• 자원리싸이클링
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• 제11권6호
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• pp.31-37
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• 2002

폐알루미늄 캔으로 제조된 2차지금과 신지금의 혼합비율에 따라 캔용 소재를 주조하고 미세조직을 조사하였다. 또한 주조후 열처리에 따른 상변화의 거동을 조사하였다. 2차지금의 혼합비율(20, 30, 40, 50, 60%)에 따라 캔용 소재를 전기로로 용해하고, ceramic filter를 사용하여 주조하였다. 주조후에는 주조조직 제어를 위해 균질화 열처리($615^{\circ}C$$\times$10hrs)를 하였다. 주조상태에서는 $\alpha$ 상($Al_{12}$ $(Fe,Mn)_3$Si), $\beta$상($Al_{6}$/(Fe,Mn)), 그리고 미세한 $Mg_2$Si상이 알루미늄 기지에 존재하며, 특히 가공성에 나쁜 영향을 미치는 것으로 알려진 $\beta$상이 많이 존재하였다. 그러나 균질화 열처리에 의해 이러한 $\beta$상은 유해성이 없는 $\alpha$상으로의 상변태가 일어났다. 기지내의 미세한 $Mg_2$Si상도 열처리에 의해 $\alpha$상으로 변화하였다. 주조시 여과된 조직을 분석한 결과 Fe, Cu, Si 등의 금속간화합물이 검출되었다.

• 대한화학회지
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• 제39권4호
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• pp.252-256
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• 1995

고순도 구리 금속중에 존재하는 미량의 안티몬을 사전 분리시키지 않고 직접 분석할 수 있는 GFAAS 조건을 조사하였다. 과량 존재하는 구리가 안티몬의 감도를 향상시키는 matrix modifier의 역할을 하고 있음을 알았다. 희화 온도는 $600^{\circ}C(20s){\sim}700^{\circ}C(10s)$를 이용할 때에 $1000^{\circ}C(20s){\sim}1100^{\circ}C(10s)$보다 감도가 향상되며, 원자화 온도는 $2200^{\circ}C$에서 가장 좋은 Sb의 흡광도를 보였다. Ar 기체의 압력은 $2.0\; kg/cm^2$일때에 최적임을 확인하였으며, 20 ppb에서 200 ppb Sb 범위에서 변화율(coefficient of variation)이 5% 미만이며 직선 관계를 보였다.

• 한국수소및신에너지학회논문집
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• 제21권2호
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• pp.81-88
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• 2010

Hydrogen energy applications have recognized clean materials and high energy carrier. Accordingly, Hydrogen energy applies for fuel cell by Mg and Mg-based materials. Mg and Mg-based materials are lightweight and low cost materials with high hydrogen storage capacity. However, commercial applications of the Mg hydride are currently hinder by its high absorption/desorption temperature, and very slow reaction kinetics. Therefore one of the most methods to improve kinetics focused on addition transition metal oxide. Addition to transition metal oxide in $MgH_x$ powder produce $MgH_x$-metal oxide composition by mechanical alloy and it analyze XRD, EDS, TG/DSC, SEM, and PCT. This report considers kinetics by transition metal oxide rate and Hydrogen pressure. In this research, we can see behavior of hydriding/dehydriding profiles by addition catalyst (transition metal oxide). Results of PCI make a excellent showing $MgH_x$-5wt.% Sc2O3 at 623K, $MgH_x$-10wt.% $Sc_2O_3$ at 573K.

• 대한치과기공학회지
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• 제11권1호
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• pp.103-109
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• 1989

Bond strength between alloy and ceramic plays an important role in deciding the quaring the processing of metalceramic restorations. Now the author had an experiment on the measurement of bond strength differences accoding to the contents of recast alloy used during the processing of metal-ceramic restorations. In the experiment, Anusavice's Planar Interface Shear Bond Test was employed to determine the bond strength. Total 25 specimens were divided as 5 groups, that is, 5 specimens in a group respections : Group I (new alloy 100%) Group II (new 75%$\cdot$recast 25%), Group III (new 50%$\cdot$recast 50%), Group IV (new 25%$\cdot$recast 75%), Group V(recast 100%). All specimens examined micropically and respective strength values of the group specimens were checked simultaneously. The results were as follows, 1. In the analtsis of variance the result showed the significant differences of 1%(P<0.01) among the each group classifid according to the recast contents. 2. When the interfaces of specimens were examined with an electron microscope, the air bubble were evenly occurred in all the specimens, and the occurrence frequencies and the sizes of air bubble were different between Group I and Group III, especially marked different Group I and Croup V. 3. In respective verification of each group through T-test, between Group I and Group II, between Group I and Group III did not show significant differences. 4. There was significant difference between Group I and Group IV, between Group I and Group V as 1%(P<0.01). 5. In the Shear Bond Test of all the groups, Croup V showed the lowest value. Explanatoion of Figures Fig 1. Main fracture type of metal-porcelain interlace showed in group I, II, III from shear Bond Test resets. Fig 2. Main fracture type of metal-porcelain interface showed In group Ⅳ, Ⅴ form shear Bond Test resets. Air bubble and their size appeared around interface of metal-porcelain. Fig 3. Group I, Fig 4. Group II Fig 5. Group III, Fig 6. Group IV, Fig 7. Group V.

• 대한치과기공학회지
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• 제35권4호
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• pp.359-364
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• 2013

Purpose: This study was to observe characteristic of metal oxidation and bonding strength according to composition of Ni-Cr alloy for porcelain fused to metal crown. The three kinds of Ni-Cr alloy with different composition ratio of parent metal were observed general properties and chemical properties of each alloy surface and measured the shear bonding strength between ceramic and each alloys. The aim of study was to suggest the material for design of parent metal's composition ratio to development of alloy for porcelain fused to metal crown. Methods: The three kinds of alloy as test specimen was Ni(59wt%)-Cr(24wt%), Ni(67wt.%)-Cr(16wt.%) alloy and Ni(71wt%)-Cr(12wt%)alloy. The oxide on surface was observed by EDX. And the shear test was performed by MTS. Results: The surface property and oxide characteristic analysis of oxide layer, weight percentage of Element O within $Ni_{59}Cr_{24}$ alloy measured 23.03wt%, $Ni_{67}Cr_{16}$ alloy measured 21.13wt% and $Ni_{71}Cr_{12}$ alloy was measured 48.55wt%. And the maximum shear bonding strength was measured 58.02Mpa between $Ni_{59}Cr_{24}$ alloy and vintage halo(H2 group). Conclusion: The surface property and oxide characteristic three kind of Ni-Cr alloy was similar. and shear bonding strength showed the highest bonding strength in H2 specimens.

• Journal of Welding and Joining
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• 제23권6호
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• pp.99-105
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• 2005

The mixing ratio effect of the GTD-111(base metal) powder and the GNI-3 (Ni-l4Cr-9.5Co-3.5Al-2.5B) powder on TLP(Transient Liquid Phase) bonding phenomena and mechanism was investigated. At the mixing ratio of the base metal powder under $50wt\%$, the base metal powders fully melted at the initial time and a large amount of the base metal near the bonded interlayer was dissolved by liquid inter metal. Liquid insert metal was eliminated by isothermal solidification which was controlled by the diffusion of B into the base metal. The solid phases in the bonded interlayer grew epitaxially from the base metal near the bonded interlayer inward the insert metal during the isothermal solidification. The number of grain boundaries farmed at the bonded interlayer corresponded with those of base metal. At the mixing ratio above $60wt\%$, the base metal powder melted only at the surface of the powder and the amount of the base metal dissolution was also less at the initial time. Nuclear of solids firmed not only from the base metal near the bonded interlayer but also from the remained base metal powder in the bonded interlayer. Finally, the polycrystal in the bonded interlayer was formed when the isothermal solidification finished. When the isothermal solidification was finished, the contents of the elements in the boned interlayer were approximately equal to those of the base metal. Cr-W borides and Cr-W-Ta-Ti borides formed in the base metal near the bonded interlayer. And these borides decreased with the increasing of holding time.

• 한국재료학회지
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• 제15권7호
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• pp.439-443
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• 2005

The oxidation behavior and the thermal stability of nanocrystalline Al-25Ti-8Mn intermetallic compound were investigated. $Al_3Ti$ intermetallic compound, which has a potential for high temperature structural material, was fabricated by mechanical alloying(MA) with $8at.\%$ Mn to enhance the thermal stability and ductility. And Al-25Ti-8Mn intermetallic compound was sintered by spark plasma sintering(SPS) at $700^{\circ}C$. After sintering process, cubic $Ll_2$ structure was maintained without phase transformation and the grain size was about 50nm. To investigate the oxidation behavior of the specimens, thermal gravimetric analysis(TGA) was performed at 700, 800, 900, and $1000^{\circ}C$ for 24 h in $O_2$. As the temperature increased from $700^{\circ}C\;to\;900^{\circ}C$ the weight gain of specimens increased. However at $1000^{\circ}C$, unlike the oxidation behavior of $700^{\circ}C\;to\;900^{\circ}C$, the weight gain of specimen decreased drastically and the transition from linear rate region to parabolic rate region occurred rapidly due to the dense $\alpha-Al_2O_3$.

• 비파괴검사학회지
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• 제24권1호
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• pp.29-37
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• 2004

22Cr-5Ni 2상 스테인리스강의 합금원소 중 몰리브덴(Mo) 원소를 텅스텐(W)으로 치환하여 크리프거동에 미치는 영향을 조사하였다. 그리프시험은 $600^{\circ}C$와 $650^{\circ}C$의 온도에서 실시하였다. $650^{\circ}C$ 크리프 시에는 취약한 금속간화합물인 ${\sigma}$상이 석출하였으며 이것은 크리프수명을 급격히 감소시키는 역할을 하였다. Mo에 대한 W원소의 치환은 일반적으로 ${\sigma}$상의 석출을 지연시킨다고 알려져 있으나, 2wt.%까지 W 치환을 실시한 본 연구범위에서는 크리프 수명 및 최소 크리프속도에 뚜렷한 영향을 미치지 못하였다. 크리프손상의 정도를 평가하기 위하여 크리프시편에 대한 초음파검사를 실시하였다 크리프온도 $600^{\circ}C$에서는 크리프시편의 수명이 증가함에 따라 음속이 비례적으로 증가하였으나 $650^{\circ}C$에서는 반대로 감소하였다.

• 대한치과재료학회지
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• 제43권4호
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• pp.317-322
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• 2016

The effect of ice-quenching after degassing on the hardness change during simulated porcelain firing in a metal-ceramic Pd-Au-Ag alloy was investigated by means of hardness test, field emission scanning electron microscopic observations, and X-ray diffraction analysis. The hardness decreased by ice-quenching after degassing, which was induced by the homogenization of the ice-quenched specimen. The decreased hardness by ice-quenching after degassing was recovered from the 1st opaque stage which was the first stage of the remaining firing process for bonding porcelain. The microstructural change showed that the increase in hardness during the remaining firing process was caused by precipitation. The ice-quenching after degassing did not affect the hardness change during the subsequent porcelain firing process.

• 전기화학회지
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• 제22권1호
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• pp.22-35
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• 2019

이차 전지의 개발이 전기자동차나 스마트그리드와 같은 중대형의 에너지저장장치로 응용범위가 확대됨에 따라 이차 전지의 경제성확보가 화두가 되고 있다. 나트륨이차전지는 리튬보다 훨씬 저렴한 나트륨원료를 사용하여 저가의 차세대 이차 전지로 크게 주목받고 있다. 이에 따라 이온 반경이 큰 나트륨이온의 삽입과 탈리를 원활하게 해줄 수 있는 음극 소재의 개발이 최근 몇 년간 활발히 수행되어 왔다. 나트륨이차전지용 음극은 세 가지의 반응 메커니즘 (층간 삽입반응, 금속-합금반응, 전환반응)을 기반한 소재들이 보고되었으며, 본 총설에서는 전환반응으로 구동하는 다양한 음극 소재들을 소개하며 나트륨 전지 셀 내 반응 메커니즘을 소개하고자 한다.