• Food Science and Preservation
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• v.17 no.6
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• pp.908-913
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• 2010

Modified atmosphere packaging (MAP) was evaluated for the storage of pumpkin rice cake as a means of preserving quality and extending shelf-life. Retail-sized amounts of rice cake were packaged in trays under different modified atmosphere conditions (air, vacuum, 60% $CO_2$/40% $N_2$ and 100% $CO_2$) using gas-barrier plastic film; control was in air-permeable stretch wrap. The packages were stored at $20^{\circ}C$ with periodical measurement of package atmosphere and cake quality attributes. The modified atmosphere packages of 60% $CO_2$/40% $N_2$ and 100% $CO_2$ inhibited the growth of molds/yeasts completely and significantly retarded the growth of aerobic bacteria. All the packages except that of 100% $CO_2$ showed the reduction of internal $O_2$ concentration and increase of the $CO_2$ with storage time due to the microbial activity. There has been slight decrease of $CO_2$ concentration for 60% $CO_2$/40% $N_2$ and 100% $CO_2$ packages just after start of the storage possibly due to dissolution of headspace $CO_2$ into the cake. Any MAP conditions did not affect the retrogradation of the rice cake. Surface color of the cake within affordable microbial quality limit was not affected significantly by packaging conditions.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.164-164
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• 2016

항만 및 해양 구조물은 육상과는 비교할 수 없을 정도로 가혹한 해수 환경에서 사용되며 계속적으로 부식 손상을 받는다. 따라서 강구조물이 장기적으로 안전하게 사용되기 위해서는 적절한 방식은 물론 철저한 유지관리가 필수적이다. 한편, 현재 해양환경 중 항만, 조선, 해양산업 등에 많이 이용되는 강구조물은 이에 대응하기 위하여 일반적으로 도장방식이나 음극방식이 사용되고 있다. 음극방식은 피방식체를 일정전위로 음극 분극하는 원리로써 외부전원을 인가하거나 비전위의 금속을 희생양극으로 연결하여 방식하는 방법이다. 이와같이 해수 중 음극방식을 실시할 경우 해수 중 용존하는 많은 이온들 중에서 특히 $Ca^{2+}$ 이나 $Mg^{2+}$ 이온이 탄산칼슘, 수산화마그네슘을 주성분으로하는 화합물로 형성된다. 이렇게 생성된 전착막은 산소 확산을 방지하는 물리적 장벽을 형성하고 부식율을 감소시키는 것으로 보고되고 있다. 그러나 전착막은 소지 금속과의 결합력이 불균일 함은 물론 막을 형성하는데 있어서 장시간이 소요된다는 단점이 있다. 따라서 본 연구에서는 해수 중 음극방식 응용 원리에 의해 전착막을 형성하고, 석출속도, 밀착성 및 내식특성을 향상시키기 위해 해수 중 기체를 용해시켜 제작한 막의 특성을 분석-평가하였다. 본 연구에 사용된 기판(substrate)은 일반구조용 강(SS400)을 사용하였으며, 면적은 $70mm{\times}30mm$, 두께는 1 mm로 제작하여 실험을 진행하였다. 외부전원은 정류기(Rectifier, xantrex, XDL 35-5T)를 사용하여 3 및 $5A/m^2$ 의 조건으로 인가하였고, 양극은 Carbon Rod를 사용하였다. 이때 해수에 주입한 이산화탄소의 양은 0.5 NL/min 였다. 각 조건별로 제작된 전착막에 대해 외관관찰, 석출량, 모폴로지, 조성원소 및 결정구조 분석을 실시하였고, 밀착성 및 내식특성을 평가하기 위해 테이핑 테스트(Taping Test, JIS K 5600-5-6)와 3.5 % NaCl 용액에서 전기화학적 양극 분극 시험을 진행하였다. 시간에 따른 전착막의 외관관찰 결과 전류밀도의 증가와 함께 상대적으로 많은 피막이 형성되었고, 용해시킨 기체에 의해 더 치밀하고 두터운 피막이 형성됨을 확인할 수 있었다. 성분 및 결정구조 분석 결과 $Mg(OH)_2$ 성분의 Brucite 및 $CaCO_3$ 성분의 Calcite 구조 및 Aragonite 구조를 확인하였으며, 용해시킨 기체의 영향으로 $CaCO_3$ 성분의 Aragonite 구조가 상대적으로 많이 검출되었다. 이는 해수 중 용해된 이산화탄소의 영향으로 인해 풍부한 ${CO_3}^{2-}$ 이온이 형성되고 용액 pH를 낮게 유지시켜 Ca 화합물 형성이 용이한 환경이 조성되는 것으로 판단된다. 밀착성 및 내식성 평가를 실시한 결과 해수중 용해시킨 기체에 의해 제작한 시편의 경우 견고하고 화학적 친화력이 높은 Aragonite 결정이 표면을 치밀하게 덮어 전해질로부터 산소와 물의 침입을 차단하는 역할을 하여 기체를 용해시키지 않은 $3A/m^2$ 및 $5A/m^2$ 보다 비교적 우수한 밀착성 및 내식 특성을 보이는 것으로 사료된다.

• Conservation Science in Museum
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• v.16
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• pp.96-113
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• 2015

High-barrier films are used to store cultural heritage objects in a safe environment sealed from oxygen and moisture. One of the high-barrier films use populary E manufactured by Japanese company M from the 1990's. However, this product has stayed in wide use, due to dearth of research on related subjects - including studies comparing it with other similar products-, in spite of the fact that high price information about its characteristics and environmental conditions is largely lacking. This study examines the characteristics of a number of high-barrier films with the goal to establish environmental standards for safer conservation of cultural heritage objects. E by the Japanese manufacturer M is compared with four other films; an electronics packaging films by a Korean firm, a film specially produced for the purposes of experiment in this study and a zipper bag-type film. Experiments were performed to compare the properties and gas blocking ability of the films by looking at their cross-section and measuring the thickness, tensile strength, elongation, absorbance of UV and visible light, yellowing and the permeability for oxygen and vapor. Based on these experiments, there are observed changes under different environmental conditions and depending on the length of use through temparature and humidification reproucing test. The results showed that while the high-barrier film by the Korean manufacturer was suitable for use as a packaging material for cultural heritage objects, the zipper bag-type film (P) was ill-adapted for this purpose. Based on the experiments reproducing the real-world environment, the length of useful life was also determined for each.

• Membrane Journal
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• v.23 no.2
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• pp.151-158
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• 2013

The effect of layered double hydroxides (LDH) on the gas separation properties of ethylene vinyl acetate copolymer was investigated. Mg-Al LDH/EVA nanocomposite membranes were prepared from solution intercalation using organically modified LDH (DS-LDH). Dodecyl sulfate (DS)-LDH was obtained by the intercalation of DS anion in the interlayer. The nanocomposite structure has been elucidated by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM). XRD pattern clearly shows that the DS-LDH layers are disorderly well dispersed in the EVA matrix. The maximum tensile strength and elongation of the LDH/EVA nanocomposite membrane were found with the LDH content 3 wt%. The thermal properties of nanocompostie membrane were enhanced by the incorporation of LDH in EVA matrix. Gas permeation of LDH/EVA nanocomposite membranes with LDH contents of 1, 3, 5 wt% was studied for $O_2$ and $CO_2$ single gases. The presence of 3 wt% LDH decreased $O_2$ permeability by up to 53% compared to the EVA membrane. In spite of barrier property of nanocomposite membrane, however, the gas permeability for $CO_2$ was increased due to its strong affinity with the residual OH groups on the LDH.

• Polymer(Korea)
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• v.33 no.6
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• pp.537-543
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• 2009

The direct fluorination of polymers is a heterogeneous reaction using the mixture of $F_2$ and inert gas. In general, the resulting fluorinated polymers have good barrier property chemical stability similar to those of the fluoro-polymers, and could be prepared from the simple process. In this study, the polysulfone dense films were surface fluorinated using the direct fluorination technique and gas permeability and selectivity of the prepared membranes were measured with varying both $F_2$ concentration and reaction time. The introduction of $F_2$ was confirmed by X-ray photoelectron spectroscopy (XPS), water contact angles, and atomic force microscopy (AFM). As the $F_2$ increased, the permeability decreased while the selectivities for $O_2$, $CO_2$, and He gases relative to $N_2$ increased.

• The Korean Journal of Nuclear Medicine Technology
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• v.16 no.2
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• pp.126-130
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• 2012

Purpose : Methode an effective block was investigated to deal with volatile radioactive gas, short lived radioactive waste generated as a result of the routinely produced radiopharmaceuticals FDG (2-deoxy-2-[$^{18}F$]fluoro-D-glucose) and compound with $^{11}C$. Materials and Methods : All components of the radiation stack monitoring and data management system for continuous radioactive gas detection in the air extract system purchase from fixed noble gas monitor of Berthold company. TEDLAR gas sampling bags purchase from the Dongbanghitech company. TEDLAR gas sampling bags (volume: 10 L) connected via paraflex or PTFE tubing and Teflon 3 way stopcock. When installing TEDLAR gas sampling bags in Hot cell on the inside and not radioactive gas concentrations were compared. According to whether the Hot cell inside a activated carbon filter installed, compare the difference in concentration of the radioactive gas $^{18}F$. Comparison of radiation emission concentration difference of module a FASTlab and TRACElab. Results : Activated carbon filter are installed in the Hot cell, a measure of the concentration of radioactive gas was 8 $Bq/m^3$. Without activated carbone filter in the hot cell was 300 $Bq/m^3$. Tedlar bag prior to installation of the radioactive gases a measure of the concentration was 3,500 $Bq/m^3$, $^{11}C$ synthesis of the measured concentration was 27,000 $Bq/m^3$. After installed a Tedlar bag and a measure concentration of the radioactive gases was 300 $Bq/m^3$ and $^{11}C$ synthesis was 1,000$Bq/m^3$. Conclusion : $^{11}C$ radioactive gas that was ejected out of the Hot cell, with the use of a Tedlar gas sampling bag stored inside. A compound of 11C is not absorbed onto activated carbon filter. But can block the release out by storing in a Tedlar gas sampling bag. We was able to reduce the radiation exposure of the worker by efficient radiation protection.

• Food Science and Preservation
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• v.10 no.1
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• pp.32-36
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• 2003

Quality stability of the dried layer Porphyra tenera depending on various light sources, water activities, packaging materials and storage temperatures were investigated by peroxide value and chlorophyll degradation. Major fatty acids of dried layer were 45.7％ eicosapentaenoic acid and 13.6% palmitic acid. Quality stability was increased in order of darkness, incandescent and fluorescent increased sharply with the decrease of water activity and temperature, and also improved by the packaging material with strong barriers of water vapor, oxygen and light.

• Proceedings of the Korean Fiber Society Conference
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• 2003.10b
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• pp.199-200
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• 2003

PEN (Polyethylene 2,6-dicarboxyl naphthalate)은 PET와 화학적 구조가 유사한 polyester 이다. PEN은 PET 의 benzene ring 대신 naphthalene ring이 있는 구조로서 rigid 한 구조를 바탕으로 PET 보다 훨씬 우수한 기계적 물성과 기체 차단성 및 전기 절연성을 가지고 있기 때문에, 현재 PEN에 대해서는 많은 연구가 진행되었고, 상업용으로도 생산되고 있다. 현재까지 진행된 PEN에 대한 연구 중 X-ray를 이용한 배향 거동에 대한 연구보고는 많았으나, 아직까지 FTIR-ATR 을 통해서 시료의 Machine Direction (MD), Transverse Direction (TD), Normal Direction (ND)의 세 방향으로 필름의 3차원적 분자 배향의 거동에 대한 연구보고는 없다. (중략)

• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.47-47
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• 2010

게이트 밸브는 진공 시스템 구성에 있어서 빠질 수 없는 중요한 부품 중 하나로 공간을 구획하여 필요에 따라 자유롭게 진공 상태와 대기 개방 상태가 공존하도록 만들어 주며 진공펌프와 같은 주요 기기들의 탈착 및 교체를 용이하게 해 준다. 게이트 밸브는 열린 상태에서는 저항이 최소화되는 반면 닫힌 상태에서는 마치 마구리 플랜지로 막은 것처럼 완벽한 차단이 요구된다. 일반적으로 게이트 밸브 상용제품은 개스킷이 닿는 밸브 시트가 한쪽에만 마련되어 있으므로 디스크 기계구조가 충분한 압력을 발휘하지 못한다면 어느 쪽이 대기압인가에 따라 디스크를 미는 힘의 크기가 변하여 기밀특성이 달라질 수 있다. 따라서 게이트 밸브의 누설검사는 순방향과 역방향 모두에 대해 시행해야 한다. 양방향 누설검사를 위해 한쪽 밸브 공간을 배기하고 반대쪽 공간에 헬륨을 뿌리는 작업을 교대로 하려면 배기시간의 단축과 신속한 잔류 헬륨기체 제거가 필수적이다. 게이트 밸브 제조 공장에서 상품을 출하하기 위한 시험검사라는 것을 전제로 합리적인 시간 내에 정확한 누설검사를 일관성 있게 할 수 있는 적절한 누설검사 시스템을 설계하고 측정절차를 상용 게이트 밸브에 대해 적용해 보았다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.6
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• pp.397-402
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• 2016

To produce adequate electricity in nuclear and thermal power plants, an optimal amount of steam should be supplied to a generator connected to high- and low-pressure steam turbines. A turbine output control device, which is a special steam valve employed to supply or interrupt the steam to the turbine, is operated using a hydraulic servo actuator. In power plants, the performance of servo actuators is degraded by the air generated from the hydraulic system, or causes frequent failures owing to an increase in the wear of the seal. This is due to the seal being burnt as generated heat using the produced compressed air. Some power plants have exhausted air using a fixed orifice, and thus they encounter power loss due to mass flow exhaust. Failures are generated in hydraulic pumps, electric motors, and valves, which are frequently operated. In this study, we perform modeling and analysis of the load-sensing air-exhaust valves, which can be passed through very fine flow under normal use conditions, and exhaust mass flow air at the beginning stage as with existing fixed orifices. Then, we propose a method to prevent failures due to the compressed air, and to ensure the control accuracy of hydraulic servo actuators.