• Title/Summary/Keyword: 나노하이브리드

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Investigation of Mechanical and Electrical Properties of Hybrid Composites Reinforced with Carbon Nanotubes and Micrometer-Sized Silica Particles (탄소나노튜브 및 실리카 입자로 강화된 하이브리드 복합재료의 기계적, 전기적 물성에 관한 연구)

  • Oh, Yun;You, Byeong Il;Ahn, Ji Ho;Lee, Gyo Woo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.12
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    • pp.1037-1046
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    • 2016
  • In this study, to enhance the electrical insulation of composite specimens in addition to the improved mechanical properties, the epoxy composite were reinforced with carbon nanotubes and silica particles. Tensile strength, Young's modulus, dynamic mechanical behavior, and electrical resistivity of the specimens were measured with varied contents of the two fillers. The mechanical and electrical properties were discussed, and the experimental results related to the mechanical properties of the specimens were compared with those from several micromechanics models. The hybrid composites specimens with 0.6 wt% of carbon nanotubes and 50 wt% of silica particles showed improved mechanical properties, with increase in tensile strength and Young's modulus up to 11% and 35%, respectively, with respect to those of the baseline specimen. The electrical conductivity of the composite specimens with carbon nanotubes filler also improved. Further, the electrical insulation of the hybrid composites specimens with the two fillers improved in addition to the improvement in mechanical properties.

Formation of Nano-structure and Compressive Residual Stress on AISI304 Stainless Steel by Ultrasonic Nanocrystalline Surface Modification (초음파 나노표면개질 공정기술에 의한 AISI304 스테인리스강의 표면나노구조화 및 압축잔류응력 형성)

  • Cho, In-Shik;Dong, Ji-Ling;Yoo, Dae-Hwang;Suh, Jung-Hwa;Amanov, Auezhan;Shin, Kee-Sam;Lee, Chang-Soon;Pyoun, Young-Shik;Park, In-Gyu
    • Korean Journal of Metals and Materials
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    • v.48 no.9
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    • pp.807-812
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    • 2010
  • In this paper, the Ultrasonic Nanocrystalline Surface Modification (UNSM) surface treatment process was used to induce compressive residual stress and nanocrystalline structure by severe plastic deformation on the UNSM-treated surface. The test results for AISI304 stainless steel demonstrated that the grain size was found to be 23 nm, the dislocation density was increased by $0.2085{\times}10^{18}\;m^{-2}$, and the volume fraction of martensite is defined as 27.6% from austenite so that the surface hardness of the surface is increased from 200 Hv up to 515 Hv. The initial tensile residual stress is changed from 300 MPa to a compressive residual stress of 500 MPa after UNSM treatment. In addition, UNSM was applied under five various conditions, and the results of those conditions were defined as a function of depth quantitative.

Use of Core-Crosslinked Amphiphilic Polymer Nanoparticles as Templates for Synthesis of Nanostructured Inorganic Materials (코아 가교 양친성 고분자 나노입자 템플레이트를 이용한 무기물 나노 구조체 합성)

  • Kim, Hyun-Ji;Kim, Na-Hae;Kim, Juyoung
    • Journal of Adhesion and Interface
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    • v.16 no.1
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    • pp.6-14
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    • 2015
  • In this study, physically and chemically stable core-crosslinked amphiphilic polymer (CCAP) nanoparticles were prepared using amphiphilic reactive precursors via soap-free emulsion process. Obtained CCAP nanoparticles were used as templates for synthesis of nanostructured $TiO_2$ nanoparticles. First, CCAP nanoparticles dispersed aqueous solutions were mixed with titanium isopropoxide to prepare stable organic-inorganic hybrid sols, and then obtained sols were spin coated onto glass substrate to prepare hybrid thin films onto glass, and then hybrid thin films were calcinated at various temperature to remove CCAP. Nanostructure of calcinated thin fims were examined by SEM. To study effect of CCAP nanoparticles on nanostructure of $TiO_2$ nanoparticles, the morphology of $TiO_2$ nanoparticles prepared using various CCAP templates was compared with that of $TiO_2$ nanoparticles prepared using conventional organic template, nonionic surfactant, Triton X-100.

Numerical Study on Couette Flow in Nanostructured Channel using Molecular-continuum Hybrid Method (분자-연속체 하이브리드 기법을 이용한 구조물이 있는 나노 채널에서의 쿠에트 유동에 대한 수치적 연구)

  • Kim, Youngjin;Jeong, Myunggeun;Ha, Man Yeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.6
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    • pp.429-434
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    • 2017
  • A molecular-continuum hybrid method was developed to simulate microscale and nanoscale fluids where continuum fluidics cannot be used to predict Couette flow. Molecular dynamics simulation is used near the solid surface where the flow cannot be predicted by continuum fluidics, and Navier-Stokes equations are used in the other regions. Numerical simulation of Couette flow was performed using the hybrid method to investigate the effect of solid-liquid interaction and surface roughness in a nanochannel. It was found that the solid-liquid interaction and surface roughness influence the boundary condition. When the surface energy is low, slippage occurs near the solid surface, and the magnitude of slippage decreases with increase in surface energy. When the surface energy is high, a locking boundary condition is formed. The roughness disturbs slippage near the solid surface and promotes the locking boundary condition.

유기-무기 하이브리드 나노기공소재의 환경응용

  • 김영훈;윤창연;강태욱;이종협
    • Polymer Science and Technology
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    • v.15 no.2
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    • pp.173-183
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    • 2004
  • 노벨 물리학상을 수상한 파인만 (Richard p. Feynman) 교수는 1959년 한 강연회에서 "There's Plenty of Room at the Bottom"이라는 내용을 발표한 바 있다. 이는 나노 세계의 가치를 처음으로 알린 계기가 되었으며, 21세기를 이끌어가는 대표적인 과학기술로 자리 잡게 만드는 시발점이 되었다. 20세기 후반부터 나노기술에 대한 관심과 투자는 신기술의 개발뿐만 아니라 종래 기술의 단점 개선과 기술의 향상을 도모하였다. 이로 인하여 기술간의 융합이 이루어졌으며, 학문간의 벽은 점차 사라져 가고 있다. 즉 바이오기술과 나노 (예, BioMEMS), 나노소재를 이용한 환경기술 등 기술융합은 진보된 새로운 기술들을 이끌어가고 있다.(중략)

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Preparation and Properties of NBR-Clay Hybrids (NBR-Clay 하이브리드의 제조 및 물성)

  • 김영진;남상용
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.131-132
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    • 2004
  • 클레이는 1 나노미터 정도의 두께를 가지는 실리케이트층으로 이루어져 있으며, 이러한 클레이를 고분자 사이에 나노미터 단위로 분산시키는 기술에 대한 연구가 활발하게 이루어져오고 있다. 최근에는 Nylon-6에 유기화된 클레이를 분산시키는 연구에 대한 결과가 발표된 바 있다. 클레이를 사용한 나노복합체의 개발은 제품의 경량화를 위한 노력과 더불어 이루어져왔으며, 특히 최근에 급격히 발전하고 있는 나노기술에 힘입어서 나노복합체의 개발위주로 이루어지고 있다.(중략)

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Preparation of Core/Shell Nanoparticles Using Poly(3,4-ethylenedioxythiophene) and Multi-Walled Carbon Nanotube Nanocomposites via an Atom Transfer Radical Polymerization (Poly(3,4-ethylenedioxythiophene)을 이용한 Core/shell 나노입자와 원자이동 라디칼중합 공정에 의한 다중벽 탄소나노튜브 나노복합체 제조)

  • Joo, Young-Tae;Jin, Seon-Mi;Kim, Yang-Soo
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.452-457
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    • 2009
  • Hybrid nanomaterials consisting of multi-walled carbon nanotube(MWNT) and/or PEDOT of conductive polymer were prepared in this study. In the presence of catalyst and ligand, the MWNT-Br compound prepared by the successive surface treatment reaction was mixed with MMA to initiate the atom transfer radical polymerization process. PMMA was covalently linked to the surface of MWNT for the formation of MWNT/PMMA nanocomposites. The EDOT and oxidant were added in the aqueous emulsion of PS produced via a miniemulsion polymerization process and then it proceeded to carry out the oxidative chemical polymerization of EDOT for the preparation of PEDOT/PS nanoparticles with the core-shell structure. The aqueous dispersion of PEDOT:poly(styrene sulfonate) (PSS) was mixed with the silica particles treated with a silane compound and thus PEDOT:PSS-clad silica nanoparticles were prepared by the surface chemistry reaction. The hybrid nanomaterials were analyzed by using TEM, FE-SEM, TGA, EDX, UV, and FT-IR.

Study on the PVdF Nanofibers and Graphene Oxide Hybrid Membrane (PVdF 나노섬유와 Graphene Oxide 하이브리드막에 관한 연구)

  • Jung, Hyemin;Chen, Weidong;Yang, Woo Seok;Byun, Hongsik
    • Membrane Journal
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    • v.23 no.3
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    • pp.204-210
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    • 2013
  • Recently, many applications with grapheneoxide (GO) have been reported. But GO membrane for water treatment has not been developed. In this study we prepared polyvinylidene difluoride (PVdF) nanofiber/GO hybrid membrane (FG) for the microfiltration application. The PVdF substrate membrane was prepared by using the electrospinning method with a solution of PVdF in N,N-dimethylacetamide (DMAc) and acetone. GO sheets used in this study were prepared by modified Hummer's method. The PVdF/GO hybrid membrane was finally prepared by spraying the GO solution dispersed in ethanol on the PVdF nanofiber. The successfully prepared FG was thoroughly examined by SEM, Raman, contact angle, porometer and UTM, and water-flux was measured with designed cell (Dead-End Cell). From the contact angle results, it was found that the surface of FG membrane was reformed by hydrophilic property and the water permeability was increased about 2.5 times than that of the nascent PVdF membrane, indicating the possible alternative of the commercial MF membrane.

Preparation and Photocatalyric Properties of Organic-Inorganic Hybrid Abaca Cellulose@Titanium Dioxide Composite (유-무기 하이브리드 형 Abaca 셀룰로오스/이산화 티타늄 복합체의 제조 및 이의 광촉매적 특성)

  • Su-A, Kang;Young-Ho, Kim
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.57-63
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    • 2023
  • In this study, an organic-inorganic hybrid composite of Abaca nanocellulose and titanium dioxide was prepared. Abaca nanocellulose was prepared by oxidizing Abaca cellulose using TEMPO (2,2,6,6-tetramethyl-piperidine-1-oxyl) as a catalyst. Titanium dioxide nanoparticles were prepared by the sol-gel method, and a composite was prepared by hybridizing them with nanocellulose. As a result of comparing the properties of the composite and its physical properties according to the change in manufacturing pH, the effect of pH was very large when combining nanocellulose and titanium dioxide, and the optimal bonding performance was shown at pH 8 in this experimental condition. In addition, the prepared composite showed photocatalytic properties, and the higher the content of titanium dioxide, the higher the hydrophilicity of the composite according to UV light irradiation.