• Proceedings of the Korea Air Pollution Research Association Conference
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• 2003.11a
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• pp.325-326
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• 2003

매립지 내부에서 진행되는 혐기성 분해로 인한 폐기물의 부패현상은 일반적으로 악취와 관련한 직접적인 대기오염문제에서부터 메탄과 이산화탄소와 같은 온실기체의 발생 등과 같이 기후환경변화와 관련된 문제에 이르기까지 매우 심각한 오염원으로 인식되고 있다. 특히 매립지 내부의 가스상 오염물질들의 누적을 억제하기 위하여 설치하는 배출공에서는 이산화탄소나 메탄과 같은 온실기체 이외에도 약 80여 종에 이르는 다양한 휘발성유기화합물질 (Volatile Organic Compound, 이하 VOC) 성분들이 검출되기도 하였다 (Young and Parker, 1983). (중략)

• Journal of the Korean Society of Propulsion Engineers
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• v.23 no.4
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• pp.70-80
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• 2019

Combustion tests using six bi-swirl coaxial injectors with different shapes and recess lengths were performed in a model combustion chamber capable of flame visualization. By utilizing gaseous methane and gaseous oxygen instead of actual propellants, the effects of injector design and experimental conditions on the flame structure and combustion stability were analyzed. It was found that not only the experimental conditions but also the injector geometry such as the recess length and orifice diameter had a considerable influence on the combustion stability. In addition, it was confirmed that the heat release pattern changed with the occurrence of combustion instability.

• Journal of the Korean Society of Propulsion Engineers
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• v.23 no.1
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• pp.1-8
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• 2019

To analyze the dynamic behavior and the structure of the gaseous methane-gaseous oxygen diffusion flame formed by a swirl/shear-coaxial injector, combustion experiments were carried out under different propellant injection conditions. As a result, the OH radical emission intensity of the diffusion flame visualized through chemiluminescence was observed to increase as the propellant mass flow and the momentum flux ratio increased. And flames with swirl showed a more high radical emission intensity than those without swirl.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.28 no.3
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• pp.95-120
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• 2023

Methane (CH₄) is a key greenhouse gas in the atmosphere with 85 times greater greenhouse potent relative to carbon dioxide (CO₂). The atmospheric concentration of CH₄ is rapidly increasing due to the intensive usage of CH₄ and the thawing of the cryosphere. Additionally, with the current warming of ocean water, the dissociation of gas hydrates, an ice-like compound and the largest reservoir of CH₄ on Earth, is expected to occur, resulting in the release of CH₄ from the seafloor into the overlying water and atmosphere. Moreover, bottom water hypoxia is another concern that potentially introduces greenhouse gases into the atmosphere. With ongoing global warming and eutrophication, the size and duration of bottom water hypoxia are rapidly increasing. These low-oxygen conditions would relocate the redox zone shallower in sediment or in the water column, causing the release of CH₄ into the atmosphere and thereby intensifying global warming. However, there exists a gap in the understanding of CH₄ dynamics including its generation in relation to bottom water hypoxia. Therefore, this review article aims to understand the relationship between CH₄ and bottom water hypoxia and to draw attention to CH₄ investigation in Korea.

• Proceedings of the Membrane Society of Korea Conference
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• 1998.10a
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• pp.43-45
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• 1998

1. 서론 : 막을 이용한 게체분리는 막층 내에서의 기체분자의 투과성의 차이를 이용하여 기체분리를 행한다. 대부분의 고분자막은 한가지 기체의 선택투과도가 증가하면 다른 기체의 선택투과도도 증가하는 경향을 나타낸다. 예를 들면 질소에 대한 산소의 선택투과도가 큰 막은 메탄에 대한 이산화탄소의 선택도도 큰 값을 나타낸다. 그런데, 대부분의 분리막은 선택도가 증가할수록 투과속도가 감소하는 경향을 나타내기 때문에 이러한 단점을 극복하기 위하여 비대칭막이나 복합막 등에 대한 연구가 많이 진행되어 왔다.

• Proceedings of the Korean Vacuum Society Conference
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• 1999.07a
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• pp.47-47
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• 1999

2.45 GHz 마이크로웨이브를 이용하는 electron cyclotron resonance plasma enhanced chemical vapor deposition(ECR-PECVD)방법으로 다이아몬드성 탄소박막(diamond-like carbon, DLC)을 증착하였다. DLC 박막의 산업 응용을 위해서는 높은 경도와 밀착력이 필요하다. 그래서 본 실험에서는 DLC 박막의 산업 응용을 위하여 ECR-PECVD 방법으로 증착된 DLC 박막의 분석결과로부터 DLC 박막의 물성과 증착조건의 관계를 조사하였다. 기판으로는 실리콘 웨이퍼와 실험용 SUS 판을 사용하였다. 아르곤 가스를 주입하여 ECR 마이크로 웨이브 플라즈마와 negative DC bias로 기판을 플라즈마 세척한 후, 수소와 메탄가스를 반응기체로 하여 DLC 박막을 증착하였다. 박막 증착시에 13.56MHz RF 전원 공급장치로 기판에 전원을 공급하였다. DLC 박막 증착의 변수는 반응기체의 호합율, 마이크로웨이브 파워, 프로세스 압력 및 RF 전원공급장치에서 유도되는 negative self DC bias 등이다. 이때 사용된 반응기체의 혼합율(메탄/수소)은 10~50%이고, 수소 가스 흐름율은 100sccm, 메탄은 10~50sccm이다. 마이크로웨이브의 크기는 360~900W, negative self DC bias는 -500~-10 V였다. 그리고 본 실험에서는 높은 증착율을 고려하여 프로세스 압력을 10~30mTorr까지 조절하였다. ER-PECVD 방법으로 증착된 DLC 박막은 SEM으로 단면, $\alpha$-Step으로 두께, Raman 분광계로 탄소 결합구조, FTIR 분광계로 탄소와 수소 결합구조, Micro-Hardness로 경도 그리고 Scratch Tester로 밀착력 등을 분석하였다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.20-23
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• 2011

The spray and atomization characteristics of swirl coaxial injectors which use gas methane and LOx as propellants are investigated experimentally with a recess length variation. Mass distribution and spray angle are measured by a patternator and droplet size to find atomization characteristics are measured by GSV(Global Size and Velocity) system. As a result, when the liquid sprayed, the spray angle decreased and the atomization characteristic was improved with the recess length increase. When the gas and liquid injected simultaneously, the spray angle was decreased and the atomization characteristic was improved comparing to only the liquid injection.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.85-88
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• 2010

This study has been mainly motivated to numerically model the supercritical mixing and combustion processes encountered in the liquid propellant rocket engines. In the present approach, turbulence is represented by the extended $k-{\varepsilon}$ turbulence model. To account for the real fluid effects, the propellant mixture properties are calculated by using SRK (Souve-Redlich-Kwong) equation of state. In order to realistically represent the turbulence-chemistry interaction in the turbulent nonpremixed flames, the flamelet approach based on the real fluid flamelet library has been adopted. Based on numerical results, the detailed discussions are made for the real fluid effects and the precise structure of gaseous methane/liquid oxygen coaxial jet flame.

• Journal of the Korean Society of Propulsion Engineers
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• v.24 no.6
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• pp.85-92
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• 2020

Ground hot-firing tests were conducted to analyze the combustion performance according to the characteristic lengths 1.37 m, 1.71 m, and 2.06 m of the combustion chamber in 200 N-class GCH4-LOx small rocket engine. Thrust, specific impulse, and characteristic velocity at the steady-state could be obtained as the key performance parameters of the rocket engine. The performance characteristics acquired through the test were compared and analyzed with the theoretical performance calculated from CEA analysis. Observation of the influence of characteristic length on the combustion performance indicates that an optimal characteristic length shall remain between 1.71 m and 2.06 m.

• Journal of the Korean Chemical Society
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• v.34 no.5
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• pp.396-403
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• 1990

We describe how to design and construct a LPCVD (Low Pressure Chemical Vapor Deposition) apparatus which can be applicable to the study of reaction mechanism in general CVD experiments. With this apparatus we have attempted to make diamond like carbon films on the p-type (111) Si wafer from (H$_2$ ＋ CH$_4$) gas mixtures. Two different methods have been tried to get products. (1)The experiment was carried out in the reactor with two different inlet gas tubes. One coated with phosphoric acid was used for supplying microwave discharged hydrogen gas stream, and methane has been passed through the other tube without the microwave discharge. In this method we got only amorphous carbon cluster products. (2) The gas mixture (H$_2$ ＋ CH$_4$) has been passed through the discharge tube with the Si wafer located in and/or near the microwave plasma. In this case diamond-like carbon products could be obtained.