• Title/Summary/Keyword: 난연화

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A Study on the Effects of Flame Retardants in Unsaturated Isophthalic Acid Polyester Resin (불포화 이소프탈산 폴리에스터 수지의 난연제 첨가 효과 연구)

  • 최원종
    • Fire Science and Engineering
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    • v.12 no.4
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    • pp.41-49
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    • 1998
  • In this study, the thermal improvement of an isophthalic acid polyester resin by the incorporation of flame retardants has been investigated. Aluminium hydroxide, antimony oxide and alumina powder were used to formulate the flame retardant systems. The improvement of an isophthalic resin by incorporating aluminium hydroxide is dramatic(burning rate and smoke emission are reduced), although the mechanical property is decreased significantly. The addition of small amount(2.5 phr) of antimony oxide produces high char yield(31%) which acts as a protective layer on the surface of the resin.

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Assessment of Flame Retardancy for Acrylonitrile Butadiene Styrene Containing Metal Powder and Flame Retardant (금속분말-난연제 함유 ABS의 난연 특성 평가)

  • Song, Young-Ho;Chung, Kook-Sam
    • Fire Science and Engineering
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    • v.21 no.2 s.66
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    • pp.30-35
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    • 2007
  • The flame retardancies by the addition of metal powder and flame retardant were evaluated to present as the fundamental data to decrease the fire hazard of polymers and life losses by suffocation and poisoning. For this study, the experiments of flame retardancy were conducted as follows : weight loss rate using thermogravimetric analysis, the measurement of the limiting oxygen index(LOI) and char yield. And smoke mass concentration and CO yield were measured. Acrylonitrile butadiene styrene containing metal powder and flame retardant reduced weight loss rate and increased LOI and char yield with the decreased smoke mass concentration and CO yield. It was found that the most effective complex was tricresyl phosphate-Mo complex.

A Study on Fire Prevention Capability Performance Evaluation of the Phosphate Flame Retardant Honeycomb Core (인계 난연 허니컴 코아의 방화성능평가에 관한 연구)

  • Moon, Sung-Woong;Lim, Kyung-Bum;Rie, Dong-Ho
    • Fire Science and Engineering
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    • v.24 no.3
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    • pp.72-77
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    • 2010
  • Honeycomb core structure with its excellent stiffness and strength is being utilized in many fields such as interior building material. Because it is inexpensive and renewable, honeycomb paper production is economically and environmentally helpful. However, the paper needs to be fireproofed because it is vulnerable to fire. In this study, we have undergone the performance evaluation process of the honeycomb paper which is widely used as interior material of a fire door and packing material. Four kinds of honeycomb (a honeycomb made of flame-resistant paper; a honeycomb attached with conventional flame-resistant film made in the laboratory; honeycomb impregnated with flame retardant; a honeycomb attached with flame-resistant film after impregnating fire retardant) were used in the study to compare the fire retardant performance. As a result, the honeycomb with impregnated flame retardant showed the highest performance. The flame-resistant film was effective in delaying the igniting time but had a negative effect on the rate of heat and smoke production.

A Study on Flame Retardant Treatment on Bamboo Nonwoven Fabric and Manufacturing of Sandwich Structure Composites (대나무 섬유의 난연화 및 샌드위치 구조 복합재료 제조연구)

  • Lee, Dong-Woo;Prabhakar, M.N.;Song, Jung-Il
    • Composites Research
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    • v.33 no.6
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    • pp.408-414
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    • 2020
  • The present engineering sector focused on the sandwich composites and almost covered all engineering fields because of decent mechanical properties with a lightweight structure. It mainly consists of high strength fiber skin and porous structure core like corrugated, honeycomb, balsa wood, and foams which is playing a pivotal role in weight reduction. Recently researchers attention grabbed by Natural fiber sandwich composites due to biodegradability, renewable, low-cost, and environmentally friendly. However special focus is highly needed towards the flammability behavior of natural fibers used as reinforcement for composites. Herein, for the first time, the flame retardant natural fiber sandwich composite was fabricated by using flame retardant treated bamboo fabric and vinyl ester via the VARTM process. The impact of flame retardant treated bamboo fabric on mechanical and flame retardant properties were studied. The results concluded that the fabricated bamboo sandwich composites show structurally lightweight with significant mechanical strength and feasibility with respect to the flame.

Synthesis of Cyclotriphosphazene Derivatives for Flame Retardants (Cyclotriphosphazene을 이용한 난연제의 합성)

  • Kim, Hae Young;Shin, Young Jae;Ji, Young Jon;Shin, Jae Sup
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.144-149
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    • 2006
  • Non-halogen flame retardants have been the focus of extensive research because of environmental problems. Hexakisp-henoxycyclotriphosphazene was synthesized in order to use as the flame retardant of ABS resin. And using bisphenol A, the polymers containing a cyclotriphosphazene structure were synthesized in order to also use as the flame retardant of ABS resin. All of the synthesized polymers themselves had the excellent flame retardancy. And as their molecular weight and crosslinking density were increased, the thermal stability was increased. But when the synthesized compounds were used as the flame retardant for ABS resin, the lower molecular weight compound in these compounds showed the better flame retardancy and the better physical properties of ABS resin.

A Study on the Fire Prevention Performance Evaluation of the Wood impregnated with flame retardant (난연제 함침 방법에 따른 목재의 난연성능 평가)

  • Moon, Sung-Woong;Lim, Kyung-Bum;Rie, Dong-Ho
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2011.04a
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    • pp.192-195
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    • 2011
  • 건축물의 밀집화로 인해 화재 확산으로 인한 피해를 막기 위한 연구는 꾸준히 진행되었다. 이에 방화구획이 도입 되었으며 이 중 방화문은 화염과 연기 전파를 차단하는 문의 역할을 한다. 본 연구에서는 목재 방화문에 사용되는 목재의 난연제 처리에 따른 난연 성능을 평가하였다. 실험 결과, $0.7kgf/cm^2$ 진공압력 내에서 30분간의 함침 처리를 통해 난연성능을 확보할 수 있는 것으로 나타났다.

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Influence of Fluoro-illite on Flame Retardant Property of Epoxy Complex (에폭시 복합체의 난연 특성에 미치는 불소화 일라이트의 영향)

  • Yu, Hye-Ryeon;Jeong, Eui-Gyung;Kim, Jin-Hoon;Lee, Young-Seak
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.47-51
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    • 2011
  • In this study, illite, an environmental friendly, low cost, and high aspect ratio additive, was used to improve flame retardant property of epoxy and it was fluorinated to enhance dispersion of hydrophilic illite in hydrophobic epoxy by introducing hydrophobic functional groups. Fluorination of illite enhanced illite dispersion ill epoxy solution before curing and that in the complex after curing. These enhanced dispersions were attributed to the increased affinity of illite to hydrophobic epoxy solution induced by fluorination of illite and the increased intercalation of epoxy polymer or exfoliation of illite by epoxy curing. Hence, limited oxygen index(LOI) of fluorinated illite/epoxy complex increased by 24%, compared to that of epoxy, suggesting that the preparation of fluorinated illite/epoxy complex increased their flame retardant properties.

난연성 Polyurethane/Vermiculite 복합성형체 제조 및 특성

  • 조명호;강영구
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2000.11a
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    • pp.113-117
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    • 2000
  • 경량 건축소재는 건축자재의 경량화, 고급화 및 다양화 등의 기능성 건축소재로의 역할을 요구하고 있으며 그 중 대표적인 것으로는 polyurethane foam이 있다 일반적인 플라스틱 foam의 경량 건축소재는 난연성에 대한 문제점과 첨가제에 의한 중량 증가, 화재 발생시 과다연기발생 등의 문제점이 있으며 저밀도 콘크리트 등의 무기소재는 flexibility가 떨어져 충격과 휨강도가 매우 낮은 단점을 가지고 있다.(중략)

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Effect of Flame Retardants on Flame Retardancy of Flexible Polyurethane Foam (난연제 종류에 따른 연질 폴리우레탄 폼의 난연 특성에 대한 연구)

  • Kwon, Ohdeok;Lee, Ju-Chan;Seo, Ki-Seog;Seo, Chung-Seok;Kim, Sang Bum
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.208-213
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    • 2013
  • In this study, the effect of phosphorus flame retardants on the flame retardancy of the flexible polyurethane foam (PUF) was investigated. Tetramethylene bis(orthophosphorylurea) [TBPU] and phosphinyl alkylphosphate ester [CR-530], resorcinol bis diphenylphosphate [RDP], triethyl phosphate [TEP] were used as flame retardants. The results of thermogravimetric analysis (TGA) indicate that TBPU added PUF produces more charred residues than the other flame retardant added PUF. It was found that TBPU added PUF exhibits low mean heat release rate (HRR), peak HRR, effective heat of combusion (EHC), mass loss rate (MLR), CO yield and $CO_2$ compared to those other flame retardants.