• Analytical Science and Technology
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• v.24 no.3
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• pp.168-172
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• 2011

The iron frame of building could be collapsed or bent at $500^{\circ}C$. Therefore the fire-resistant paint should be applied for safety. This study performed the comparative analysis to show the characteristics of fireresistant paint. And then 12 products of fire resistant paint and 6 products of paints were used as samples. And the samples were analyzed by TGA (Thermogravimetric Analyzer) as analyzer for measuring the variation of weight on temper of weight by heating. When TGA analyzer could measure the variatiature, and FT-IR was measured for analyze gas components on variation on of weight by heating on 12 products of fire resistance, the samples showed to decrease 40% of weight to $800^{\circ}C$, and because paints had 50% to 40% of loss weight, it showed to be equal with loss weight of fire resistance paint on high temperature or was lower loss weight than it of fire resistance paints. However number 6 sample of fire resistance paints could show to decrease 20% of total weight on $800^{\circ}C$. And then in the case of FT-IR, fire resistance paints could show to have the high intensity of $CO_2$ spectrum as complete combustion. However paints could show to have the lower intensity of $CO_2$ spectrum, have the higher intensity of water spectrum. Therefore the TGA graph of result could be much different until $250^{\circ}C$. When it was burned, FT-IR spectrum could show to confirm the characteristics of fire resistance paints, and the characteristic could be confirmed on inorganic paint of fire resistance by weight loss of TGA.

• Fire Science and Engineering
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• v.28 no.5
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• pp.58-63
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• 2014

Fire-resistance paints are supposed to become intumescent and diminish heat transfer along the steel frames in case of a fire. If unsatisfactory fire-resistance paints which do not satisfy their standard specification are used, it may result in a severe disaster. Because satisfactory fire-resistance paints are hardly discriminated from the unsatisfactory ones by a simple visual inspection, more reliable and convenient onsite evaluation methods are necessary. Here we report the preliminary study result on the fire safety testing method for fire-resistance paints using an X-ray analysis method. It was found that the existence and quantity of effective constituents in fire-resistance paints can be detected by the X-ray analysis method. X-ray fluorescence (XRF) analyses showed that P and Cl elements are much more enriched in fire-resistance paints, compared to normal paints. X-ray diffraction (XRD) analyses showed that ammonium polyphosphate is present as the main crystalline material in fire-resistance paints, but absent in normal paints. The X-ray analysis method is expected to be used for the onsite inspection of fire-resistance paints with the upcoming availability of portable XRF and XRD instruments.

• Fire Science and Engineering
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• v.23 no.1
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• pp.40-47
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• 2009

Applying fire resistive coating to steel members is one of the general methods to secure fire resistance performance of steel members. And intumescent coating system is currently one of methods giving fire resistance to steel members. Intumescent coating system for fire resistance, however, has undesirable weaknesses that fire resistance performance of steel members is being deteriorated due to cracks and falling-offs of the coverings as time goes after completion of the coverings to the members. So it is necessary to understand changes of the durability and the fire resistance performance of intumescent coating system over a time elapse and to reflect such change properly into the building design and construction. This research is performed to present the test method of durability and the maintenance of intumescent coating system through theoretical investigation of the test method of durability and the guide of maintenance & management of intumescent coating system of several countries, including the Britain, United States, Japan.

• Fire Science and Engineering
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• v.30 no.1
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• pp.31-36
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• 2016

This study investigates the characteristics of thermal decomposition of an epoxy-based intumescent paint using thermogravimetric analysis (TGA) and numerical simulation. A mathematical and numerical model is introduced to describe mass loss profiles of the epoxy-based intumescent coating induced by the thermal decomposition process. The decomposition scheme covers a range of complexity by employing simplified 4-step sequential reactions to describe the simultaneous thermal decomposition processes. The reaction rates are expressed by the Arrhenius law, and reaction parameters are optimized to fit the degradation behavior seen during thermogravimetric (TG) experiments. The experimental results show a major 2-step degradation under nitrogen and a 3-step degradation in an air environment. The experiment also shows that oxygen takes part in the stabilization of the intumescent coating between 200 and $500^{\circ}C$. The simulation results show that the proposed model effectively predicts the experimental mass loss as a function of time except for temperatures above $800^{\circ}C$, which were intentionally not included in the model. The maximum error in the simulation was less than 3%.

• Fire Science and Engineering
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• v.31 no.4
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• pp.1-6
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• 2017

A fire resistance certification needs to be obtained before fire protection paint can be used in Korea. In the case of paint, the tests for certification are fire, gas hazard and bond strength. According to the hazard test standard of combustion gas, 16 mice are sacrificed every test. Therefore, there are ethical problems for the experimenter and legal problems for the laboratory. Accordingly, many alternatives are being assessed, such as combustion gas analysis, but they have not replaced animal testing yet. With gas hazard testing, the exhaust gas temperature can be measured. The property of the initial reaction of a specific fire paint can be characterized by this temperature. The purpose of this study was to consider the improvement point for a gas hazard test through comparative analysis of the exhaust temperature and the time of death of the mice.

• Fire Protection Technology
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• s.41
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• pp.21-31
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• 2006

• Fire Protection Technology
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• s.42
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• pp.6-16
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• 2007

• Fire Protection Technology
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• s.26
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• pp.43-50
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• 1999

• Fire Protection Technology
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• s.39
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• pp.38-46
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• 2005

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.11a
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• pp.63-64
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• 2012

Recently, Fire-proof performance of buildings becomes important to ensure safety. As a result, fire-proof paint is required for 3 hours. However, Experiments are only performed by standard KS F 2271 for estimation of fire-proof paint. Because there is no domestic estimation standard for performance of fire-proof paint as well. So estimation standard of fire-proof paint is needed to guarantee their performance for establishing quality system and to assure same performance for safety of people in the building from unpredicted fire accident. Owing to these reasons, we studied comparative estimation for quality performance of two kinds of fire-proof paint and bond performance.