• Membrane Journal
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• v.18 no.4
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• pp.354-361
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• 2008

Effects of operational conditions and solution chemistry on permeate flux in a hybrid ozone-ceramic ultra-filtration (UF) membrane system treating natural organic matter (NOM) were investigated. Results showed that the extent of permeate flux decline was higher at higher cross-flow velocity and ozone dosage, but it was higher at lower transmembrane pressure (TMP). The mechanism of fouling mitigation was found to be more dependent upon reaction between ozone and natural organic matter at/near catalytic membrane surface than scouring effect due to ozone gas bubbles. Addition of calcium into model NOM solution at high pH led to significant decline in permeate flux while the calcium effect on permeate flux decline was less pronounced at lower pH. After permeate flux decline during the early stage of filtration, the flux started recovering and approached fully to the initial value of it due to degradation of NOM by catalytic ozonation at ceramic membrane surface in the hybrid ozone-ceramic membrane system.

• Korean Chemical Engineering Research
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• v.48 no.2
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• pp.198-204
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• 2010

Solids flow characteristics have been determined in a pressurized solids recycle systems of silica sand particles for the application in a pressurized CFB(PCFB). The solids recycle system is composed of a downcomer(0.10 m i.d. 2.25 m high) and a loop-seal(0.10 m i.d.). The silica sand($d_p=240{\mu}m$, ${\rho}_s=2582kg/m^3$) particles were transported at room temperature and system pressure($P_{sys}$) up to 0.71 MPa using air. Solids mass flux($G_s$) increases with increasing system pressure at constant aeration rate. Pressure gradient, solids velocity and actual gas velocity increase with increasing $P_{sys}$ at constant aeration rate. The Pressure drop number($\Phi$) on pressure gradient in downcomer has been correlated with Transportation number(Tr). Pressure drop across the loop-seal increases with increasing of $G_s$ irrespective of variation of $P_{sys}$. The obtained $G_s$ and Transportation number(Tr) have been correlated with the experimental variables.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.164-164
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• 2016

항만 및 해양 구조물은 육상과는 비교할 수 없을 정도로 가혹한 해수 환경에서 사용되며 계속적으로 부식 손상을 받는다. 따라서 강구조물이 장기적으로 안전하게 사용되기 위해서는 적절한 방식은 물론 철저한 유지관리가 필수적이다. 한편, 현재 해양환경 중 항만, 조선, 해양산업 등에 많이 이용되는 강구조물은 이에 대응하기 위하여 일반적으로 도장방식이나 음극방식이 사용되고 있다. 음극방식은 피방식체를 일정전위로 음극 분극하는 원리로써 외부전원을 인가하거나 비전위의 금속을 희생양극으로 연결하여 방식하는 방법이다. 이와같이 해수 중 음극방식을 실시할 경우 해수 중 용존하는 많은 이온들 중에서 특히 $Ca^{2+}$ 이나 $Mg^{2+}$ 이온이 탄산칼슘, 수산화마그네슘을 주성분으로하는 화합물로 형성된다. 이렇게 생성된 전착막은 산소 확산을 방지하는 물리적 장벽을 형성하고 부식율을 감소시키는 것으로 보고되고 있다. 그러나 전착막은 소지 금속과의 결합력이 불균일 함은 물론 막을 형성하는데 있어서 장시간이 소요된다는 단점이 있다. 따라서 본 연구에서는 해수 중 음극방식 응용 원리에 의해 전착막을 형성하고, 석출속도, 밀착성 및 내식특성을 향상시키기 위해 해수 중 기체를 용해시켜 제작한 막의 특성을 분석-평가하였다. 본 연구에 사용된 기판(substrate)은 일반구조용 강(SS400)을 사용하였으며, 면적은 $70mm{\times}30mm$, 두께는 1 mm로 제작하여 실험을 진행하였다. 외부전원은 정류기(Rectifier, xantrex, XDL 35-5T)를 사용하여 3 및 $5A/m^2$ 의 조건으로 인가하였고, 양극은 Carbon Rod를 사용하였다. 이때 해수에 주입한 이산화탄소의 양은 0.5 NL/min 였다. 각 조건별로 제작된 전착막에 대해 외관관찰, 석출량, 모폴로지, 조성원소 및 결정구조 분석을 실시하였고, 밀착성 및 내식특성을 평가하기 위해 테이핑 테스트(Taping Test, JIS K 5600-5-6)와 3.5 % NaCl 용액에서 전기화학적 양극 분극 시험을 진행하였다. 시간에 따른 전착막의 외관관찰 결과 전류밀도의 증가와 함께 상대적으로 많은 피막이 형성되었고, 용해시킨 기체에 의해 더 치밀하고 두터운 피막이 형성됨을 확인할 수 있었다. 성분 및 결정구조 분석 결과 $Mg(OH)_2$ 성분의 Brucite 및 $CaCO_3$ 성분의 Calcite 구조 및 Aragonite 구조를 확인하였으며, 용해시킨 기체의 영향으로 $CaCO_3$ 성분의 Aragonite 구조가 상대적으로 많이 검출되었다. 이는 해수 중 용해된 이산화탄소의 영향으로 인해 풍부한 ${CO_3}^{2-}$ 이온이 형성되고 용액 pH를 낮게 유지시켜 Ca 화합물 형성이 용이한 환경이 조성되는 것으로 판단된다. 밀착성 및 내식성 평가를 실시한 결과 해수중 용해시킨 기체에 의해 제작한 시편의 경우 견고하고 화학적 친화력이 높은 Aragonite 결정이 표면을 치밀하게 덮어 전해질로부터 산소와 물의 침입을 차단하는 역할을 하여 기체를 용해시키지 않은 $3A/m^2$ 및 $5A/m^2$ 보다 비교적 우수한 밀착성 및 내식 특성을 보이는 것으로 사료된다.

• Journal of the Korean Chemical Society
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• v.31 no.5
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• pp.425-433
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• 1987

The separation of 19 organochlorine pesticides was studied by capillary column gas chromatography. The applicability of this method to the fresh rice was investigated. Comparison of the resolution of pesticides by OV-17 and SE-30 capillary columns revealed that OV-17 column (25m ${\times}$ 0.20mm, 0.27${\mu}$m thickness) showed better resolution. The relative standard deviations (RSD) for their retention times and peak areas obtained by splitless injection mode were within 0.16% and 8.2%, respectively. The recoveries of pesticides spiked in fresh rice were mostly over 85% and their RSDS did not exceed 11.4%.

• Fire Science and Engineering
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• v.16 no.3
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• pp.1-7
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• 2002

Diffusion and dispersion of injected $CO_2$gas into the $N_2$ gas flow are complex. In the packed column with porous particles the axial dispersion and the extra-particle mass transport as well as the intra-particle mass transport are involved. The pulse spreads by stationary diffusion during the period of arrested flow. Hence, the effect of axial dispersion, and of entrance and exit, as well as that of intraparticle convection should be eliminated during the period. The effective diffusivity was determined experimentally by using the gas chromatography, which is to arrest the gas flow during the period after injecting the pulse. This experiment method hasn't been used often in the field. Effective diffusivities are raised with temperature increasing, and it is quite satisfied com-pared to literature values. In this study, the calculated data of gaseous chemical for extinguish fires could be helpful to appreciate several physical phenomenons. Also, it could be expected that, the calculated data of this study might be very useful for development of excellent gaseous chemical for extinguish fires and improvement of its efficiency.

• Journal of the Microelectronics and Packaging Society
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• v.12 no.4 s.37
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• pp.345-349
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• 2005

Low resistive ($300{\mu}{\Omega}$-cm) W-C-N films have been deposited on tetraethylorthosilicate (TEOS) interlayer dielectric by atomic layer deposition (ALD) with $WF_6-N_2-CH_4$ gas. The exposure cycles of $N_2$ and $CH_4$ are synchronized with pulse plasma. The W-C-N films on TEOS layer follow the ALD mechanism and keep constant deposition rate of 0.2 nm/cycle from 10 to 100 cycles. As a diffusion barrier for Cu interconnection the W-C-N films maintain amorphous phase and Cu inter-diffusion is not occurred even at $800^{\circ}C$ for 30 min.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2012.06a
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• pp.123-124
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• 2012

Effervescent atomizer in which the liquid is ejected from nozzle with bubble caused by gas injection into the liquid is one of twin-fluid atomizers. Effervescent atomizer is operated with the lower injection pressure and the smaller air flow rate when compared with those of other twin-fluid atomizers. In this study, we attempted experiment study to investigate the atomization characteristics of effervescent atomizer related with the internal flow condition. The nozzle was made with acrylic material to investigate the nozzle internal flow. The macroscopic spray analysis was conducted with internal flow images and spray images. Furthermore, SMD was measured by using the laser diffraction method. According to this study, the internal flow condition changed from bubbly flow to annular flow as the air-liquid mass ratio(ALR) increases. At that time, the atomization characteristics were improved.

• Proceedings of the KSME Conference
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• 2003.11a
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• pp.712-716
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• 2003

In the present study, the gas injection system based on air-water model was designed to investigate the behavior characteristics of bubbles injected into a ladle. The parameters such as gas volume fraction and bubble rise velocity were exprementally measured in a gas-liquid flow region. To measure gas volume fraction, an electo-conductivity probe was used and bubble rise velocity was obtained by a high speed CCD camera. Gas volume fraction was symmetric to the axis of nozzle secured on the bottom of a ladle. The bubble rise velocity was calculated for two different experimental conditions. That is, gas flow conditions were following two case: 1) Q = $0.63{\times}10^{-4}$ $m^{3}/s$, 2) $1.26{\times}10^{-4}$ $m^{3}/s$. As a gas injected into the liquid ladle, the liquid-phase region is circulated by bubbles' behavior. The bubble rise velocity was influenced of the circulation flow of liquid phase. As a result, the bubble rise velocity was appeared higher middle region of ladle than near the nozzle.

• Korean Chemical Engineering Research
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• v.48 no.2
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• pp.185-192
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• 2010

The chemical-looping combustion(CLC) has advantages of no energy loss for separation of $CO_2$ without $NO_x$ formation. This CLC system consists of oxidation and reduction reactors where metal oxides particles are circulating through these two reactors. In the present study, the reaction kinetic equations of iron oxide oxygen carriers supported on bentonite have been determined by the shrinking core model. Based on the reactivity data, design values of solid circulation rate and solids inventory were determined for the rector. Two types of interconnected fluidized bed systems were designed for CLC application, one system consists of a riser and a bubbling fluidized bed, and the other one has a riser and two bubbling fluidized beds. Solid circulation rates were varied to about $30kg/m^2s$ by aeration into a loop-seal. Solid circulation rate increases with increasing aeration velocity and it increases further with an auxiliary gas flow into the loop-seal. As solid circulation rate is increased, solid hold up in the riser increases. A typical gas leakage from the riser to the fluidized bed is found to be less than 1%.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.5
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• pp.564-570
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• 2007

This study investigated the treatment of liquid waste containing highly concentrated iron(III)-ethylenediaminetetraaceticacid (Fe(III)-EDTA) of 70,000 mg/L by an underwater electrical discharge process using low voltage and high current. When AC voltage is applied to the discharging electrode with the other electrode grounded, the temperature of the liquid waste around the discharging electrode rapidly increases, and at the same time, hydrogen and oxygen gases are formed at the electrode as a result of electrochemical reactions. Ultimately, gases formed by vaporization of water and electrochemical reactions cover the electrode. Since the liquid waste is electrically conductive, it elongates the ground electrode up to the border of the gas layer, where electrical discharge occurs. Without hydrogen peroxide, electrical discharge was able to remove about 50% of Fe(III)-EDTA. As the concentration of hydrogen peroxide added increased, the removal efficiency of Fe(III)-EDTA increased. When the molar ratio of hydrogen peroxide to the initial Fe(III)-EDTA was higher than 24.7, more than 80 g of Fe(III)-EDTA was removed with an energy of 1 kWh. A comparison between tungsten and steel electrodes showed that electrode material did not affect the Fe(III)-EDTA removal. In the present underwater electrical discharge process, the removal of Fe(III)-EDTA was completed within 30 min at molar ratios of hydrogen peroxide to the initial Fe(III)-EDTA higher than 24.7.