• Journal of Korean Society of Environmental Engineers
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• v.35 no.10
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• pp.710-716
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• 2013

New and renewable energy sources have drawn attention because of climate change. Many studies have been carried out in waste-to-energy field. Fast pyrolysis of waste lignocelluosic biomass is one of the waste-to-energy technologies. Bubbling fluidized bed (BFB) reactor is widely used for fast pyrolysis of the biomass. In BFB pyrolyzer, bubble behavior influences on the chemical reaction. Accordingly, in the present study, hydrodynamic characteristics and fast pyrolysis reaction of waste lignocellulosic biomass occurring in a BFB pyrolyzer are scrutinized. The computational fluid dynamics (CFD) simulation of the fast pyrolysis reactor is carried out by using Eulerian-Granular approach. And two-stage semi-global kinetics is applied for modeling the fast pyrolysis reaction of waste lignocellulosic biomass. To summarize, generation and ascendant motion of bubbles in the bed affect particle behavior. Thus biomass particles are well mixed with hot sand and consequent rapid heat transfer occurs from sand to biomass particles. As a result, primary reaction is observed throughout the bed. And reaction rate of tar formation is the highest. Consequently, tar accounts for 66wt.% of the product gas. However, secondary reaction occurs mostly in the freeboard. Therefore, it is considered that bubble behavior and particle motions hardly influences on the secondary reaction.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2005.10a
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• pp.75-82
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• 2005

Pyrolysis of biomass is one of the promising methods to obtain energy and valuable chemical stocks. Fast pyrolysis of Q. acutissima and L. letolepis has been carried out in a bubbling fluidized bed reactor to determine the optimum operating conditions of the pyrolyzer. Effects of reaction temperature, Uo/Umf, L/D ratio, and feed rate have been determined and the optimum conditions are as follows: $T\;=\;400^{\circ}C,\;U_o/U_{mf}\;=\;3.0,\;L/D\;=\;2.0$. Maximum yield of bio-oil was about 55% and the main compositions were carbohydrates, guaiacols, furans, phenols, and syringols. Product gas was consists of CO, $CO_2$, light hydrocarbons and the measured gas yield using the compositions agreed with the calculated value.

• Clean Technology
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• v.23 no.1
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• pp.80-89
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• 2017

The bubbling fluidized bed (BFB) reactor with a diameter of 0.1 m and a height of 1.2 m was used for experimental study of co-firing and emission characteristics fueled by sewage sludge (SS) and wood pellet (WP). The facility consists of a fluidized bed reactor, feeding system, cyclone, condenser and gas analyzer, The mean particle diameter and minimum fluidization velocity are $460{\mu}m$ and $0.21ms^{-1}$ respectively. SS produced from Korea and WP from Canada were examined. The various mixing ratios of WP were 20, 50, and 80% based on HHV. The equivalence ratio of 1.65, reactor temperature of $800^{\circ}C$, air flow rate of $100Lmin^{-1}$, and fluidization number of 4 were fixed in the BFB experiment. In TGA, the range of combustion temperature of SS was wider than that of WP. It represents that the combustibility of WP is higher than that of SS. The BFB reactor temperature was maintained between 800 and $900^{\circ}C$. CO emission of SS was high because of lower combustibility. $NO_X$ and $SO_X$ formation of SS were higher than that of WP since high nitrogen and sulfur contents of SS. CO, $NO_X$, and $SO_X$ formation were suppressed as the mixing ratio of WP was increased. The slagging and fouling tendencies show high in all test conditions.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1999.05a
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• pp.81-84
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• 1999

순환유동층 (Circulating Fluidized Bed : CFB) 은 기존의 기포유동층에 비하여 높은 유속에서 조업되는 반응기로, 고속의 기체와 크기가 작은 고체 입자간의 긴밀한 접촉을 통하여 비교적 대규모의 여러 가지 화학적, 물리적 작업을 수행하는 유동층기술의 한 분야이다. 순환유동층은 1940년부터 공업적으로 이용되기 시작하였으며 현재에는 가솔린의 제조, 석탄의 연소, 가스화 등에 널리 사용되고 있다.(중략)

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.110.2-110.2
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• 2010

현재 상용가능한 연소전 $CO_2$ 포집 기술은 습식 스크러빙 방식으로 고온의 합성가스를 상온 수준으로 온도를 낮춘 후 $CO_2$를 포집해야 하고 포집된 $CO_2$의 압력이 낮아 재압축하여 저장소로 보내야 함에 따라 큰 폭의 열효율 손실이 불가피하다. 고온 고압에서 이산화탄소를 포집할수 있는 고체 흡수제를 이용할 경우 이산화탄소 포집 치 저장 추가에 따른 시스템 효율 저하를 최소화할 수 있다. 고체 $CO_2$ 흡수제는 서로 연결된 두 개의 유동층 반응기를 순환하면서 흡수탑에서는 합성가스 중의 $CO_2$를 흡수하고 재생탑에서는 고온의 수증기와 접촉하여 흡수된 $CO_2$를 다시 배출함으로써 재생된다. 따라서 건식 재생 $CO_2$ 흡수제는 유동층 공정에 응용가능한 물성과 함께 높은 $CO_2$ 흡수능과 빠른 반응성이 요구된다. 본 연구에서는 유동층 공정에 적합한 물성을 가진 연소전 $CO_2$ 포집용 고체 흡수제를 분무건조법으로 제조하였으며, 모사 합성가스를 이용하여 열중량분석기와 기포유동층반응기를 이용하여 $200^{\circ}C$ 흡수, $400^{\circ}C$ 재생, 압력 20 bar 조건으로 반응성을 측정하였다. 개발된 고체 $CO_2$ 흡수제는 열중량분석기에서는 반응 후 10-13 wt%의 무게증가를 나타내었고 기포유동층반응기에서는 8-10 wt%의 $CO_2$ 흡수능을 보여주었다. 특히 수증기의 함량이 10% 이상에서 높은 흡수능을 나타내어 수증기가 반응에 크게 작용하고 있음을 알 수 있었다.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2001.11a
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• pp.251-256
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• 2001

• Korean Chemical Engineering Research
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• v.54 no.5
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• pp.678-686
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• 2016

The effect of internal and shroud nozzle distributor to bubbling fluidized beds which has the size of $0.3m-ID{\times}2.4m-high$ column was modeled by CPFD (Computational Particle-Fluid Dynamics). Metal-grade silicon particles (MG-Si) were used as bed materials which have $d_p=149{\mu}m$, ${\rho}_p=2,325kg/m^3$ and $U_{mf}=0.02m/s$. Total bed inventory and static bed height were 75 kg and 0.8 m, respectively. Effect of vertical internal on the bubble rising velocity was investigated. Bubbles were split by internal when the axial position of the internal from the distributor, z = 0.45 m. Bed pressure drop and axial solid holdup were not affected by internal. However, in the case that axial distance of internal from distributor was too close to jet penetration length, bubbles were not separated and bypassed internal, and faster than without internal or z = 0.45 m.

• Clean Technology
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• v.23 no.3
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• pp.331-342
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• 2017

To estimate the combustion characteristics of sewage sludge and wood pellet, thermogravimetric analysis (TGA) was conducted. As TGA results, combustion characteristics of sewage sludge was worse than wood pellet. In ash fusion temperature (AFT) analysis, slagging tendency of sewage sludge is very high compared to wood pellet. And also, the bubbling fluidized bed reactor with a inner diameter 400 mm and a height of 4300 mm was used for experimental study of combustion characteristics fueled by sewage sludge and wood pellet. The facility consists of a fluidized bed reactor, preheater, screw feeder, cyclone, ash capture equipment and gas analyzer. The thermal input of sewage sludge cases were $54.5{\sim}96.5kW_{th}$, in case of wood pellet experiment, it was $96.1kW_{th}$. As experiment results, the $NO_x$ emission of sewage sludge was averagely about 10 times the $NO_x$ emission of wood pellet. And also CO emission of sewage sludge is about 3.5 times of wood pellet. Lastly as a result of analysis of captured ash in cyclone, the combustion efficiency of all cases were over 99%, but the potential for slagging/fouling was high at all cases by component analysis of ash.

• Korean Chemical Engineering Research
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• v.52 no.4
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• pp.522-529
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• 2014

Circulating fluidized bed system consists of SEWGS reactor - lower loop seal - regeneration reactor - riser - cyclone - upper loop seal has been used for solid circulation between the SEWGS reactor and the regeneration reactor in a SEWGS system for pre-combustion $CO_2$ capture. A vertical type lower loop seal has been used in current system but this lower loop seal requires high gas flow rate through the lower loop seal for fluidization and smooth solid circulation, and consequently, causes slugging behavior sometimes. To overcome these disadvantages, inclined type lower loop seal was proposed by this study. Solid circulation characteristics with change of lower loop seal geometry were measured and compared in a bubbling - bubbling - riser type circulating fluidized bed using $CO_2$ absorbent (P-78) as bed material at ambient temperature and pressure. We could conclude that the inclined lower loop seal is better than the vertical type lower loop seal from the viewpoints of minimum flow rate requirement for stable solid circulation and solid height change during solid circulation.

• Korean Chemical Engineering Research
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• v.58 no.4
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• pp.651-657
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• 2020

Fluidization processes in which solid particles vividly move like gas or liquid have been widely used in various industrial sectors, such as thermochemical energy conversion and polymerization processes for general purpose polymer resins. One of the general purpose polymer resins, LLDPE(Linear low-density polyethylene) resins have been produced in bubbling fluidized bed processes in the world. In a bubbling fluidization polymerization reactors, LLDPE particles with relatively larger particle size and low density are fluidized by hydrogen gas for polymerization reaction. Though LLDPE polymerization reactors are one of bubbling fluidization processes, slugs that have negative impact for reaction exist or occur in these processes. Therefore, the fluidization state of LLDPE particles was investigated in a simulation model similar to a pilot-scale polymerization reactor (0.38 m l.D., 4.4 m High). In particular, the effect of gas velocity (0.45-1.2 m/s), solid density (900-199 kg/㎥), solid sphericity (0.5-1.0), and average particle size (120-1230 ㎛), on bed height and fluidization state were measured by using a CPFD(Computational particle-fluid dynamics) method. With CPFD analysis, the occurrence of a flat slug was visualized. Also, the change in particle properties, such as particle density, sphericity, and size, could reduce the occurrence of slug and bed expansion.