• Journal of Korean Society of Environmental Engineers
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• v.35 no.2
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• pp.75-83
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• 2013

We applied a sensitive method based on on-line solid-phase extraction (SPE) and liquid chromatography/mass spectrometry (LC/MSD) using an electrospray interface for the determination of eleven perfluorinated compounds (PFCs) in water. The on-line connection suppressed the target loss by keeping the cartridge from drying, which resulted in improvement of the recovery and saving of the analytical time. For the on-line solid-phase extraction of 10 mL water samples, recoveries were between $80.4{\pm}5.2%{\sim}109.5{\pm}1.4%$ and limit of quantification (LOQ) were 3.6~15.9 ng/L for the PFCs. The total PFCs concentrations of the tributaries and main stream of Nakdong River water samples were in the range of $8.0{\sim}678.6{\mu}g/L$.

• Proceedings of the Korea Water Resources Association Conference
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• 2017.05a
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• pp.81-81
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• 2017

최근 발생하는 태풍 또는 국지성호우는 단기간에 많은 양의 강우를 동반하고 있으며, 이로인한 내수침수 및 외수범람 피해가 빈번히 발생하고 있다. 이와 같은 홍수피해를 저감하기 위한 하나의 대책으로 내수 또는 외수로 인한 피해를 미리 예측하고 대비하는 방법이 필요하다. 피해를 미리 예측하기 위한 기존의 모델들은 지표유출, 지하유출, 침투, 증발산 등 다양한 강우-유출 알고리즘에 의해 홍수범람모의를 분석하게 된다. 따라서 그 모의시간이 길게 나타나 재난상황을 대처하는 데 문제가 있다. 본 연구에서는 홍수로 인한 제내지의 침수 확산 경로 빠른 시간 안에 모의하기 위하여 여러 가지 알고리즘을 단순화시킨 홍수범람 모형을 개발하였다. 개발된 분포형 홍수범람 모형인 SIMOD(Simplified Inundation MODel)는 홍수가 발생된 시점에서 그리드화된 주변셀로의 홍수전의를 위하여 주변셀과의 경사를 이용하여 차등 분배하는 다중흐름방향법(Multi Direction Method, MDM)과, 하나의 낮은 고도의 셀에서 수위가 높아져 인접셀보다 수위가 증가하면 그 수위는 인접 셀들과 균등해 진다는 가정인 평수가정법(Flat-Water Assumption, FWA)인 두 가지 알고리즘을 이용한다. 개발된 모형의 적합성을 확인하기 위하여 상용 모형인 FLO-2D를 이용하여 각 모의시간별 침수면적과 모형의 구동시간을 비교하였다. 비교결과 초기 1시간을 제외하고 홍수피해 면적이 10% 전후로 나타나 SIMOD의 적용성이 확인되었다. 모의 구동시간의 경우 32시간 모의시 SIMOD는 10분 안에 결과가 나오는 반면 FLO-2D는 1시간 이상 소요되는 것으로 나타났다. 또한 대피계획을 수립하기 위하여 제방붕괴시나리오를 이용한 제내지 침수모의를 실시하였다. 대상지역은 금호강하류 성서산업단지 유역으로 계획홍수위는 200년 빈도 홍수위를 기준으로 하였으며 폭 35m, 높이 7m의 제방파제로 인한 외수위 유입을 가정하여 제내지의 시간별 침수면적 모의하였다. 모의된 결과를 이용하여 시간대별 대피경로를 산정함으로써 홍수로 인한 대피 계획 수립에 적용 가능함을 확인하였다.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.420-420
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• 2022

우리나라의 기후 변화(여름철 집중호우, 동절기 가뭄 등)로 인하여 과거에 비해 하천의 식생영향은 증가하는 추세이고, 하도 내 수중식생은 성장과 소멸을 반복하며 기존 수위-유량관계에 변동성을 유발하고 있다. 수중식생은 수위가 상승하는 경우(강우, 방류량 증가 등)에 일부 소멸하여 유량이 증가하고, 수위가 유지되거나 평균기온이 상승하는 경우에는 성장으로 인하여 유량이 감소하는 경향을 가지고 있다. 본 연구에서는 하도 내 수중식생의 성장과 소멸에 따른 수위-유량관계곡선식의 변화의 영향을 분석하기 위해 금호강 제1지류 자호천에 위치한 영천시(단포교)관측소를 대상으로 '18년~'21년까지의 수중식생의 성장과 소멸, 회귀하는 기간의 유량 측정 성과를 확보하고 수중식생 모니터링 자료를 수집하여, 식생영향에 따른 수위-유량관계 변화를 분석하였다. 영천시(단포교)관측소는 수중식생영향을 지속적으로 받고 있으며 단면 통제나 하도 통제가 아닌 식생통제를 고려하여 '18년~'20년까지는 식생 활착, 성장과 소멸이 진행되는 기간의 성과를 확보하였고, '21년은 저수위구간의 식생성장에서 소멸까지 점차 회귀하는 성과를 각 기간별로 확보하고 분석을 통해서 수위-유량관계 곡선식을 개발하였다. 수중식생의 성장에 따라 평균유속이 감소하며 곡선식은 (-)전이가 발생하였고, 수중식생의 소멸이 발생한 경우 평균유속이 증가하여 곡선식은 (+)전이가 발생하였다. 영천시(단포교)관측소는 이러한 모니터링 결과와 유량측정성과를 바탕으로 총 5개의 기간분리가 발생하였으며, 각 기간별 곡선식 불확도와 편차율 검토 결과 유량측정성과와 곡선식은 정밀도 높은 정확성을 갖고 있는 것으로 분석되었다. 결과적으로 본 연구에서는 하도 내 수중식생영향에 따른 유량측정성과를 확보하였으며 확보한 유량측정성과의 분석을 통한 신뢰도 높은 수위-유량관계곡선식을 개발하였고 이를 통해 생산된 유량자료는 정확도가 매우 높은 것으로 분석되었다.

• The Journal of Engineering Geology
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• v.13 no.1
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• pp.1-16
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• 2003

Geochemical characteristics of groundwater in the different kinds of various lithology such as Haman formation, Panyaweol formation, Jusan andesitic formation and Palgongsan granite is distinguished by mineralogical and chemical compositions. The Concentration of the majority of solutes in groundwaters of Haman and Panyaweol formation is higher than in that of andesite and granite. Higher concentration of $HCO_3^{-}{\;}and{\;}SO_4^{2-}$ anions in the groundwater is peculiar. High concentrations of $Ca^{2+},{\;}Mg^{2+},{\;}HCO_3^{-}$ in the groundwaters of the sedimentary rocks result mainly from reaction of $CO^{2-}$ charged water with calcite and weathered feldspars. With the Piper diagram, the groundwaters of Haman formations are mainly plotted in $CaSO_4-CaCl_2$ type, whereas those of Panyaweol formations are plotted in the bothside of $Ca(HCO_3)_2{\;}and{\;}CaSO_4-CaCl_2$ type. Thses two different types of $Ca(HCO_3)_2{\;}and{\;}CaSO_4-CaCl_2$ groundwater were originated from dissolution of calcite($Ca(HCO_3)_2)$ and the oxidation of pyrite($CaSO_4-CaCl_2$), respectively. And it also is influenced by anthropogenic contamination. Three factors were extracted from the factor analysis for chemical data. Factor 1, controlled by $SO_4^{2-},{\;}Na^{+},{\;}Ca^{2+}$ and Fe, explains the dissolution of calcite, plagioclase and oxidation of pyrite. Factor 2, controlled by $HCO_3^{-}{\;}and{\;}Mg^{2+}$, mainly explains the dissolution of Mg-carbonates and dolomitization. Factor 3, controlled by $Cl^{-},{\;}K^{+}{\;}and{\;}NO_3^{-}$, is subject to the influence of artificial pollution including industrial waste water disposal. In this study area, some industrial complex which is close to Keumho river show the higher score of factor 3.

• Journal of Korean Society on Water Environment
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• v.28 no.4
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• pp.561-573
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• 2012

The object of this study was to analyze long-term water quality gradients during 1992-2008 at six sites of Geumho River and near-by two sites of Nakdong River and their influences on fish trophic guilds and tolerance guilds along with ecological health. Water quality including biological oxygen demand (BOD), chemical oxygen demand (COD), conductivity, total phosphorus (TP), total nitrogen (TN), and total suspended solids (TSS) varied largely depending on the sampling locations and seasons. Values of ambient BOD, COD, TP, and TN were greater in the downstream than in the upstream reach, and seasonal and interannual variabilities were also higher in the downstreams. This phenomenon was evident due to a dilution by the Asian monsoon rainfall during the monsoon. These outcomes indicate that point sources near the downstream are important for the chemical conditions, but also seasonal stream runoff was considered as an important factor regulating the chemical conditions. Conductivity decreased rapidly during the summer due to ionic dilution, and nutrients (N, P), BOD, COD had an inverse function of seasonal precipitation. Based on the water quality, we selected two sites (control site = $C_s$ vs. impacted site = $I_s$) for impact analysis of water chemistry on fish community and trophic/tolerant guilds. Fish guild analysis showed that species diversity was higher in the headwater stream ($C_s$) than the impacted downstream ($I_s$), and that the proportion of tolerant and omnivore species were greater in the impacted site of downstream. Comparisons of water quality between Geumho River and Nakdong River indicated that Geumho River was considered as a point source which degradated water quality to the Nakdong River. Overall, chemical water quality and fish guild analysis suggest that even if current chemical quality got better after 1996 due to continuous constructions of wastewater disposal plants near the downstreams, fish compositions of tolerant and omnivores were still dominated the community. Thus, biological restoration based on ecological health is required for the ecosystem conservation.

• Journal of the Korean association of regional geographers
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• v.10 no.1
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• pp.83-95
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• 2004

Chilgok District is a historical area, which has had a certain amount of development. It has its own regional characteristics originating from its isolation from the existing built up area of Daegu City by the Kumho River This study explores the historical development processes and pending development issues of Chilgok District. In 1640 after the Japanese invasion of Korea in 1592, the district upgraded into Chilgok Dohobu due to its importance as a transportation hub of Youngnamdaero(the main road of Youngnam province in Chosun Dynasty). In its early stages, the government office was located in Kasan fortress, later the of office was moved to Eupnae-Dong. The Chilgok district has experienced a developmental lag resulting from the office's removal to Waegwan, located on the Kyungbu railroad since 1914. Later, due to the increasing influence of nearby Daegu City, urbanization continued gradually. Finally in 1981 Chilgok district was officially incorporated into Daegu Metropolitan City. In the later 1980s, the housing land development project was applied into the district centered on the alluvial plain of Palgeo-Cheon(stream) of the Northern part of Taejun-Bridge. Although the old built up zone was excluded from public sector development projects, private sector development has made the zone a modern town. Now, Chilgok district has transformed into a high-density residential new town in which high-rise apartment complexes mingle with numerous houses. As the district has developed, traffic jams have become a hot issue and it is going to get worse than now as the development continues. To solve this problem, Daegu city needs to swiftly construct the fourth belt way and the third subway line.