. Results show that the relative errors become slightly smaller with the equation of state proposed in this study. Correlations are obtained for the mixtures of which the vapor liquid equilibruim data are available to us in the literature. Those mixtures are R14/R23, R23/R12, R13/R12, R13/R11, R13B1/R22, R13B1/RC318, R12/RC138, R12/R114 and R12/R11. The binary interaction coefficients are found under the condition of minimizing the pressure deviations at the vapor liquid equiblibrium state and the estimation of the vapor liquid equilibrium for the refrigerant mixtures is done. Pressure-enthalpy and temperature-entropy diagrams are plotted for the refrigerant mixtures of specific composition.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.12
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• pp.1656-1667
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• 1997

Condensing heat transfer characteristics of hydrocarbon refrigerants are experimentally investigated. Single component hydrocarbon refrigerants (propane, isobutane, butane and propylene) and binary mixtures of propane/isobutane and propane/butane are considered as test fluids. Local condensing heat transfer coefficients of selected refrigerants are obtained from overall conductance measurement. Average heat transfer coefficients at different mass fluxes and heat transfer rates are shown and compared with those of R22. Pure hydrocarbon refrigerants have higher values of heat transfer coefficient than R22. It is also found that there is a heat transfer degradation for hydrocarbon mixtures due to composition variation during condensation. Measured condensing heat transfer coefficients are compared with predicted values by available correlations. An empirical correlation for pure and mixed hydrocarbon is developed, and it shows good agreement with experimental data.

• Journal of the Korean Institute of Gas
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• v.11 no.4
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• pp.35-40
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• 2007

In this paper, evaporation heat transfer characteristics of propane and iso-butane in micro-fin tubes were investigated experimentally. Test section has a micro-fin tube with outside diameter of 12.70 mm, and 75 fins with a fin heights of 0.25 mm. The experimental results summarize as the followings: The average evaporation heat transfer coefficients of He's refrigerants is higher than those of HCFC22, and appeared in the order of iso-butane, propane with respect to the approaching of the high mass flux. The evaporation heat transfer coefficient of micro fin tube is about $10{\sim}80%$ higher than those of smooth tube. This results from the study can be used in the case of designing heat transfer exchanger using hydrocarbons as the refrigerant for the air-conditioning systems.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.3
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• pp.423-436
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• 1996

Thermodynamic performance of eight zeotropic R-22 alternative refrigerant mixtures selected by AREP(R-22 Alternative Refrigerants Evaluation Program) and R-32/R-125/R-134a(23%/25%/52%), namely R-407C were evaluated by the "drop-in" simulation method. An existing air conditioner was selected and its design data were used for the simulation. "ARI Test A" air conditions were applied. The degree of vapor superheat at the compressor inlet fixed at $5^{\circ}C$ for all the mixtures. The results of the simulation were compared with those of R-22. COPs of all mixtures except for R-32/R-227ea(35%/65%) and R-32/R-125/R-134a(10%/70%/20%), were higher than that of R-22 by 2%~8%, while the capacities were all lower than that of R-22 by 13%~27%. COP of R-32/R-134a(40%/60%) was 2.4% higher but the capacity was 15% lower than those of R-22. In the case of R-32/R-134a(30%/70%), COP and capacity were 5.5% higher and 15% lower than those of R-22, respectively. Among the ternary mixtures, R-407C and R-32/R-125/R-134a(30%/10%/60%) showed the best performance. COP of R-407C was 2.4% higher than those of R-22 but the capacity was 15% lower.

• Journal of Energy Engineering
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• v.15 no.4 s.48
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• pp.243-249
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• 2006

An experimental study on the refrigerant-side pressure drop of slit fin an tube heat exchanger has been carried out. A comparison was made between the predictions of previously proposed empirical correlations and experimental data for the pressure drop on design conditions of condenser in micro-fin tube for R22 and Rl34a. Experiments were carried out under the conditions of inlet refrigerant temperature of $60^{\circ}C$ and mass fluxes varying from $150\;to\;250\;kg/m^{2}s$ for R22 and Rl34a. The inlet air conditions are dry bulb temperature of $35^{\circ}C$, relative humidity of 40% and air velocity varying from 0.68 to 1.43 m/s. Experiments show that pressure drop for R134a was $22{\sim}22.6%$ higher than R22 for the degree of subcooling $5^{\circ}C$ For the mass fluxes of $200{\sim}250\;kg/m^{2}s$, the deviation between the experimental and predicted values for the pressure drop was less than ${\pm}20%$ for R22 and Rl34a.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.9
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• pp.2131-2137
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• 1993

This study, examines the performance and the heat pump cycle systematizing characteristics for non-azeotropic refrigerant systems. In order to conduct such an examination, the cycle characteristics of heat pumps for pure R-22, R-114, and their mixtures were experimentally investigated. The results show that cooling/heating capacities for the mixtures was more suited at the evaporating temperature of $5^{\circ}C$ than that of $0^{\circ}C$, $-5^{\circ}C$, and $-10^{\circ}C$. The C.O.P of the 50 wt% mixtures was considerably higher than for pure R-22, and the compression power of the 25 wt% was as much as 60% lower than that of pure R-22. Even small fractional mixture variations can lead to significant changes in the characteristics of the heat pump cycle. This experiment verified the importance of accurate weight fractions of refrigerant mixtures.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.3
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• pp.408-415
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• 1998

This study presents experimental results on the shut-down and start-up characteristics of a residential split-system air-conditioner with capillary tube, using R410A as a R22 alternative refrigerant. During shut-down, the transient characteristics are evaluated by measuring the high side and low side pressures and temperatures of the system. The dynamic behavior of the system after start-up is also investigated at the high temperature cooling test condition. All experiments are performed in psychrometric calorimeter. The cooling capacity, power consumption, dehumidification capacity and cycle characteristics after start-up are analyzed.

• Journal of Advanced Marine Engineering and Technology
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• v.20 no.4
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• pp.70-80
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• 1996

Experimental results for forced convection condensation of R-22 and R-407C inside 7.5mm ID and 4000mm length of horizontal tubes are presented. The experimental data covered total flow rate from 114.3 to 267.1kg/($m^2$.s) and quality from 0 to 1. The vapor temperature and pressure drop along the tube were measured. The pressure drop for R-407C increased with flow rate similar to that of R-22. The experimental data compared with the available perdictions for pressure drop. Based on the data a prediction method was presented for the calculation of pressure drop of R-22 alternative refrigerants.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.24 no.5
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• pp.391-400
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• 2012

In this study, performance of HFC32/HFC152a mixture is measured in the composition range of 20 to 50% R32 with an interval of 10% for the comparison with the conventional HCFC22 in water-source heat pumps. Tests are carried out under the same capacity in a heat pump bench tester equipped with a variable speed compressor at the evaporation and condensation temperatures of 7/$45^{\circ}C$ and -7/$41^{\circ}C$ for summer and winter conditions, respectively. Test results show that the compressor power of the HFC32/HFC152a mixture is 13.7% lower than that of HCFC22 while the coefficient of performance(COP) the HFC32/HFC152a mixture is 15.8% higher than that of HCFC22. Hence, from the view point of energy efficiency, the HFC32/HFC152a mixture is excellent as compared to HCFC22. Compressor discharge temperatures of HFC32/HFC152a mixture are increased up to $15.4^{\circ}C$ as compared to that of HCFC22. The amount of charge for HFC32/HFC152 mixture decrease up to 27% as compared to that of HCFC22. Overall, HFC32/ HFC152a mixture is an excellent long term candidate to replace HCFC22 in water-source heat pumps.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.2
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• pp.177-186
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• 1996

The characteristics of the flow of pure HFC refrigerants(R32, R125, and R134a) and their mixtures through capillary tubes were investigated experimentally. Two capillary tubes with 1.2mm and 1.6mm inner diameter and 1.5m length were adopted as test sections. Mass flow rates and temperatures and pressures were measured for several condensing temperatures and degrees of subcooling at capillary tube inlet. The effects of the condensing temperature, inner diameter of capillary tube, and subcooling on the mass flow rate of refrigerants were discussed, and the mass flow rates of HFC refrigerants were compared with that of R22. The pressure and temperature distributions along the capillary tube compared with that of R22. The pressure and temperature distributions along the capillary tube show that there is a metastable equilibrium state in the flow through the tube. Underpressure for vaporization increases as refrigerant mass flux increases and inlet subcooling decreases. Empirical correlation was suggested to predict underpressure for vaporization of the HFC refrigerants.