• Fire Science and Engineering
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• v.28 no.3
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• pp.55-61
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• 2014

This study was performed to test the combustive properties of pinus rigida specimens treated with methylpiperazinomethyl-bis-phosphonic acid $M^{n+}$ ($PIPEABPM^{n+}$)s and methylpiperazinomethyl-bis-phosphonic acid (PIPEABP). Pinus rigida Plates were painted in three times with 15 wt% $PIPEABPM^{n+}s$ and PIPEABP solutions at the room temperature respectively. After drying specimen treated with chemicals, combustive properties were examined by the cone calorimeter (ISO 5660-1). It was indicated that the specimens treated with $PIPEABPM^{n+}s$ showed the lower speed to peak mass loss rate ($MLR_{peak}$), (0.104~0.121) g/s than that of PIPEABP plate. In adition, the specimens treated with $PIPEABPM^{n+}s$ showed both the lower total smoke release rate (TSRR), (224.4~484.0) $m^2/m^2$ and $CO_{mean}$ production (0.0537~0.0628) kg/kg than those of PIPEAB plate. Especially, for the specimens treated with $PIPEABPM^{n+}$ by reducing the smoke production rate except 2nd-smoke production rate (2nd-SPR), (0.0254~0.02270) g/s treated with $PIPEABPNi^{2+}$, 2nd-SPR (0.0117~0.0146) g/s was lower than that of PIPEABP plate. Thus, It is supposed that the combustion-retardation properties were improved by the partial due to the treated $PIPEABPM^{n+}s$ in the virgin plate.

• Applied Chemistry for Engineering
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• v.26 no.4
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• pp.505-510
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• 2015

This study was performed to test the combustive properties of pinus rigida specimens treated with methylpiperazinomethyl-bis-phosphonic acid $M^{n+}$ ($PIPEABPM^{n+}$)s and methylpiperazinomethyl-bis-phosphonic acid (PIPEABP). Each pinus rigida plates were painted three times with 15 wt% $PIPEABPM^{n+}s$ or PIPEABP solutions at the room temperature. After drying specimens treated with chemicals, combustive properties were examined by the cone calorimeter (ISO 5660-1). It was indicated that the speed to peak mass loss rate ($MLR_{peak}$), (0.104~0.121) g/s for specimens treated with $PIPEABPM^{n+}s$ was lower than that of PIPEABP plate. In addition, the total smoke release rate (TSRR), $(224.4{\sim}484.0)m^2/m^2$ for $PIPEABPM^{n+}s$ treated specimens except specimen treated with PIPEABPAl3+ and $CO_{mean}$ production (0.0537~0.0628) kg/kg was smaller than that of PIPEABP plate. In particular, for the specimens treated with $PIPEABPM^{n+}$ by reducing the smoke production rate, the second-smoke production rate (2nd-SPR) $(0.0117{\sim}0.0146)m^2/s$ was lower than that of PIPEABP plate. It can thus be concluded that combustion-retardation properties of the treated $PIPEABPM^{n+}s$ were partially improved compared to those of the virgin plate.

• Fire Science and Engineering
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• v.29 no.5
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• pp.7-13
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• 2015

This study was performed to test the production of combustion toxic gases by Pinus rigida specimens treated with various types of methylpiperazinomethyl-bis-phosphonic acid $M^{n+}$ ($PIPEABPM^{n+}$) and methylpiperazinomethyl-bis-phosphonic acid (PIPEABP). Three coats of 15 wt% $PIPEABPM^{n+}$ and PIPEABP solutions were applied to plates of Pinus rigida at room temperature. After drying the treated specimens, the production of combustion toxic gases was examined using a cone calorimeter (ISO 5660-1). The specimens treated with $PIPEABPM^{n+}$ showed lower carbon monoxide production ($CO_{2\;peak}$; 0.0136~0.0178% at 532~678 s) than the PIPEABP plates, except for the specimen treated with $PIPEABPFe^{3+}$. In addition, the peak carbon dioxide production ($CO_{2\;peak}$) was lower (0.03648~0.3648% at 373~433 s) than that of the PIPEABP-treated plate. Notably, oxygen production was much higher than 15%, which can be fatal to humans. Therefore, the resulting risk could be eliminated. The results indicate that the combustion toxicities were partially decreased due to treatment of the virgin plate with $PIPEABPM^{n+}$.

• Resources Recycling
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• v.22 no.6
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• pp.73-80
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• 2013

Marine mineral resources are classified into submarine and seawater mineral resources. In seawater, huge amounts of useful minerals, such as uranium, lithium, magnesium, aluminum, zinc, iron, silver, copper, vanadium, nickel, titanium and cobalt are present. If the rare metals recovery technology from seawater is developed, the commercialization of the precess will be possible. For the 21st century, countries rich in resoures tend to weaponize the resources, according to the depletion of reserves and quality degradation of metal resources in the land. Therefore, Korea that relies on imports for most of the metal resources, should focus on the research and development of the rare metals recovery technology from seawater by using the geographical characteristics of the country that is on three sea-sides.

• Journal of the Korea Convergence Society
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• v.9 no.5
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• pp.151-156
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• 2018

In this study, CFRP and metal or nonmetal were bonded with adhesive and the fracture study on this material was carried out. CFRP at the upper side of specimen and metal or nonmetal were assigned at the lower side of specimen by using DCB specimen as the analysis condition. And it was desribed that the structural adhesive were bonded between both upper and lower sides. As this analysis result, the least equivalent stress was shown at the specimen bonded with aluminium. The maximum shear stress was shown to become lowest at the de-bonded CFRP specimen when titanium was used. In conclusion, it was shown that the deformation of specimen became lowest when titanium was used. On the basis of this study result, the esthetic sense can be shown as the fracture data of bonded interface using adhesive are grafted onto the real life.

• Elastomers and Composites
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• v.47 no.3
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• pp.210-215
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• 2012

Whitening phenomena of the EPDM composites with different inorganic filler compositions which were aged at $90^{\circ}C$ for 7 days in air and tap water atmospheres, respectively, were investigated. The aged samples in tap water containing stearic acid exhibited severe whitening phenomena, while all the samples aged in air did not show any whitening. Depending on the filler compositions, there was no big difference in the whitening phenomena. The whitening materials were analyzed using gas chromatography/mass spectrometry (GC/MS), image analysis, energy-dispersive X-ray spectroscopy (EDX), and attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR). The whitening materials were identified to be salts of stearic acid. The salts of stearic acid were formed by reaction of metal cation in tap water and stearic acid in the sample.

• The Journal of the Korea institute of electronic communication sciences
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• v.9 no.2
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• pp.161-166
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• 2014

This Electromagnetic metal piece detection sensor, having high sensitivity even under high humidity and dust density, using LVDT was investigated. Metal detection characteristics using phase detection method, for 3 frequencies covering ELF and LF band, were experimentally measured. It was found that the sensitivity for metal and animal food, in which metal piece was included, was exponentially increased as frequency increased. Reducing cutoff frequency of LPF after PD was found to be effective to proportionally increase sensitivity. Also the sensitivity of metal piece detection was enhanced by optimizing BPF bandwidth and SNR. Metal piece detection limit using available ferrous test samples was found to be 0.7mm diameter from the experiment using 50kHz, in ELF band, which was known to have better selectivity to animal food. is an example of ABSTRACT format.

• Proceedings of the KSME Conference
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• 2005.11a
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• pp.138.2-138.2
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• 2005

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.103.1-103.1
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• 2018

기존의 연성인쇄회로기판(FPCB)은 top down방식에 의한 에칭기술이 일반화되어 있으나, 고가의 장비를 사용한 제조방식과 복잡한 공정으로 인하여 품질수준은 높은 편이나 제조단가가 매우 비싼 편이다. 기존의 값비싼 top down방식을 대체하여 저렴한 가격으로 FPCB를 대체하려는 기술들이 지속적으로 연구되고 있다. 그중에서 가장 기술개발이 활발한 분야가 인쇄(잉크젯 혹은 레이저)방식이지만 아직 인쇄노즐의 크기와 잉크의 전도도에 한계가 있어 사용에 많은 제약이 있다. 그러나 금속미세회로(MMP)기술은 도금방식에 의한 bottom up기술로 회로의 정밀도와 전도도가 높으면서 연속제조방식에 의한 대량생산이 가능하므로 저렴하게 생산할 수 있어, 기존의 FPCB제조공정을 대체할 기술로 각광받고 있다.

• Proceedings of the KAIS Fall Conference
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• 2008.11a
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• pp.93-96
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• 2008

500나노 입자 및 기본 물성이 우수한 이중층상구조금속수화물(LDH)를 합성하고 PVC 수지에 적용하여 고온, 저온열안정성 및 가공특성으로 인장강도, 신율, 체적저항 등이 우수한 시제품을 합성한 후 개발한 이중층상구조금속수화물(LDH) 시제품을 사용하여 무독성안정제(금속석검계), 내외부활제류, 가공조제, 산화방지제 등 기타 첨가제 등을 사용하여 PVC수지에 적용하여 수지배합에 따른 시험편을 제작하여 배합비별로 고온, 및 저온열안정성, 체적고유저항, 가공성(인장강도, 신율 등), 내후성, 초기 착색성 등 물성, 기계적 가공특성 및 성능이 우수한 할로겐수지용 무독성배합을 개발한다. 최종적으로 개발한 이중층상구조금속수화물(LDH)을 사용하여 제조하여 PVC 수지의 열안정성 및 기계적 가공특성이 우수한 중금속계대체용 무독성복합열안정제를 개발하였다.