• Journal of the Korean Ceramic Society
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• v.37 no.12
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• pp.1229-1233
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• 2000

(1-x)NdAlO$_3$-xCaTiO$_3$세라믹스의 결정구조와 마이크로파 유전특성을 조사하였다. 시편의 결정구조는 조성에 따라서 변화하였는데, 그 결정구조는 x$\leq$0.1일 때는 능면정(rhombohedral) 구조를, 0.3$\leq$x$\leq$0.7에서는 정방정 (tetragonal) 구조를 그리고, x$\geq$0.7일 때 다시 사방정 (orthorhombic) 구조로 바뀌었다. 또한 (1-x)NdAlO$_3$-xCaTiO$_3$세라믹스에서 이차상의 두 종류가 발견되었다. x$\leq$0.5인 시편에서는 Nd$_4$Al$_2$O$_{9}$상이, x$\geq$0.7인 시편에서는 Al-rich상이 발견되었다. x가 증가함에 따라, 유전율 ($\varepsilon$$_{r}$)과 공진주파수의 온도계수 ($ au$$_{f}$ )가 증가하였고, Q$\times$f 값은 x의 증가에 따라 증가하며, x=0.5일 때 최대값을 얻었다. 그리고 0.3NdAlO$_3$-0.7CaTiO$_3$에서 Q$\times$f=46,000, $\varepsilon$$_{r}$=45 그리고 $\tau$$_{f}$ =-1.5 ppm/$^{\circ}C$의 우수한 마이크로파 유전특성을 얻을 수 있었다.

• Applied Microscopy
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• v.32 no.2
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• pp.157-162
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• 2002

Microstructural investigations of $(Na_{1/2}Pr_{1/2})TiO_3$ (NPT) complex perovskite compounds were carried out using X-ray diffractometry and transmission electron microscopy. NPT had not 1:1 chemical ordering of Asite cations but had the antiphase and inphase tilting of oxygen octahedron and the antiparallel shift of cations. Both the antiphase boundaries and the ferroelastic domains were not present in the microstructure. Unidentified second phase was found in the microstructure. The measured dielectric properties were ${\varepsilon}_r=99.6,\;Q\;{\Large f}_o=1124\;GHz,\;{\tau}_{f}=-233.64ppm/^{\circ}C$.

• Proceedings of the Korea Crystallographic Association Conference
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• 2003.05a
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• pp.25-25
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• 2003

BaTi₄O/sub 9/계 세라믹스에 저온 소결 조제로 첨가된 lithium-borosilicate계 유리 프리트의 첨가에 따른 상분해 현상을 XRD, TEM에 의하여 분석하였다. 유리 프리트의 첨가가 없는 BaTi₄O/sub 9/계 세라믹스는 첨가량과 열처리 온도에 관계없이 BaTi₄O/sub 9/상과 소량의 TiO₂상만이 관찰되었으나 저온 소결 조제로 사용된 유리 프리트의 첨가량이 증가할수록 BaTi₄O/sub 9/계 세라믹스는 BaTi₄O/sub 9/상 보다 Ti-rich상인 Ba₂Ti/sub 9/O/sub 20/상, BaTi/sub 5/O/sub 11/상, 또는 BaTi/sub 5/O/sub 11/상과 Ba₄Ti₃O/sub 30/상으로 공존하며 분해되는 것을 관찰하였다. 공존하며 분해되는 것을 관찰하였다. 유리 프리트가 10 wt% 첨가시 600℃ 까지는 BaTi₄O/sub 9/상과 TiO₂상으로 존재하였으나 700℃ 전후에서 BaTi/sub 5/O/sub 11/상과 Ba₄Ti/sub 13/O/sub 30/상으로 분해되기 시작하여 875℃에서는 BaTi₄O/sub 9/상이 완전히 분해되어 BaTi/sub 5/O/sub 11/상이 주상으로 Ba₄Ti/sub 13/O/sub 30/상은 이차상으로 존재하는 것을 확인하였다. 또한, 열처리 온도가 증가할수록 Ba₄Ti/sub 13/O/sub 30/상이 상대적으로 감소하고 있는 것도 관찰할 수 있었다.

• Journal of the Korean institute of surface engineering
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• v.49 no.6
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• pp.595-603
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• 2016

Rare-earth zirconates, including lanthanum zirconate and gadolinium zirconate, have been investigated as ones of the most promising candidates for next-generation thermal barrier coating (TBC) materials due to their excellent properties such as low thermal conductivity, chemical stability at high temperature and so on. In this study, TBCs with three compositions, in the $La_2O_3-Gd_2O_3-ZrO_2$ system with reduced rare-earth contents from $RE_2Zr_2O_7$ compositions, were fabricated by using suspension plasma spray with different suspension preparation methods. The phase formation, microstructure, and thermal properties of TBCs were examined. In particular, each coating exhibited single fluorite phase and a dense, vertically-separated microstructure. The potential of coatings with rare-earth zirconates for TBC applications was also discussed.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.9
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• pp.766-771
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• 2009

Lead-free $0.94(Na_{0.5}K_{0.5})NbO_3$-0.06Ba$(Ti_{0.9}Sn_{0.1})O_3$ [0.94NKN-0.06BTS] ceramics doped with 1 mol% $MnO_2$ were synthesized by a conventional solid state method. The phase transitional behavior and piezoelectric properties of the ceramics sintered at various temperatures were investigated. The 0.94NKN-0.06BTS ceramics sintered at $1050^{\circ}C$, having morphotropic phase boundary of orthorhombic and tetragonal phases, exhibited a microstructure with abnormal grain growth. A diffused phase transition behavior for all the specimens was verified as high degree of diffuseness (${\gamma}$) values from 1.45 to 1.79. A high piezoelectric constant of $d_{33}=256$ pC/N and a satisfactory electromechanical coupling factor of $k_p=42%$ were obtained for the relatively dense 0.94NKN-0.06BTS ceramics sintered at $1050^{\circ}C$.

• Journal of architectural history
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• v.19 no.6
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• pp.121-135
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• 2010

This study was to analyze the architectural characteristics and facade construction of brick masonry auditorium through the Auditorium of Namsan Primary School in 1936. The results of this study were described separately as follows. 1. The auditorium is located away from the school buildings, and its plane is a chamber of rectangle type with an entrance installed on each of the four sides. 2. The external appearance is Renaissance eclectic style, laid red bricks on the lower wall of the window and having a mansard roof. The front and the rear are symmetric with respect to the projected wall at the center. 3. As to the structure of the building, a concrete lower wall was built on the concrete continuous footing, and the brick wall was constructed on the lower wall. The roof is queen post roof truss, and the wall girders were installed on the brick wall. 4. The auditorium has had a number of repairing and maintenance works, which changed the roof and windows outside and the floor, walls, ceiling, etc. inside. 5. The decorative elements of external appearance include lower wall, brick wall, entrances, windows, roof, and dormer windows. The brick wall gives verticality and solidity to the surface of the wall, and the lower wall and wall girders are connected like a cornice of the wall. The surface of the mansard roof and dormer windows express a stable vertically oriented shape.

• The Korean Journal of Soil Zoology
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• v.2 no.2
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• pp.83-91
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• 1997

One year study with litter bags(mesh size - 0.4mm, 0.8mm, 1.7mm and 5.0mm) was carried out to investigate the soil invertebrate community in the process of leaf decomposition in Namsan and Kwangreung deciduous forests, which were considered to be under different degrees of environmental selective pressure. Soil animals collected from litter bags were classified into the class of order or higher taxa. Acari and Collembola were major groups: Acari and Collembola were about 60% and 30% of total soil animals in their numbers, respectively. Among minor groups, Dipteria, Araneae, Diplopoda, Coleoptera and Chilopoda were comparatively dominant. In Namsan forest which was considered to be under higher environmental selective pressure than Kwangreung, the densities of Acari and Collembola were somewhat higher than in Kwangreung, although there was no statistically significant difference between two sites. The densities of Chilopoda, Enchytraeidae and Nematoda were much higher in Namsan than in Kwangreung but Diplopoda and Symphyla were much more in Kwangreung. It was expected that those groups could be used as bioindicators. The densities of Acari and Collembola were very low until March and then showed the peak in May. But they decreased slowly until November. There was no significant difference among the mesh sized of litter bags in the densities of Acari and Collembola but other groups of soil invertebrates seemed to be prevented from immigrating into the litter bag of mesh size 0.4mm. Decomposition rate of litter in the litter bag was low in early stage of decomposition. The % residual mass over initial mass at 8 months after litter bag introduction in the field was over 80%. Thereafter, % residual mass decreased more fast and was about 60% at 1 year after bag introduction. There was little evidence for the effects of soil invertebrates upon the litter decomposition in the period of this study. And there was no significant difference between Namsan and Kwangreung or among mesh sizes of litter bags in the decomposition rate.

• Korean Journal of Materials Research
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• v.24 no.7
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• pp.351-356
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• 2014

A spherical $Sr_4Al_{14}O_{25}:Eu^{2+}$ phosphor for use in white-light-emitting diodes was synthesized using a liquid-state reaction with two precipitation stages. For the formation of phosphor from a precursor, the calcination temperature was $1,100^{\circ}C$. The particle morphology of the phosphor was changed by controlling the processing conditions. The synthesized phosphor particles were spherical with a narrow size-distribution and had mono-dispersity. Upon excitation at 395 nm, the phosphor exhibited an emission band centered at 497 nm, corresponding to the $4f^65d{\rightarrow}4f^7$ electronic transitions of $Eu^{2+}$. The critical quenching-concentration of $Eu^{2+}$ in the synthesized $Sr_4Al_{14}O_{25}:Eu^{2+}$ phosphor was 5 mol%. A phosphor-converted LED was fabricated by the combination of the optimized spherical phosphor and a near-UV 390 nm LED chip. When this pc-LED was operated under various forward-bias currents at room temperature, the pc-LED exhibited a bright blue-green emission band, and high color-stability against changes in input power. Accordingly, the prepared spherical phosphor appears to be an excellent candidate for white LED applications.

• The Korean Journal of Ecology
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• v.21 no.5_3
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• pp.633-648
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• 1998

The forest vegetation of Mt. Nam Nature Park was investigated according to the phytosociological method. The vegetation in this study area was classified into 5 communities Quercus mongolica (Acer pseudo-sieboldianum subcommunity, Prunus sargentii subcommunity), P. sargentii, Pinus densiflora (Q. mongolica subcommunity, Stephanandra incisa subcommunity) and 5 afforestations Robinia pseudo-acacia, Populus tomentoglandulosa, P. koraiensis, P. rigida, Metasequoia glyptostroboides. Generally, were P. densiflora forest at the Southern slope and Q. mongolica forest at Northern slope dominant species from the top zone standing in Namsan tower. The dominance sequences on each stratum determined by the R-NCD (Relative net Contribution Degree) showed Q. mongolica and P. densiflora in tree-1 layer, Styrax japonica and Corbus alnifolia in tree-2 layer, S. incisa, S. japonica and rhododendron schlipenbachii in shrub layer, and Oplismenus undulatifolius, Eupatorium rugosum, Parthenocissus tricuspidata and Disporum smilacinum in herb layer. The soil was analyzed to investigate the soil conditions and fertility. The pHs of soil collected in each sites appeared strongly acidic with the range of 4.34 to 5.01 each community and especially, was the lowest value 4.34 in P. rigida afforestation. And Q. mongolica-P. sargentii subcommunity was distributed at the area with relative mesic conditions and high organic matters. Nitrogen was highest at P. sargentii community, phosphate at P. densiflora-S. incisa subcommunity, calcium, potasium and magnesium of exchangeble cation at R. pseudo-acacia afforestation. Especially, the level of calcium in R. pseudo-acacia afforestation, P. koraiensis afforestation and P. densiflora community was shown the highest (0.38-1.48 mg/100g) compared to other communities, because of the influence of lime fertilization used to improve acidic soil.

• The Korean Journal of Ecology
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• v.21 no.5_3
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• pp.695-702
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• 1998

This study was carried out to investigate to determine seasonal variation of dehydrogenase activity, phosphatase activity, adenosine tri-phosphate content and some physicochemical properties, such as soil pH, moisture content, organic matter and several heavy metal concentrations from Apr. 1997 to jan. 1998 in Pinus densiflora and Quercus mongolica forest in Mt. Nam, to explain a relationship between enzyme activity and the soil factors. There were ranges of 4.03-4.65 in soil pH, 18.65-51.09% in moisture content and 6.69-95.95% in orgainc matter. The organic matter content decreased with soil horizon, showing the higher values in Q. mongolica forest. In comparison to the results of Kawngneung site as control area, there were slightly differences due to a development level of forest ecosystem and microbial degradation of organic matter. The heavy metal concentrations showed 32.50-75.55 ${\mu}g/g$ in Cu, 69.33-134.84 ${\mu}g/g$ in Zn, 57.02-150.32 ${\mu}g/g$ in Pb, and 0.36-1.00 ${\mu}g/g$ in Mt. Nam. These values are higher than in Kwangneung site because of long-term exposure to air pollutants from central city. On the other hand, ATP contents in Mt. Nam were lower than in Kawngneung site in relation to soil organic matter, moisture content and relatively high heavy metal concentrations. ATP contents per soil weight was largest in F+H layer and in spring time of other seasons. Dehydrogenase activity as an index of soil microbial activity had a ranges of 170.67-1,221.66 ${\mu}g$ TPF/g that showed lower values than in Kawngneung site. However, phophatase activity had a contray tendency due to P fertilization for a continuous management. Those values increased through spring to a maximum in the summer and fall in autumn. This is basically caused by metabolic state of soil on the biological activity and several and several factors, such as aeration, soil temperature, vegetation and microflora.