• Title/Summary/Keyword: 그라이트

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Trend and Future Strategy of Ammonia Gas Recovery based on Adsorption from Livestock Fields (축산현장에서 발생된 암모니아 기체의 흡착기반 회수 동향 및 향후 전략)

  • Sangyeop Chae;Kwangmin Ryu;Sang-hun Lee
    • Resources Recycling
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    • v.32 no.6
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    • pp.45-53
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    • 2023
  • This study discussed the trend and future strategy of adsorption technology R&D to effectively recover ammonia emitted from the livestock fields. A proper ammonia adsorbent should incorporate acidic or hydrogen bonding functional groups on the surface, as well as a high specific surface area and a good surface structure appropriate for ammonia adsorption. Activated carbon and minerals such as zeolite have widely been used as ammonia adsorbents, but their adsorption effects are generally low, so any improvement through surface modification should be necessary. For example, incorporation of metal chloride included in a porous adsorbent can promote ammonia adsorption effectiveness. Recently, new types of adsorbents such as MOFs (Metal-Organic Frameworks) and POPs (Porous Organic Polymers) have been developed and utilized. They have shown very high ammonia adsorption capacity because of adjustable and high specific surface area and porosity. In addition, Prussian Blue exhibited high ammonia adsorption and desorption performance and selectivity. This looks relatively advantageous in relation to the recovery of ammonia from livestock waste discharge. In the future, further research should be made to evaluate ammonia adsorption/desorption efficiency and purity using various adsorbents under conditions suitable for livestock sites. Also, effective pre- and/or post-treatment processes should be integrated to maximize ammonia recovery.

A Preliminary Study of The Singer-Loomis Type Deployment Inventory for the Korean Version (싱어 루미스 심리 유형 검사의 한국판 제작을 위한 예비연구)

  • Hyoin Park
    • Sim-seong Yeon-gu
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    • v.28 no.2
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    • pp.139-153
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    • 2013
  • Psychological typology in analytic psychology is used not only for ascertaining the attitude or function of the conscious ego, but also as one blueprint for the individuation process. We all know the need to emphasize an awareness of the deployment and development of the superior function, the secondary function, the third function and the inferior function for the individuation process. This study has the goal of refining our awareness of this deployment and development of typological functions. The questionnaires of the Myers-Briggs Type Inventory and the Gray Wheelwrights Jungian Type Survey use the method of a forced-choice questionnaire, on the assumption of a bi-polarity hypothesis. But the questionnaire of the Singer-Loomis Type Deployment Inventory uses the Likert scale. It is able to show the deployment of the superior function, the secondary function, the third function and the inferior function visibly. It allows us to test the subject at stated periods for his/her development or change of psychological typology. The Singer-Loomis Type Deployment Inventory is a statistically superior method for showing Jung's psychological typology relative to both the Myers-Briggs Type Inventory and the Gray Wheelwrights Jungian Type Survey. I have studied how the original authors of The Singer-Loomis Type Deployment Inventory understood Jung's psychological typology. I produced the reliability and the item-discrimination power of the Korean Version of the Singer-Loomis Type Deployment Inventory. On the basis of this study, I produced the revised Korean version 1 of Singer-Loomis Type Deployment Inventory.

Petrology of the Blastoporphyritic Granite Gneiss in the Southwestern Part of the Sobaegsan Massif (소백산육괴 서남부의 잔류반상 화강편마암의 암석학적 연구)

  • Lee, Choon-Hee;Lee, Sang-Won;Ock, Soo-Seck;Song, Young-Sun
    • Journal of the Korean earth science society
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    • v.22 no.6
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    • pp.528-547
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    • 2001
  • The blastoporphyritic granite gneiss (BPGN) including much alkali-feldspar megacrysts occurs in Jiri mountains area, southwestern part of Sobaegsan massif, Korea. The BPGN is formed gneiss complexes with other gneisses in Precambrian. The BPGN was named as porphyroblastic gneiss with porphyroblasts of alkali-feldspar megacrysts by other researchers, but the BPGN includes of euhedral alkali-feldspars (microcline), and the boundary with the granitic gneiss represents sharp contact as intrusive relationship. The BPGN mainly composes of alkali-feldspar megacrysts, quartz, plagioclase, K-feldspar and biotite some almandine and accessary minerals are muscovite, chlorite, apatite, zircon and opaques. The alkali-feldspar is microcline with perthitic texture. An content of plagioclases show 30 to 40. Biotites occur two type, one is Brown biotite which shows compositional ranges of Mg/Fe+Mg ratios from 0.38 to 0.52, the other is Green Bt. which is retrograde product. Camels to be various sizes and shapes have composition of almandine with 73 to 80 mole percent, but represent retrogressive zoning from core (X$_{pyr}$: 15.9${\sim}$20.8) to rim (X$_{pyr}$:13.7${\sim}$15.9) to be evidence of retrograde metamorphism. Megacrysts of alkali-feldspar in the BPGN show rectangular shape of euhedral and some become ellipsoidal or spheroidal in shape and the average size up to 20 cm long. The megacryst includes of biotite, plagioclase and quartz, and rarely euhedral apatite as inclusions. In petrochemistry the BPGN represents granodiorite composition, characteristics of peraluminous S-type granitoid and calc-alkaline features.

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Structural and Compositional Characteristics of Skarn Zinc-Lead Deposits in the Yeonhwa-Ulchin Mining District, Southeastern Taebaegsan Region, Korea Part I: The Yeonhwa I Mine

  • Yun, Suckew
    • Economic and Environmental Geology
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    • v.12 no.2
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    • pp.51-73
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    • 1979
  • The zinc-lead deposits at the Yeonhwa I mine were investigated in terms of ore-forming geologic setting, structural style of ore control, geometry of individual orebodies, zoning, paragenesis and chemical composition of skarn minerals, as well as metal grades and ratios of selected orebodies. The Yeonhwa I mine is characterized by a large swarm of chimney type massive orebodies with thin skarn envelopes, boldly developed through a thick sequence of Pungchon Limestone, the overlying Hwajeol Formation, and the underlying Myobong Slate of Cambrian age. Nearly 20 orebodies of similar shape, but of varying size are arranged in a V-shaped pattern with northwest and northeast trends, clearly indicating an outstanding ore control by a conjugate system of fractures with these trends. Important orebodies are the Wolam 1, 2, 3, and 5 orebodies in the west, and the Namsan 1, 2, 3. and 5 orebodies in the east, among others. The Wolam 1 orebody, which was observed from the -360 level through the -240, -120, and 0 levels to the surface outcrops (totaling a vertical height of about 500m), shows a vertical variation in skarn mineralogy, ranging from pyroxene-garnet zone on the lower levels. through pyroxene (without garnet) zone on the intermediate levels, and finally to rhodochrosite vein on the upper levels and surface. Microprobe analyses of pyroxene and garnet on a total of 14 mineral grains revealed that pyroxenes are manganoan salitic in most samples, with downward increase of Fe and Mn, whereas garnets are highly andraditic, containing fractions of subordinate grossular with downward decrease of Fe. This indicates a reverse relationship of Fe-contents between pyroxene and garnet with depth. Ore minerals are major sphalerite, subordinate galena, and minor chalcopyrite. Sulfide gangue minerals include major pyrrhotite, and minor pyrite and marcasite of later age. Two types of variational trends in metal grades and ratios with depth are present on the plots of assay data from the Wolam orebodies: one is a steady upward increase in Pb, Zn, and Pb:Zn ratios, with a terminal decline at the top of orebody: the other is an irregular or sinusoidal change. The former is characteristic of chimney-type orebodies, whereas the latter is of vein· shaped orebodies. The Pb grades show large variations among orebodies and from level to level, whereas the Zn grades are relatively constand or less variable.

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Petrogenesis of Plutonic Rocks in the Andong Batholith (안동저반 심성암류의 암석성인)

  • 황상구;장윤득;이윤종
    • The Journal of the Petrological Society of Korea
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    • v.11 no.3_4
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    • pp.200-213
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    • 2002
  • The Andong granitoid batholith represents five temporally distinct episodes (phases) of igneous activity. The batholith represents a plutonic complex of five pulsatively emplaced distinct intrusive multiphases. The petrochemical data show that the plutons fall into calc-alkaline series except for the Yean pluton, and plot within the diaenostic range for I-type origin and continental arc orogenic tectonic setting. Each pluton reveals systematic compositional variations of major and trace elements with $SiO_2$ or MgO, but different variation trends for some elements and considerably different REE patterns. Thus discontinuous, inconsistent variations in the elements indicate that the five plutons can not be explained by simple fractional crystallization from the same primary magma, but were intruded and solidified from the independent magmas of chemically heterogeneous origin. In the Andong, Dosan and Pungsan plutons, high values of molar CaO/(MgO+$FeO^{t}$ ) combined with low $Al_2$$O_3$/(MgO+$FeO^{t}$ ) and $K_2$O$Na_2$O ratios suggest a magma originated by dehydration melting of a metabasaltic to metatonalitic protolith. Whereas the Imha pluton show similar values of CaO/(MgO+$FeO^{t}$ ), but significantly higher ratios of $Al_2$$O_3$/(MgO+$FeO^{t}$ ) and $K_2$O$Na_2$O implying to a metagreywacke protolith.

Pyrite Content using Quantitative X-Ray Diffraction Analysis and Its Application to Prediction of Acid Rock Drainage (정량 X-선회절분석을 이용한 황철석 함량 결정과 산성 암반 배수 발생 평가에의 응용)

  • Chon, Chul-Min;Kim, Jae-Gon;Lee, Gyoo-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.2 s.48
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    • pp.71-80
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    • 2006
  • We examined the mineralogical composition of pyrite-bearing rocks by quantitative powder X-ray diffraction analysis using the matrix-flushing method and ROCKJOCK (a full pattern fitting computer program). The neutralization potential (NP) and acid generating potential (AP) were calculated on the basis of mineralogical compositions. The mineralogical AP was compared with the conventional AP calculated from bulk sulfur concentration to assess the applicability to the prediction of acid rock drainage(ARD). The pyrite content calculated by matrix-flushing method showed a high positive correlation($r^2$=0.95) with those by ROCKJOCK. The pyrite contents by matrix-flushing method was 1.45 times larger than those by ROCKJOCK. The pyrite content and mineralogical AP obtained by the matrix-flushing method had a better correlation($r^2$=0.98) with those by the total sulfur concentrations in the all samples except KB sample. The mineralogical NPs of YJ sample were 23.0 and 34.0(kg $CaCO_3$ equivalent per tonne) by matrix-flushing method and ROCKJOCK, respectively. The AP calculated by matrix-flushing method and ROCKJOCK program were 47% and 72% of those by the conventional ABA test. We hereby suggested that the quantitative analysis using XRD data can be applied to prediction of ARD. For more reliable calculation of the mineralogical NP and AP, other sulfide and carbonate minerals such as pyrrhotite, dolomite, ankerite, siderite, rhodochrosite which can affact the mineralogical NP and AP should be considered.

RGB Channel Selection Technique for Efficient Image Segmentation (효율적인 이미지 분할을 위한 RGB 채널 선택 기법)

  • 김현종;박영배
    • Journal of KIISE:Software and Applications
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    • v.31 no.10
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    • pp.1332-1344
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    • 2004
  • Upon development of information super-highway and multimedia-related technoiogies in recent years, more efficient technologies to transmit, store and retrieve the multimedia data are required. Among such technologies, firstly, it is common that the semantic-based image retrieval is annotated separately in order to give certain meanings to the image data and the low-level property information that include information about color, texture, and shape Despite the fact that the semantic-based information retrieval has been made by utilizing such vocabulary dictionary as the key words that given, however it brings about a problem that has not yet freed from the limit of the existing keyword-based text information retrieval. The second problem is that it reveals a decreased retrieval performance in the content-based image retrieval system, and is difficult to separate the object from the image that has complex background, and also is difficult to extract an area due to excessive division of those regions. Further, it is difficult to separate the objects from the image that possesses multiple objects in complex scene. To solve the problems, in this paper, I established a content-based retrieval system that can be processed in 5 different steps. The most critical process of those 5 steps is that among RGB images, the one that has the largest and the smallest background are to be extracted. Particularly. I propose the method that extracts the subject as well as the background by using an Image, which has the largest background. Also, to solve the second problem, I propose the method in which multiple objects are separated using RGB channel selection techniques having optimized the excessive division of area by utilizing Watermerge's threshold value with the object separation using the method of RGB channels separation. The tests proved that the methods proposed by me were superior to the existing methods in terms of retrieval performances insomuch as to replace those methods that developed for the purpose of retrieving those complex objects that used to be difficult to retrieve up until now.

Composting of the Pig Manure Used with the Ceramic Biocarrier (복합세라믹 담체를 이용한 돈분 퇴비화 연구)

  • Hwang, Joon-Young;Lee, Jong-Eun;Chang, Ki-Woon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.11 no.2
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    • pp.110-116
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    • 2003
  • This study was executed to evaluate the utilization and efficiency of the ceramic biocarrier as the promoter of decomposing on the organic matters for the composting using with pig manure by analyzing of the physico-chemical properties during composting. The treatments of this experiment were consisted of the control(C),microorganism(M), M with natural zeolite(M+Z), M with synthesized zeolite(M+SZ), and M with ceramic biocarrier(M+CZ). The process term of composting was conducted for 30days in the rapidly fermented machine(as pilot system). The results of the physico-chemical properties of the composts were as follows. The changes of temperature during composting was not relative with the microorganism and zeolite materials used in the composts. At all of the treatments were similar to changing of temp. from the initial stage to the final stage. But the added microorganism treatments were higher than control. And the entire pH value of treatments were appeared the same that above temperature result, also the M+CZ and M+SZ treatment among the treatment were higher. At the results of T-C, T-N and C/N ratio, in case of T-C value, the M+CZ treatment was highly more decreased than others. However at the T-N value, there were not the differences from the each treatment. And the C/N ratio was changed according to the changes of T-C and T-N value. Especially, at the M+CZ aud M+SZ treatments were remarkably reduced by about 21.4-23.3 value. In the result of G.I for evaluating of the compost humidity, the M+CZ and M+SZ treatments were close up approximately 110 value compared with the control(G.I value 100). Therefore, the examined ceramic biocarrier amended with compost-promoting-bacteria could be applied to the production of many high quality fertilizers. It is also expected that the results of this researches could be applied to the recycle of the organic wastes based on the experimental results of ceramic biocarrier and compost-promoting-bacteria application.

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Influence of Continuous Application of Gypsum, Popped Rice Hulsl and Zeolite on Soil Aggregation of Reclaimed Silt Loam Soils (석고, 팽화왕겨 및 제오라이트 연속시용이 간척지 미사질 양토의 입단화에 미치는 영향)

  • Baek, Seung-Hwa;Kim, Jae-Yeong;Kim, Seong-Jo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.2
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    • pp.41-50
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    • 2013
  • We investigated influence of continuous application of gypsum(G:$CaSO_4{\cdot}2H_2O$), popped rice hulls(H) and zeolite(Z) on soil aggregation of reclaimed silt loam soils. The application rates amended to silt loam from reclaimed soils at Saemangeum of Mangyeong were varied as follows; 1550(G1), 3100(G2), 6200 (G3) gypsum kg/10a, 1000(H1), 2000(H2), 3000(H3) popped rice hulls kg/10a, and 200(HZ1), 400(HZ2), 800(HZ3) zeolite kg/10a added to 1500 popped rice hulls kg/10a, respectively. In addition, the bermuda grass was growing, and the soil aggregates were analyzed for 60, 90 and 120 days after treatments(DAT). At 60 DAT, the effect of treatment was in order of G>H${\geq}HZ$, and the 1550kg/10a(G1) was the highest as 52.48%. At 90 DAT, the effect of treatment was also in order of G>H>HZ. Those was 3.78-3.12, 2.03-3.03 and 1.79-2.57 times in compared with the control, respectively. At 120 DAT, the effect of treatment was similar continued in order of G>H>HZ. Those was 3.00-2.20, 1.06-1.64 and 0.92-1.23 times in compared with the control, respectively. In conclusion, we found that the continuous application for two year of gypsum, popped rice hulls and zeolite was excellent above the 1 year, and the effect of the treatment for soil amendments of reclaimed silt loam soil was excellent in order of G>H>HZ.

The Effects of Marine Sediments and NaCl as Impurities on the Calcination of Oyster Shells (굴패각 소성시 해저 퇴적물과 NaCl 불순물이 소성 특성에 미치는 영향)

  • Ha, Su Hyeon;Kim, Kangjoo;Kim, Seok-Hwi;Kim, Yeongkyoo
    • Economic and Environmental Geology
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    • v.52 no.3
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    • pp.223-230
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    • 2019
  • The calcination of oyster shells have been studied as the possible substitute for the limestone used as an absorbent of $SO_2$ gas. However, since pure shells can not be used in calcination process, some impurities are contained and the changes in the characteristics of the calcination products are expected. In this study, the surface characteristics of the calcination products are investigated by mineralogical analysis according to the contents of NaCl, which can be derived from sea water, and sediments on the surface of the shell as impurities. The marine sediments on the shells were mainly composed of quartz, albite, calcite, small amounts of amphibole and clay minerals such as ilite, chlorite and smectite. After calcination of oyster shells mixed with 0.2-4.0 wt% sediments at $900^{\circ}C$ for 2 hours, regardless of the dehydration, dehydroxylation, and phase change of these minerals at the lower temperature than this experiment, no noticeable changes were observed on the specific surface area of the calcined product. However, when mixed with 0.1 to 2.0 wt% NaCl, the specific surface area generally increases as compared with the shell sample before calcination. The specific surface area increases with increasing amount of salt, and then decreases again. This is closely related to the changes of surface morphology. As the amount of NaCl increases, the morphology of the surface is similar to that of gel. It changes into a slightly angular, smaller particle and again looks like gel with increasing amount of NaCl. Our results show that NaCl affects morphological changes probably caused by melting of some oyster shells, but may have different effects on the specific surface area of calcination product depending on the NaCl contents.