• Title/Summary/Keyword: 납 도포

Search Result 10, Processing Time 0.029 seconds

Adsorption Characteristics Evaluation of Natural Zeolite for Heavy-metal Contaminated Material Remediation (중금속 오염물질 정화를 위한 천연제올라이트의 흡착특성)

  • Shin, Eun-Chul;Park, Jeong-Jun;Jeong, Cheol-Gyu;Kim, Sung-Hwan
    • Journal of the Korean Geosynthetics Society
    • /
    • v.13 no.2
    • /
    • pp.59-67
    • /
    • 2014
  • The amount of the contaminants that can be adsorbed on the drain was evaluated for the effective remediation of the contaminated soil, and the contaminants adsorptivity of the drain was evaluated by comparing the isothermal adsorption model after carrying out the contaminants adsorption test of the reactants coated on the surface of the drain. The reactant used in the experiment is a natural zeolite, and the contaminants are copper, lead and cadmium. The results that Freundlich and Langmuir adsorption isotherm model are compared to the adsorption amount according to the change of the initial concentration by the contaminants. As a result of the component analysis, because Si, Al and O are contained approximately 28%, 11% and 48%, respectively, it is identified that the material coated on the surface of the drain is the component of the zeolite which is the reactant for the adsorption of the heavy-metal (Cu, Pb, Cd) contaminants. The heavy-metal adsorption kinetic of the zeolite which is the reactant was decreased in order of lead, copper and cadmium. The important factor of the performance evaluation of the adsorbent is the reaction rate, and if zeolite is used as the reactant in the relationship between the maximum amount of adsorption and reaction rate, it can be utilized as the design factor that determine the removal order of the complex heavy-metal. In other words, because the maximum adsorption quantity of lead is smaller compared to copper but the reaction rate is relatively fast, it can be primarily removed, and copper can be removed after removing the lead. It was analyzed that Cadmium can be finally removed after that other heavy-metal is removed.

The Influence of the Commercial Flame Retardant to the Physical and Chemical Properties of Dancheong Pigments (시판용 방염제 도포에 의한 단청안료의 물리화학적 변화 연구)

  • Lee, Han Hyoung;Kim, Jin Gyu;Lee, Hwa Soo;Lee, Ha Rim;Chung, Yong Jae;Kim, Do Rae;Han, Gyu Seong
    • Journal of Conservation Science
    • /
    • v.32 no.2
    • /
    • pp.249-259
    • /
    • 2016
  • Effect of the flame retardants on Dancheong is studied in the present work. Two kinds of flame retardants were applied on Dancheong specimens and compared with control groups on which distilled water was applied instead of the flame retardants. The flame retardants enhanced the hygroscopic property of the surface of Dancheong. Furthermore, the added flame retardants reacted with oyster shell white($CaCO_3$) and lead red($Pb_3O_4$), producing new chemical compounds like Calcium phosphate tribasic and Lead Phosphates which make the painted layer of Dancheong dissolving and whitening over certain period of time. When applied in excessive amount and exposed in repetitive wet and dry condition, especially, they aggravate the surface problems significantly. These results will provide a good reference on the study of the discoloring/whitening effect of Dancheong layers at many traditional wooden building in Korea.

A Fuzzy Logic Decision-Making for Vision-Based Inspection system (비전기반 검사시스템에서의 퍼지로직을 이용한 정상-불량 판단)

  • Choi Kyung-Jin;Lee Young-Hyun;Park Chong-Kug
    • Proceedings of the Korean Institute of Intelligent Systems Conference
    • /
    • 2005.11a
    • /
    • pp.463-466
    • /
    • 2005
  • 본 논문은 퍼지로직을 이용하여 메탈스텐실의 홀의 정상-불량 판단을 수행한다. 메탈스텐실 은 PCB의 SMD의 패드 위에 납을 도포하기 위해 사용되는 것으로, 레이저를 이용하여 패드모양과 동일하게 홀을 생성한다. 가공 시 발생하는 불량은 레이저 출력의 약화로 홀이 정상적으로 가공되지 않는 것이다. 검사를 위해 비전시스템을 이용하여 메탈스텐실에 대한 카메라이미지를 획득하고, 기준이미지는 메탈스텐실을 제조하기 위해 사용되는 거버 파일을 이용하여 생성한다. 퍼지로직의 입력변수는 각 이미지에서의 검사대상 홀의 위치오차와 크기비율이고, 출력변수는 홀의 정상판단율이다. 홀의 위치와 크기는 두 이미지에 대해 영상처리를 수행하여 계산한다. 퍼지규칙은 작업자의 판단 규칙을 적용하여 작성한다. 4종류의 메탈스텐실에 대해 정상-불량 판단을 위해 고정된 임계치를 사용하였을 경우와 제안된 퍼지로직을 적용한 실험결과에 대해 설명한다.

  • PDF

Solder Paste Inspection of PCB using Laser Sensor (Laser 거리센서를 이용한 PCB에서의 납 도포상태검사)

  • O, Seung-Yong;Choe, Gyeong-Jin;Lee, Yong-Hyeon;Park, Jong-Guk
    • Proceedings of the KIEE Conference
    • /
    • 2003.11b
    • /
    • pp.291-294
    • /
    • 2003
  • In this paper, 2D and 3D inspection algorithm for printed solder on PCB is introduced. The aim of inspection is the detection of error such as rich solder poor solder and missing solder. For Inspection, laser distance sensor is used. For 2D inspection, laser image that is created by normalizing laser data between 0 and 255 are used. Reference Image is made using gerber file. Image processing algorithm is used for 2D inspection. By adding thickness of metal stencil to laser image, volume for solder can be calculated and 3D inspection is carried out.

  • PDF

Remediation Efficiency Evaluation of Heavy Metal Contaminated Soils by Reactive Material Covered Vertical Drains in Incheon (반응물질이 도포된 연직배수재를 활용한 인천지역의 중금속 오염토양 정화에 관한 연구)

  • Shin, Eun-Chul;Eo, Jae-Won;Kim, Ki-Sung
    • Journal of the Korean Geosynthetics Society
    • /
    • v.14 no.2
    • /
    • pp.45-55
    • /
    • 2015
  • In Incheon area, 1960s of economic development planning and heavy industry center of efforts industrial park and port facilities, It is industrial land reclamation by coastal landfill, these industrial park has the characteristics of Low permeability lipid is embedded in the silty sand that was dredged. In this study, To evaluate the heavy metal adsorption ability to filter of drains that have been developed as environmentally friendly materials by applying the effective zeolite to heavy metal adsorption for soil pollution purification suitable for geological characteristics of Incheon. soil pollution Survey data and Literature search, which is the current through the industry, the most problematic was set to Cadmium (Cd) and Copper(Cu), Lead (Pb). and Using the Numerical Analysis using the Visual Modflow, was presented the most efficient drains set interval and format.

Study on Coloring and Aging Pattern of Bongchae used for Conservation Treatment of Paper Cultural Properties (지류문화재의 보채에 쓰이는 봉채의 채색 및 열화 양상 연구)

  • Song, Jung Won;Kim, Myoung Nam;Lee, Jang Jon
    • Journal of Conservation Science
    • /
    • v.35 no.5
    • /
    • pp.416-429
    • /
    • 2019
  • Bongchae is primarily employed for toning, which is the last step in the conservation treatment of paper's cultural properties. The objective of this study is to identify the coloring patterns of four types of Bongchae(Bonram, Gamboge, Yeonji, and Daeja) and determine the associated color change patterns through accelerated aging experiments. By examining the coloring patterns, it is observed that Yeonji, Bonram, and Daeja are painted as particles, whereas Gamboge indicates a close state of coating. Results obtained from X-ray diffraction analysis of Bongchae indicate that the presence of quartz, calcite, and pyrophyllite can be equally detected in Bonram, Yeonji, and Daeja. Additionally, the presence of goethite is also detected in Daeja. Gamboge becomes discolored from yellow to orange color during wet thermal aging, and Gamboge and Yeonji become decolorized during UV irradiation aging. Hence, cultural properties of paper colored with Gamboge can be predicted to become discolored to orange color by alkalis and can be darkened by UV rays because the decolorization of Gamboge and Yeonji occurs preferentially.

비증착 방법에 의한 사용후 핵연료의 EPMA 분석

  • 정양홍;송웅섭;김도식;김희문
    • Proceedings of the Korean Radioactive Waste Society Conference
    • /
    • 2004.06a
    • /
    • pp.353-354
    • /
    • 2004
  • 사용후 핵연료의 조성을 분석하거나 또는 반사전자상과 2차 전자상 등으로 시료를 관찰하기 위해서는 핫셀(Hot cell)에 증착기(coater)를 설치하여 시료표면을 전도성 물질인 탄소 등으로 증착시켜야 한다. 그러나 원격조정기를(manipulator)를 이용하여 수행되는 핫셀에서의 증착작업은 사용후 핵연료 시험의 선진분석기술을 갖고 있는 원자력 선진국에서도 핫셀내에 설치되어 있는 증착기의 탄소봉을 교체하는 작업과 진공장치의 성능 유지가 까다로워 시료표면에 균질하게 전도성 물질을 증착시키는 작업에 많은 어려움을 겪고 있다. 본 연구는 통상적으로 이용되는 증착기를 사용하지 않고 Silver Paint를 사용하여 사용후 핵연료를 분석할 수 있는 새로운 방법에 대한 연구를 수행하였다. 산화물 핵연료는 전기전도도가 매우 낮아($3{\times}10^{-1}~4{\times}10^{-8}/ohm{\cdot}cm$)입사된 전자의 이동이 원활하지 못해 일어나는 들뜸(Charging)현상이 발생한다. 그러나 Silver Paint 에 사용후 핵연료를 접착하면 모세관(capillary)현상에 의해 시료 주위와 핵연료의 결정립계로 Silver가 스며들어 입사된 전자의 이동이 원활해져 전도성이 극히 낮은 시료의 분석이 가능하게 된다. 본 시험에 사용된 EPMA는 (Electron Probe Micro Analyzer, SX-50R, CAMECA, Paris, France) 고 방사능을 띤 조사 핵연료의 시험을 수행할 수 있도록 기기의 적절한 부위에 납과 텅스텐으로 차폐되어 시편의 방사능 세기가 $3{\times}10^{10}Bq$까지 시험 가능한 기기이다. 그림 1은 JAERI 에 설치 운영중인 증착기 설비 사진이다. 그림에서 핫셀에 설치된 증착기의 진공을 유지하기 위해 핫셀 벽을 관통하여 증착기 본체까지 연결된 배출관의 형상과 복잡한 주변장치들을 볼 수 있다. 그림 2는 비조사 핵연료 시편을 Silver Pain떼 접착한 사진이다. 그림은 시료주위와 시료 표면까지 Silver Paint가 도포된 모습을 보여주고 있다. 상용발전소에서 연소도가 50,000 Mwd/tU인 사용후 핵연료를 상기와 같은 방법으로 만든 시편의 표면을 관찰한 사진을 그림 3~8에 나타내었다. 그림 3은 핵연료 중앙부위의 결정립을 나타낸 그림이다. Silver Paint만으로 접착한 시료의 표면관찰 및 정량분석이 그림에서 보듯이 가능함을 확인하였다. 그림 4는 사용후 핵연료시료를 중앙부위에서 가장자리까지를 다섯 부위로 나누어 그 중 중앙부위(1/5) 지점의 입계 및 형상을 관찰한 사진이다. 결정립의 크기가 다른 부위보다 상대적으로 크고, 결정립에 생성된 기공이 발달되어 있음을 볼 수 있다. 그림 5와 6과 7은 중심부위와 rim부위 사이 지점을 관찰한 사진으로서 결정립과 기공의 분포가 비슷한 형상을 나타내고 있음을 관찰할 수 있었다. 그림 8은 rim 부위 사진으로 전형적인 rim 영역 현상을 관찰할 수 있었다. 표 1은 그림 2와 같이 비조사 산화물 핵연료를 Silver Paint로 접착한 시편을 정량 분석한 결과이다. 시편의 조성은 33.6 at% U, 66.4 at% O의 결과를 얻었다. 산화물 핵연료의 표면 관찰 및 정량 분석 시험시 시편 표면을 전도성 물질로 증착시키지 않고, Silver Paint 에 시편을 접착하는 방법으로도 만족한 시험 결과를 얻을 수 있었다.

  • PDF

Characteristics of Concrete Sidewalk Block Manufactured Using Stone Powder Sludge and photocatalytic agent (석분슬러지와 광촉매제를 사용한 콘크리트 보도블록의 특성)

  • Jung, Yong-Wook;Lee, Seung-Han;Choi, Jong-Oh
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.16 no.6
    • /
    • pp.4237-4244
    • /
    • 2015
  • This study examined the efflorescence characteristics of a concrete sidewalk block manufactured using recycled stone powder sludge and photocatalytic generated by surface polishing during the sidewalk block manufacturing process. The study evaluated the characteristics of the sidewalk block in terms of its quality, based on the amount of stone powder sludge used, efflorescence, and further based on the mixing ratio and number of applications of the photocatalytic. The experimental results indicated that heavy metals such as lead, hexavalent chrome, cadmium, and mercury were not present in the concrete sidewalk block, thereby confirming the effectiveness of the recycled stone powder sludge. The optimum mixing ratio of used in the concrete sidewalk block (for satisfying KS standard values such as water absorption ratio and flexural strength) was found to be 20%. The concrete sidewalk block incorporating the stone powder sludge and photocatalytic exhibited a water absorption ratio of 5.4% and flexural strength of 5.2 MPa, thereby satisfying the quality standards. Additionally, when the photocatalytic was used, efflorescence did not occur even at the low temperature of $-5^{\circ}C$, and the by the sidewalk block was found to be 70% under normal conditions and 68% when subjected to an accelerated weathering test.

The Microalgal Attachment and its Growth on the Artificial Surfaces Immersed in Seawater: I. Attachment and Micro-succession (해수에 잠긴 인공기질 표면에서 미세조류의 부착과 성장: I. 부착 및 천이)

  • Shim, Jae-Hyung;Kang, Jung-Hoon;Cho, Byung-Cheol;Kim, Woong-Seo
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
    • /
    • v.3 no.4
    • /
    • pp.249-260
    • /
    • 1998
  • To understand the attachment of micro algae and their subsequent growths on artificial surfaces immersed in seawater, the relationship between attachment of diatoms on the immersed artificial substrates and species pool in the surrounding water was investigated. We used acryl slides for the study of diatom attachment and examined the surrounding water samples collected in Incheon Harbour from July 1995 to February 1997. Variations of species composition and abundances by exposure time in seawater were investigated during the early phase of biofilm formation on various substrates, e.g. glass, acryl, titanium, copper and antifouling paint-treated slides. Immigration rates of diatoms to acryl slides during spring and winter were significantly correlated with the abundance of benthic diatoms in surrounding water ($r^2$=0.78, p<0.01, n=42), suggesting that immigration rates were affected by variations of benthic diatom abundances in surrounding water. Immigration coefficient of monoraphid diatoms was 5 times higher than that of biraphid diatoms, but relative abundance of monoraphid diatoms was 3 times lower than that of biraphid diatoms on acryl slides in spring. In winter, immigration coefficient and relative abundance of centric diatoms were higher compared to other raphe forms. These results suggest that the attachment of diatoms seems to be caused by the abundance and immigration coefficients of benthic diatoms in surrounding water. Pennate diatoms predominantly attached to all artificial surfaces throughout all experimental periods. Interestingly, centric diatoms predominantly attached to all artificial surfaces in winter. Hantzschia virgata, Licmophora abbreviata and Melosira nummuloides appeared dominantly on antifouling paint-treated slides, probably being tolerant of the antifouling paint. During incubations, the abundance of attached diatoms increased exponentially on glass, titanium and acryl slides with exposure time. The maximum abundance was highest on glass slide, followed by acryl, titanium, copper and antifouling paint-treated slides. The growth rates of attached diatom community on all artificial surfaces were higher at temperature of $24-25^{\circ}C$ than that of $2-3^{\circ}C$. The growth rate of attached diatoms on glass slide was generally higher compared to other slides during the study period. Dominant morphotypes of observed species with exposure time in seawater were prostrate form Amphora coffeaeformis, fan shape Synedra tabulata, stalk type Licmophora paradoxa and chain type M. nummuloides. A micro-succession in the attached microalgal community was observed. The composition of dominant species seems to be the result of species-specific response to gradually limited space with development of microalgal film.

  • PDF