• Journal of Conservation Science
• /
• v.29 no.3
• /
• pp.287-296
• /
• 2013

Excavated iron objects are preserved in stable condition through processes of conservation treatment because they are found in the form of various corrosion products. However, the conservation treatment leads to re-corrosion over time and accordingly, iron objects can be severely damaged, and therefore fundamental measures need to be prepared to control it. In this study, the types and characteristics of corrosion products were scientifically analyzed according to the re-corrosion of iron artifacts. In addition, the stability of the corrosion products was evaluated by exposing the standard samples under the re-corrosion environment. Re-corrosion proceeded with weeping in reddish brown on the cracks of iron artifacts. Weeping was detected akagan$\acute{e}$ite had a low hydrogen ion concentration and high chloride ion. The selection of standard sample goethite, lepidocrocite, hematite, and magnetite, were evaluated corrosive by weeping. After the samples were immersed in HCl(pH 1), $H_2SO_4$(pH 1), $H_2O$(pH 6) solution, they had been maintained for 180 days in relative humidity of 20%, 50%, 80% to investiage the changes of chemical components. As a result of analysis, the changes of chemical components were not showed in goethite, lepidocrocite, and hematite. But magnetite was changed to lepidocrocite in solution including chloride ion($Cl^-$) and to goethite and lepidocrocite solution including sulfuric acid($SO{_4}^{2-}$). Results of the study, in the case of magnetite known as s stable corrosion compound, it was identified the corrosion of magnetite occurs by corrosive ions, which means weeping generated in the iron artifacts can corrode magnetite as well as base metal.

• Journal of Conservation Science
• /
• v.30 no.3
• /
• pp.263-275
• /
• 2014

It's shown how to proceed the study on Manufacturing techniques & Conservation to the Iron Pot from Cheonmachong Ancient Tomb(the 155th Tomb in Hwangnam-dong). In order to investigate manufacturing techniques of the Iron Pot, some parts of the relic were gathered. After mounting, polishing and etching on the relic, analyzing the metal microstructure was conducted. Also it's conducted a SEM-EDS analysis on the nonmetallic inclusion. White iron structure was observed in the metallurgical structure inspection, SEM-EDS analysis. It seems to be dried slowly at room temperature after casting, doesn't look as particular heat treatment to improve brittleness. It is estimated that it's as the handle seam side were verified about 3cm inch wide, 1.5 thick in center of body, so 2 separate half-completed products was cast with width-type mould. The manufacturing techniques Using white cast iron structure, width-type mould are observable to the Iron Pot excavated from Sikrichong Ancient Tomb & Hwangnamdaechong grand Ancient Tomb around those were constructed the same time. It's able to recognize that it's almost identical manufacturing techniques at that time. Conservation is generically following those are survey of pretreatment, foreign material removal, stabilization, restoration and color matching in the order. cleaning & drying were added to the process as occasion demands. The strengthening treatment were difficult with artifact's volume, low concentration Paraloid NAD-10 solution was spread two or three times with a brush, surface hardening also came up with 15wt% Paraloid NAD-10 solution after the conservation was complete. There were connection & restoration for the restoration to the damage after modeling forms that it's similar to damaged parts by using the Fiber Reinforced Plastic resins(POLYCOAT FH-245, mold laminated type). Throughout this research, capitalizing on accumulations of measurements about the production technique of Iron Pot in the time of the fifth and 6th centuries is no less important than the Iron artifact's conservation for a better study in the future.

• Analytical Science and Technology
• /
• v.11 no.4
• /
• pp.316-320
• /
• 1998

An image analysis was used for the interpretation of microstructures of ferrous metal artifacts. For the purposes, various microstructural features such as average grain size, phase area, shape factor, and composition of the inclusions, were parameterized for the information about manufacturing techniques such as casting, heating and tempering. The carbon content was determined through the evaluation of the amount of pearlite phase. As the amount of pearlite phase increased the shape factor also increased. Grain size was relatively smaller in trans-section than in cross-section. The manufacturing direction was trans-sectional because the orientation of inclusions was elongated lengthwise. All inclusions was of silicate groups and the manufacturing temperature was estimated up to $1450^{\circ}C$.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2015.11a
• /
• pp.172-173
• /
• 2015

3D 프린터를 이용하면 짧은 시간에 복잡한 3차원 형상을 제작하는 것이 가능하며 적층하는 횟수를 조절하여 제작물의 크기와 모양, 두께를 쉽게 조절할 수 있다. 또한, 표면 열처리 기술을 적용하여 열로 표면을 처리하게 되면 매끄러운 표면 도출과 함께 외부 충격에 대한 내구성 및 접착력을 향상시킬 수 있다. 이러한 표면처리 기술은 촉각패턴과 표면과의 접착력의 제어가 가능하기 때문에 종이뿐만 아니라, 플라스틱, 금속, 세라믹 등 다양한 소재로 이루어진 표면에 적용이 가능하다. 따라서 본 연구에서 제안하는 3D 프린팅 기술과 표면 열처리 방식을 이용하면 기존의 점자 제작 방식을 개선할 수 있으며 기존 방법으로 표현하기 어려웠던 교과서 내에 삽입된 다양한 유물이나 동식물의 성장 과정 모델 등의 학습 자료를 입체적으로 만들 수 있다.

• 보존과학연구
• /
• s.14
• /
• pp.1-34
• /
• 1993

1. Metallurgical Properties of Iron artifacts excavated from Yangju-Mountain fortress were studied for the scientific conservation and metallurgical history of ancient Iron artifacts.2. Iron artifacts form Yangju-Mountain fortress were found to be the products of having well-established Carburizing and remelting technique in that period.3. These artifacts seem to be manufactured from very pure ores, because very pure ferrite structure and low impurity.4. Especially evidence of very suitable carburizing technic well-established and usealloying method of Fe-C system on purpose were found.5. Cast iron artifacts were found to be eutectic composition (4.31%) having lowestmelting point in Fe-C system.

• Conservation Science in Museum
• /
• v.9
• /
• pp.105-116
• /
• 2008

The Conservation Science Team of National Museum of Korea has established the data base of lead isotope ratio as the scientific research of bronze patina, which was acquired from conservtion process of metal objects, and based on this result, it intends to conduct the research related to the origin of raw material for the bronze objects. As the equipment for analysis of lead isotope ratio of the bronze patina, the thermal ionization mass spectrometer(TIMS) was used. As a part of this study, in 2nd year 2008, lead isotope ratios of total 18 samples inclding 2 samples of Round-type gold-bronze belong to Baekje period, the 2 items of head of bronze arrow belong to Nangnang(Lelang) and 10 items of the flower-shaped bronze dishes from the Unified Silla period, the 4 items of the bronze patina from the objects(era of 1 item not identified) of Wonpungtongbo(year 1078-North Sung) were analyzed.

• 보존과학연구
• /
• s.27
• /
• pp.165-180
• /
• 2006

The research was conducted to understand type of iron used by those who lived at dwelling site of Yangsoo-ri in between the first century B.C. and the first century A.D. to make steel products and their technique such as steel making process and heat treatment, based on micro structure information obtained through microscopic metallographic structure analysis with SEM-EDS of six steel productsexhumed at the site. Key findings are summarized as below. In the sense that Si-Ca-Al style and less than 0.5% of Ti were found in the non-metallic inclusion, the material used for forged iron ware was magnetite resolved in that. It is, however, unclear whether magnetite was resolved at high temperature or at low temperature. Microscopic structure analysis revealed that forged steel products were made through repeated hot working, the technique of molding by hitting after heating in the process of resolving and molding iron. As a result, the iron used here for the products was not the iron ore which was produced through resolution from discarded cast iron axe, ingot iron. It is probable that to make those steel products, disposed-of cast iron was reused after being molded by decarburizing. Although a few of relics were analyzed for the research, they were of critical importance in defining the process of ironware production from the first century B.C. and the first century A.D. at the Yangsoo-ri region. Judging from the iron from A-19 dwellingsite, it is possible to conclude that the iron was manufactured from cast iron decarburized and yet more research has to be done into relics yetto be exhumed in order to ascertain the finding. All of these findings are believed to play a critical role in further studies to define the steel-manufacturing technique used on the central Korean peninsular in the ancient times.

• Korean Journal of Heritage: History & Science
• /
• v.54 no.1
• /
• pp.4-17
• /
• 2021

This study analyzed 19 samples of harness fittings and pendants, which were excavated in Tomb No. 15 in Songhyeon-dong, Changnyeong. Harness fittings and pendants are used for ostentation, rather than practicality, and were excavated from ancient tombs in Gaya culture. So, they are considered artifacts that compare the production techniques and raw materials. This study aimed to examine the production techniques and provenience studies of Bihwa Gaya, which is estimated to be from the 5th to 6th centuries. According to the research, harness fittings were made of pure copper and were gilded with Au·Ag alloys on their surfaces. Hg was detected together and plated with a mercury amalgam method. As a result of the pendant (fish scales-pattern, oval and fish-tail shape), analysis showed that Fe in the background metal, Cu in the middle layer, and Au and Ag on the surface were the main components. The method of adhesion between Cu and Au·Ag gilded layers are plated by a mercury amalgamation method. So, it was identified by the gilt-iron·gold·bronze technique. Since the pendant (heart shaped) is found to be the main component of Fe in the background metal and Ag in the surface layer, the metal was made gilt-iron·silver technique. The background metal and gilding were additionally fixed using a rivet. The raw materials of 3 harnesses excavated from Changnyeong are plotted in zone 2 in the southern Korean Peninsula. And 16 harnesses were plotted in Chinese copper ore by Mabuchi Hishao in the Chinese Peninsula.

• Conservation Science in Museum
• /
• v.29
• /
• pp.33-46
• /
• 2023

Modern and contemporary cultural assets are defined as a collective term for tangible historical and cultural assets produced in the modern and contemporary period (around the opening of Joseon to the present) in Korea. Among them, rickshaws have been used as a major means of transportation for about 40 years since the opening of the ports in Joseon. The repair process for rickshaws divides the rickshaw into three parts, namely the body, the cover, and the wheels, applying a plaster treatment process by referring to the outcomes of the condition assessment and material analysis for the metal, wood, fiber, and paint used. Overall, the repair process is carried out through dry/wet cleaning, joining, stabilization, reinforcement of damaged parts, and other restoration treatments, which reveal metal decorations and patterns on the scaffolding (flowers, arabesque patterns, etc.) that were previously not observable with the naked eye, while also adding to the stability of the artifact. In addition, props were produced to ensure the artifact's safe exhibition.

• Journal of Conservation Science
• /
• v.25 no.3
• /
• pp.273-282
• /
• 2009

As a result of investigating research papers concerning the metal bound rim decoration on four pieces of 'Bowl, white porcelain with impressed floral design and sliver bound rim' and one piece of 'Bowl, white porcelain with sliver bound rim' from among the Jingdezhen white porcelain, which are Sinan remains that are kept in a National museum of Korea. It was found that the material of the bound rim was not silver but tin, and lacquer was used as glue. Based on such a scientific analysis, this study conducted a reproduction test of the manufacturing technique and the bonding method of the metal bound rim attached to the upper tip of the china ware. As a way of reproducing the bound rim, the study was able to discover the best method in terms of the avoidance of loss of materials and the workability out of various cutting methods for tin plates, and it also discovered that the use of lacquer in mixture with soil showed a better workability than the use only of a lacquer ingredient in a test of the bonding method of a metal bound rim using lacquer. Also, in the test of a drying method, a bonding method after drying within a short time at a relatively high temperature was found to be more effective than the drying method after humidifying at a normal temperature, which is used in traditional lacquer ware preservation treatment.