• Title/Summary/Keyword: 기공특성

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Graphene Oxide Incorporated Antifouling Thin Film Composite Membrane for Application in Desalination and Clean Energy Harvesting Processes (해수담수화와 청정 에너지 하베스팅을 위한 산화 그래핀 결합 합성 폴리머 방오 멤브레인)

  • Lee, Daewon;Patel, Rajkumar
    • Membrane Journal
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    • v.31 no.1
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    • pp.16-34
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    • 2021
  • Water supplies are decreasing in comparison to increasing clean water demands. Using nanofiltration is one of the most effective and economical methods to meet the need for clean water. Common methods for desalination are reverse osmosis and nanofiltration. However, pristine membranes lack the essential features which are, stability, economic efficiency, antibacterial and antifouling performances. To enhance the properties of the pristine membranes, graphene oxide (GO) is a promising and widely researched material for thin film composites (TFC) membrane due to their characteristics that help improve the hydrophilicity and anti-fouling properties. Modification of the membrane can be done on different layers. The thin film composite membranes are composed of three different layers, the top filtering active thin polyamide (PA) layer, supporting porous layer, and supporting fabric. Forward osmosis (FO) process is yet another energy efficient desalination process, but its efficiency is affected due to biofouling. Incorporation of GO enhance antibacterial properties leading to reduction of biofilm formation on the membrane surface. Pressure retarded osmosis (PRO) is an excellent process to generate clean energy from sea water and the biofouling of membrane is reduced by introduction of GO into the active layer of the TFC membrane. Different modifications on the membranes are being researched, each modification with its own advantages and disadvantages. In this review, modifications of nanofiltration membranes and their composites, characterization, and performances are discussed.

Study of Paprika Growth Characteristic on Covering Selective Light Transmitting Filter in Greenhouse (선택적 광 투과에 따른 파프리카 생육특성 연구)

  • Kang, D.H.;Kim, D.E.;Lee, J.W.;Hong, S.J.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.23 no.1
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    • pp.59-66
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    • 2021
  • This study aimed to a basic research for the development of dye-sensitized solar cells that the wavelength band required for crop growth is passed, and the wavelength band that is not necessary for crop growth can be used for the generation of electricity. The transmissivity according to the illuminance was about 10% higher in the Blue filter and the Green filter than in the Red filter, but the transmissivity according to the PPFD was about 10% higher in the Red filter and the Blue filter than in the Green filter. In addition, the greenhouse attached with 30% infrared blocking filter was predicted to have a lower air temperature than other greenhouses, but it was investigated that there was no significant difference. Therefore, it was investigated that the application of the infrared cut filter would not be appropriate in a greenhouse that controls the temperature by opening a window. As a result of investigating, it was found that the Green and Blue filter greenhouses had the severe overgrowth and the stems grew weaker. The fresh weight of paprika in the infrared blocking filter greenhouse was the highest at 678.9g, and the growth of Red filter and the control greenhouses was relatively poor. Photosynthetic rate, amount of transpiration, and stomatal conductivity were the infrared blocking filter and control greenhouse higher than others. On the other hand, the water use efficiency did not show a big difference.

Formaldehyde Adsorption Properties of Activated Carbon Fiber-Papers by Nitrogen Plasma Treatment (질소 플라즈마 처리에 따른 활성탄소섬유 페이퍼의 포름알데하이드 흡착 특성)

  • Min, Chung Gi;Lim, Chaehun;Myeong, Seongjae;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.624-629
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    • 2022
  • Formaldehyde is an indoor pollutant that is harmful to humans, such as causing respiratory and skin diseases. Nitrogen plasma treatment was performed to introduce nitrogen groups on the surface of the activated carbon fibers (ACFs), and the adsorption characteristics of formaldehyde for the surface-modified ACFs were considered. As the nitrogen gas flow rate increased, the content of nitrogen functional groups introduced to the surface of the ACFs increased by about 7%, and the ratio of nitrogen functional groups to each type present was similar. Ultramicropores increased on the ACFs surface due to the etching effect of plasma treatment. The adsorption efficiency of formaldehyde on the modified ACFs surface was also enhanced. However, under the nitrogen flow rate of 120 sccm or more, the surface of the ACFs was excessively etched, and the specific surface area and the formaldehyde adsorption capacity decreased. Therefore, the content of the nitrogen groups is the main factor in the adsorption of formaldehyde on the nitrogen plasma-treated ACFs, but it can be found that the adsorption efficiency of formaldehyde is improved when the ACFs have a suitable pore structure.

Cesium Ions Adsorption of Activated Carbon Treated by Oxygen Plasma (산소 플라즈마 처리된 활성탄소의 세슘 이온 흡착)

  • Ha, Seongmin;Kwak, Cheol Hwan;Lim, Chaehun;Kim, Seokjin;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.38-43
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    • 2022
  • The effect of introducing oxygen functional groups by oxygen plasma treatment of activated carbon on adsorption properties of cesium ions was investigated. During the oxygen plasma treatment, the frequency, power, and oxygen gas flow rates were fixed at 100 kHz, 80 W, and 60 sccm, respectively, while the reaction time was varied. Under the experimental conditions, the amount of cesium ion adsorption increased as the content of oxygen groups on C-O-C and O=C-O bonds increased when the reaction time with oxygen gas was 10 minutes. However, when the reaction time increased to 15 minutes, the oxygen functional group content decreased resulting in the decrease of the adsorbed cesium ion amount. On the other hand, unlike the oxygen content of the surface-treated activated carbon, the specific surface area and pore properties were hardly affected by the oxygen plasma reaction time. As a result, the oxygen plasma-treated activated carbon improved the cesium ion removal rate by up to 97.3% compared to that of the untreated activated carbon. This is considered to be due to the content of oxygen groups on C-O-C and O=C-O bonds introduced on the surface of the activated carbon through oxygen plasma treatment.

Comparison in Water Consumption, Plant and Fruit Growth of Different Europe Eggplant Cultivars in Coir Substrate Hydroponics under High Temperature Conditions (고온조건하에서 코이어 배지에서 유럽형 가지 품종별 수분소비량, 식물체 생육 및 과실 특성 비교)

  • Seoa Yoon;Jeongman Kim;Eunyoung Choi;Kiyoung Choi;Kyunglee Choi;Kijeong Nam;Seokkwi Oh;Jonghyang Bae;Yongbeom Lee
    • Journal of Bio-Environment Control
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    • v.32 no.2
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    • pp.139-147
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    • 2023
  • This study aims to select eggplant cultivars adaptive to the hot temperature period greenhouse climate by water consumption, and growth performance of plants and fruits of different European eggplant cultivars, including 'Bartok (BA)', 'Bowie (BO)', 'Black Pearl (BP)', 'Ishbilia (I)', 'Mabel (M)', 'Vestale (VE)' and 'Velia (VL)', in substrate hydroponic cultivation under hot and humid greenhouse conditions. On the 118 DAT, the leaf number and stem dry weight were highest in 'VL', followed by 'M', and there was no significant difference in leaf dry weight among cultivars. The marketable fruit number per plant was 16.4 for 'M', which was higher than other cultivars, and 'VE' and 'VL' were 8.5 and 8.8, respectively. The weight per fruit was low for 'M' at 136 g, and the highest in 'VE' and 'VL' at 332 and 281 g, respectively. There was no significant difference in fruit production per plant. In this study, 'M', which has high water use efficiency and a large number of fruits, and 'VL', which required less quantity to water consumption for producing 200 g of fruit and had a high product weight, will have excellent adaptability in the UAE greenhouse condition.

Catalytic Behavior of Ni/CexZr1-xO2-Al2O3 Catalysts for Methane Steam Reforming: The CexZr1-xO2 Addition Effect on Water Activation (메탄 습식 개질 반응용 Ni/CexZr1-xO2-Al2O3 촉매의 반응 특성: CexZr1-xO2 첨가에 의한 물 활성화 효과)

  • Haewon Jung;Huy Nguyen-Phu;Mingyan Wang;Sang Yoon Kim;Eun Woo Shin
    • Korean Chemical Engineering Research
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    • v.61 no.3
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    • pp.479-486
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    • 2023
  • In this study, we investigated the effect of the CexZr1-xO2 (CZ) addition onto Ni/Al2O3 catalysts on the catalytic performance in methane steam reforming. In the reaction results, the CZ-added Ni/Al2O3 catalyst showed higher CH4 conversion and H2 yield under the same reaction conditions than Ni/Al2O3. From the characterization data, the two catalysts had similar support porosity and Ni dispersion, confirming that the two properties could not determine the catalytic performance. However, the oxygen vacancy over the CZ-added Ni/Al2O3 catalyst induced an efficient steam activation at low reaction temperatures, resulting in an increase in the catalytic activity and H2 yield.

Characterization of a Gamma Radiation-Induced Salt-Tolerant Silage Maize Mutant (방사선 유도 내염성 증진 사료용 옥수수 돌연변이체 특성 분석)

  • Cho, Chuloh;Kim, Kyung Hwa;Choi, Man-Soo;Chun, Jaebuhm;Seo, Mi-Suk;Jeong, Namhee;Jin, Mina;Son, Beom-Young;Kim, Dool-Yi
    • Korean Journal of Breeding Science
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    • v.51 no.4
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    • pp.318-325
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    • 2019
  • Salt stress is a significant factor limiting growth and productivity in crops. However, little is known about the response and resistance mechanism to salt stress in maize. The objective of this research was to develop an enhanced salt-tolerant silage maize by mutagenesis with gamma radiation. To generate gamma radiation-induced salt-tolerant silage maize, we irradiated a KS140 inbred line with 100 Gy gamma rays. Salt tolerance was determined by evaluating plant growth, morphological changes, and gene expression under NaCl stress. We screened 10 salt-tolerant maize inbred lines from 2,248 M2 mutant populations and selected a line showing better growth under salt stress conditions. The selected 140RS516 mutant exhibited improved seed germination and plant growth when compared with the wild-type under salt stress conditions. Enhanced salt tolerance of the 140RS516 mutant was attributed to higher stomatal conductance and proline content. Using whole-genome re-sequencing analysis, a total of 328 single nucleotide polymorphisms and insertions or deletions were identified in the 140RS516 mutant. We found that the expression of the genes involved in salt stress tolerance, ABP9, CIPK21, and CIPK31, was increased by salt stress in the 140RS516 mutant. Our results suggest that the 140RS516 mutant induced by gamma rays could be a good material for developing cultivars with salt tolerance in maize.

Shading Treatment-Induced Changes in Physiological Characteristics of Thermopsis lupinoides (L.) Link (차광처리에 따른 갯활량나물의 생리 특성)

  • Seungju Jo;Dong-Hak Kim;Jung-Won Yoon;Eun Ju Cheong
    • Journal of Korean Society of Forest Science
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    • v.113 no.2
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    • pp.198-209
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    • 2024
  • This study aimed to investigate the impact of light intensity, manipulated through different shading levels, on the growth and physiological responses of Thermopsis lupinoides. To assess the effects of shading treatments, we examined leaf mass per area, chlorophyll content, chlorophyll fluorescence response, and photosynthetic characteristics. T. lupinoidesexhibited adaptive responses under low light conditions (50% shading), showing increased leaf area and decreased leaf mass per area as shading levels increased. These changes indicate morpho-physiological adaptations to reduced light availability. At 50% shading, the physiological and ecological responses were favorable, with optimal photosynthetic functions including chlorophyll content, photosynthesis saturation point, photosynthetic rate, carbon fixation efficiency, stomatal conductance, transpiration rate, and water use efficiency. However, at 95% shading, the essential light conditions for growth were not met, significantly impairing photosynthetic functions. Consequently, 50% shading was determined to be the most optimal condition for T. lupinoides growth. These findings provide valuable insights for effective ex-situconservation practices and site selection for T. lupinoides, serving as foundational data for habitat restoration efforts.

Electrochemical Characteristics of Setaria viridis-Based Carbon Anode Materials Prepared by Thermal Treatment for Lithium-Ion Secondary Batteries (열처리에 의해 제조된 강아지풀 기반 리튬 이온 이차전지용 탄소 음극재의 전기화학적 특성)

  • Dong Ki Kim;Chaehun Lim;Seongjae Myeong;Naeun Ha;Chung Gi Min;Young-Seak Lee
    • Applied Chemistry for Engineering
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    • v.35 no.2
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    • pp.140-147
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    • 2024
  • In order to increase the utilization of biomass, an electrochemical performance was considered after manufacturing a carbon anode material (SV-C) for a Setaria viridis-based lithium ion secondary battery through a heat treatment process. When the heat treatment temperature of the Setaria viridis is as low as 750 ℃, the capacitance (1003.3 mAh/g, at 0.1 C) is high due to the negative (-) charge of oxygen present on the surface attracting lithium, along with the low crystallinity and high specific surface area (126 m2/g), but the capacity retention rate is believed to be as low as 61.0% (at 500 cycles and 1 C). In addition, it was confirmed that when the heat treatment temperature increased to 1150 ℃, the carbon layer was condensed to be excellent in arrangement, and the structural defects were reduced, resulting in a significant reduction in the specific surface area (32 m2/g) of the pores. Furthermore, when the surface defects of the anode material are reduced and the crystallinity is increased, the capacity retention rate is as high as 89.7% (at 500 cycles and 1 C), but the degree of defects is small, the active point is reduced, and the specific capacity is considered to be very low at 471.7 mAh/g. In the scope of this study, it was found that in the case of the Setaria viridis-based carbon anode material manufactured according to the heat treatment temperature, the surface oxygen content and crystallinity have higher reliability on the electrochemical properties of the anode material than the specific surface area.

Basic Characteristics of ALC using Carbon dioxide Conversion Capture Materials (이산화탄소전환탄산화물 혼합 경량기포 콘크리트의 기초 특성)

  • Hye-Jin Yu;Sung-Kwan Seo;Yong-Sik Chu;Woo-Sung Yum;Kuem-Dan Park;Young-Gon Kim;Eun-Sung Yoo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.2
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    • pp.121-127
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    • 2024
  • In this study, the applicability of replacing DG(Desulfurized Gypsum) from oil refinery with CCCMs(Carbon dioxide Conversion Capture Materials) as an ALC(Auto-claved LIghtweight Concrete) raw material was examined, and basic properties of ALC was measured. The main chemical components of DG and CCCMs were CaO and SO3, and an increase in LOI(Loss of ignition) due to mineral carbonation reaction was verified. The crystalline phases of CCCMs were CaCO3, CaSO4, Ca(OH)2, and CaSO4·2H2O. When DG, a raw material for ALC production, was replaced with CCCMs, foaming height, pore shape, absolute dry gravity, and compressive strength results measured similar for all binders. In addition, the formation of tobermorite which is main crystalline phase of ALC was shown for all specimens in microstructural analysis.