• Proceedings of the Korean Environmental Sciences Society Conference
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• 1998.04a
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• pp.102-104
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• 1998

• Proceedings of the Korean Ceranic Society Conference
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• 2000.10a
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• pp.27.1-27
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• 2000

• Journal of the Mineralogical Society of Korea
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• v.20 no.1 s.51
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• pp.61-70
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• 2007

• Proceedings of the KSEEG Conference
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• 1999.04a
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• pp.36-38
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• 1999

• Journal of the Mineralogical Society of Korea
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• v.7 no.1
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• pp.1-13
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• 1994

The industrial minerals play an important role in mining sector. More than 70 % of total mineral production come from industrial mineral sector. This paper reviews geological occurrence of kaolin, pyrophyllite and limestone, and current demand-supply status of major industrial minerals in the Republic of Korea. The kaolin is mainly distributed in the Kyeongsang province, formed by deep weathering of Precambrian anorthosite on mountainside of gentle slope. The pyrophyllite mainly occurs in the Kyeongsang and Chulla provinces, formed by hydrothermal alteration of late Cretaceous andesitic and rhyolitic rocks. Pyrophyllite comprises massive and lenticular bodies and contains minor amounts of kaolin, alunite and pyrite, in some places andalusite and illite. The limestone(Great Limestone Series of Cambrian age) is distributed widely in the Kwangwon and Chungcheong provinces. The limestone bodies are approzimately 70 km long and 3 km wide, elongated NE-ward, and show high grade of CaO content. In 1992, the self-sufficiency ratio of 44 nonfuel (metallic and non-metallic) minerals was no more than 30 percent. However, the ratio of 27 industrial minerals (non-metallic) represents high value of about 72 percent. The export/productjon ratio of the industrial minerals shows decreasing patterns from 12.2 % in 1983 to 4.2 % in 1992. Also the import/production ratio shows rapidly decreasing pattern from 84 % in 1983 to 38.2 % in 1992.

• Journal of the Mineralogical Society of Korea
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• v.22 no.2
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• pp.163-176
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• 2009

The pyrophyllite deposits located in Jinhae area have been studied through field observations and laboratory works including the X-ray diffraction (XRD), X-ray fluorescence (XRF), Electron probe microanalyzer (EPMA) and Inductively Coupled Plasma (ICP). The pyrophyllite deposits consist of mainly illite, dickite, pyrophyllite, diaspore, chlorite, pyrite and copiapite. According to the mineral assemblages, geological occurrences and alteration modes, the altered rocks can be classified into four types: Type A; quartz with silicifictaion, Type B; quartz + illite with illitization, Type C; quartz + dickite + illite with kaolin alteration, Type D; pyrophyllite + illite + dickite + diaspore with pyrophyllite alteraion. Rocks in Type A, which is generated by silicifictaion, have high $SiO_2$ contents more than 90 wt% and distinctive equigranular textures with microcrtstalline quartz. The pyrophyllites from the study area belong to 2M polytype. The host rocks of the pyrophyllite ore in this mine are rhyolitic rock, andecitic tuff and volcanic breccia. The alteration products seem to be controlled by the different lithology of the host rocks. The hydrothermal solution formed the deposits would be inferred to the acidic and have relatively high ionic activity of hydrogen and silica judging from alteration mineral assemblage. Pyrophyllite alteraion zone is generated by highest temperature condition of all alteration zone.

• Journal of the Mineralogical Society of Korea
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• v.20 no.2 s.52
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• pp.135-145
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• 2007

The needs for the ultra fine particles have been increased in preparation field of raw powders such as fine ceramics and high functional products. In this study, a series of wet grinding experiments were carried out on inorganic powders such as calcite, pyrophyllite and talc by a stirred ball mill. The particle size distribution of ground products of each test material fur a given grinding time was found to be expressed by the grinding rate (selection function) which was obtained from the grinding kinetics analysis. The median diameter decreased from 6.49 to $0.47{\mu}m$ in calcite, and decreased from 3.91 to $1.14{\mu}m$ in pyrophyllite. However, in talc, median diameter was decreased a little bit from 10.30 to $6.67{\mu}m$. The grinding rate changing on calcite and pyriphyllite were similar at the same conditions. However, in the case of talc, it was observed that the grinding rate was not increased compared to other samples.

• Journal of the Mineralogical Society of Korea
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• v.28 no.3
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• pp.265-277
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• 2015

Hydrothermal alteration patterns and environment are studied by mineral assemblages and chemical analyses of surface and core samples from Miryang pyrophyllite deposit. The alteration zones of this deposit can be divided into three zones on the basis of mineral assemblage; advanced argillic, phyllic, and propylitic zone. Advanced argillic zone mainly consists of pyrophyllite-dickite (-quartz) and corresponds to principal mining ore. The common mineral assemblage of phyllic zone and propylitic zone are sericite-quartz-dickite and chlorite-quartz, respectively. Horizontal and vertical alteration patterns and major element geochemistry indicate that pyrophyllite ores have been formed several times by hydrothermal alteration. And it also suggests that the huge ore bodies may be extended from the deeper part of recent quarries to the south-southeastern direction. The paragenesis of ore minerals and polytype (2M) suggest that ore deposit was formed at about $300-350^{\circ}C$.

• Journal of the Korean Ceramic Society
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• v.28 no.9
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• pp.730-738
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• 1991

Machinable ceramics containing ${\beta}$-spodumene crystal was fabricated by melting method using domestic pyrophyllite. Raw materials were batched by molar ratio of 8:2, 7:3, 6:4, and 5:5 for fluorophlogopite and ${\beta}$-spodumene. These compounds were melted at 1450$^{\circ}C$ for 1 hr and formed in graphite mold. Base glasses were heat-treated according to 2-step schedule which was determined from DTA, XRD analysis and SEM observation. Fabricated machinable ceramics have excellent themal, chemical properties and machinability.

• Journal of the Korean Ceramic Society
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• v.21 no.1
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• pp.5-10
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• 1984

$eta$-Sialon synthesis was investigated via the simulataneous reduction and nitriding of Wando pyrophyllite. When Wando pyrophyllite-graphite-$Si_3N_4$ seed mixture was heated at 135$0^{\circ}C$ for as long as 10 hours in 80% $N_2$-20%$H_2$ atomsphere $eta$-$Si_3N_4$ solid solution was mainly formed together with a small amount of $\alpha$-$Si_3N_4$ The value z of the forming $Si_{6-x}Al_2O_2N{8-z}$ was decreased with heating time.