• 제목/요약/키워드: 규산

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Morphological Effect of Hematite on the Synthesis of Fayalite in Reducing Atmosphere (환원성 분위기에서의 규산철의 합성에 미치는 산화 제2철의 형태학적 효과에 관한 연구)

  • 임응극;권명수
    • Journal of the Korean Ceramic Society
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    • v.12 no.4
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    • pp.37-42
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    • 1975
  • 철(II)이온을 안정화 하기위하여, 2산화 규소와, 구상, 입방체상 및 침상의 서로 다른형태의 산화 제2철로부터 규산철을 합성하였다. 메타놀증기로 포화시킨 질소까스를 튜브로에 도입시켜 얻은 환원성 분위기속에서, 114$0^{\circ}C$에서 11$65^{\circ}C$의 온도범위에서, 가스유속을 0.13 및 0.25l/min. 로서, 환원시간 4-150분동안 교상반응을 진행하였다. 반응생성의 동태를 오르자트 가스분석으로 검토하였으며, 생성물의 확인은 X-선 회절시험 및 감량정량에 의하였으며, 결과는 다음과 같다. 1 : 1.1의 몰비로 혼합한 산화제2철과 2산화 규소의 경우, 가스유속이 0.13l/min일 때, 규산철 합성반응시간은 구상, 입방체상 및 침상산화철에 있어서 각기 8-27분, 10-16분 및 6-7분으로 구상의 경우가 범위가 가장 넓었다. 또한, 반응속도는 산화제2철의 표면적의 평방근에 비례하였고 반응시간의 평방근에 역비례하였다.

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Influences of Silicate Fertilizer Application on Soil Properties and Red Pepper Productivity in Plastic Film House (규산질비료가 시설재배지 토양특성과 고추수량에 미치는 영향)

  • Ahn, Byung-Koo;Han, Soo-Gon;Kim, Jong-Yeob;Kim, Kab-Cheol;Ko, Do-Young;Jeong, Seong-Soo;Lee, Jin-Ho
    • Korean Journal of Environmental Agriculture
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    • v.33 no.4
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    • pp.254-261
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    • 2014
  • BACKGROUND: This study was conducted to investigate effects of silicate fertilizer application on red pepper (Capsicum annuum L.) productivity with improving soil chemistry under plastic film house in paddy field. METHODS AND RESULTS: The silicate fertilizer was applied as 0, 100, 200, and 300 kg/10a as basal dressing before transplanting pepper plant seedlings. Cultivar of the pepper plant was Cheon-Ha-Dae-Se. Amounts of inorganic fertilizer applied as $N-P_2O_5-K_2O$=19.0-6.4-10.1kg/10a was estimated depending on soil test values. After applying 50% of nitrogen, 100% of phosphorus, and 60% of potassium fertilizers as basal dressing, the seedlings of pepper plant were transplanted. The rests of nitrogen and potassium fertilizers were applied as side-dressing after the first, second, and fourth harvests of red pepper. When comparing selected chemical properties of soils between before transplanting and after final(the fifth) harvest, soil pH, available $P_2O_5$, and exchangeable $Ca^{2+}$ increased with increasing the applications of silicate fertilizer, whereas electrical conductivity(EC) decreased. However, exchangeable $K^+$ was higher with the treatments of 100 and 200 kg/10a, and exchangeable $Mg^{2+}$ was higher with 300 kg/10a application. In addition, nitrogen and phosphorus concentrations of red pepper collected from the first harvesting stage decreased with increasing the applications of silicate fertilizer, but potassium, calcium, and magnesium concentrations in red pepper were highest with 300 kg/10a application. Yield of red pepper increased between 9.0 and 11.8% with the applications of silicate fertilizer. Marketable fruit rate of res pepper was highest(97.3%) with 200 kg/10a application. CONCLUSION: The application of silicate fertilizer as basal dressing in paddy-converted fields improved soil chemistry and increased red pepper productivity.

Effect of Long-Term Application of Ammonium Sulfate, Urea, Composts, and Calcium Silicate on Macroelements and Rice Yields in Paddy Soil (논토양(土壤)에서 황산(黃酸)암모늄, 요소(尿素), 퇴비(堆肥) 및 규산질비료(珪酸質肥料)의 연용(連用)이 다량원소(多量元素)의 행동(行動)과 벼 수량(收量)에 미치는 영향(影響))

  • Park, Jun-Kyu;Oh, Wang-Keun;Kim, Weon-Chul
    • Korean Journal of Soil Science and Fertilizer
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    • v.23 no.4
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    • pp.287-292
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    • 1990
  • A study has been conducted since 1954 to elucidate the effects of longterm application of ammonium sulfate (AS), urea, compost, and calcium silicate(CS) fertilizers on major soil nutrients and rice yields in wetland soil. The soil pH in the AS plot become lower than that in the urea plot but had little influence on rice yield. Continuous application of AS and urea with compost and CS raised the soil pH compared with single applications of AS or urea. Soil organic matter content increased yearly in plot with no fertilizer and in those with AS and urea, and increased considerably in plots with compost and CS. Application of compost and CS promoted rice top growth as well as root growth, resulting in increased dry matter. Soil contents of N, $P_2O_5$, Ca, Mg, and $SiO_2$ in the NPK with composts plot increased considerably compared with the NPK plot; however. the exchangeable K content was rather low. Rice growth increased with compost application. which enhanced K uptake, and the coarse texture promoted K leaching. With compost and CS addition, con tents of exchangeable Ca and Mg in the AS plot decreased considerably more than in the urea plot. Probably this was the result of higher Ca and Mg precipitation by sulfate in the AS plot. The re are no significant differences in rice yield between AS and urea plots. With compost and CS treatments, rice yields increased in the AS plot compared with the urea plot. The increase in yield is considered to be the effect of S. which is a constituent of AS.

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Changes in Barley Yield and Some Physico-chemical Properties of Upland Soil by Longterm Application of Silicate Fertilizer and Compost (밭에서 규산(珪酸) 및 퇴비(堆肥)의 장기연용(長期連用)에 의한 보리수량(收量) 및 토양(土壤)의 이화학성(理化學性) 변화(變化))

  • Kim, Chang-Bae;Park, No-Kwuan;Lee, Suk-Hee;Park, Seon-Do;Choi, Boo-Sull
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.3
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    • pp.195-200
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    • 1994
  • This study was conducted to evaluate the changes in barley yield some physico-chemical properties of soils affected by annual application of N.P.K and N.P.K+silicate fertilizer 250kg/10a and N.P.K+compost 1,000kg/10a to the silty clay loam upland soil during the 18 years from 1975 to 1992. The results obtained are as follows. 1. Barley yield of the 18th year increased by 17~18% in the treatments of N.P.K+compost annually applied in comparison with N.P.K treated plot. So, simillar effect was recognized between the silicate fertilizer and the compost treatment plot. 2. The amount of nutrient's uptake by barley plant at the harvesting stage in the treats of N.P.K+silicate fertilizer and N.P.K+compost annually applied increased by 6~8% in comparison with N.P.K treated plot. Fertilizer's efficiency remarkably increased with $P_2O_5$, and $K_2O$ in the treats of N.P.K+silicate fertilizer and N.P.K+compost annualy applied comparing to N.P.K treated Plot. 3. According to soil analysis after experiment, the N.P.K+silicate fertilizer and N.P.K+compost annually applied plot were increased in soil pH, OM, available $P_2O_5$ exchangable cations and soluble $SiO_2$ content, but the content of $NO_3$-N was low. 4. Average yield of barley for 18 years increased by 22% in the treat of N.P.K+silicate fertilizer 250kg/10a annually applied plot and by 31% in the treat of N.P.K+compost 1,000kg/10a annually applied plot in comparison with N.P.K treated plot.

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Effect of Silicate on Creeping Bentgrass Growth of Green at the Golf Course during Summer in Korea (규산염의 시비가 크리핑 벤트그래스의 여름철 생육에 미치는 영향)

  • Lee, Jae-Pil;Yoo, Tae-Young;Moon, Se-Jong;Ham, Suon-Kyu;Kim, Doo-Hwan
    • Asian Journal of Turfgrass Science
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    • v.22 no.2
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    • pp.217-223
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    • 2008
  • This study was conducted to figure out the effect of silicate as growth stimulator on growth of 'Pencrosss' creeping bentgrass. Creeping bentgrass(Agrostis palustris cv. 'Pencross') at the nursery of Sinwon Country Club was used. Silicate was applied at the concentration of 0, $200{\times}$, $500{\times}$, $1.000{\times}$. Polt size was 1 by 2 meter and there were three replications with completely randomized design(CRD). Creeping bentgrass growth was evaluated with visual turf grass quality, root length and No. of tiller density(ea/$cm^2$). Results of this study are as followings; 1. Average root length with silicate was $1.5{\sim}1.9cm$ longer than control. Especially, Root length of silicate was $7{\sim}8cm$ in summer. 2. Tiller density with silicate was $l8{\sim}22ea/cm^2$, $0.4{\sim}2.l$ less than control. But there was no significant difference. 3. Visual turfgrass quality with silicate was $5.0{\sim}8.3$, $0.3{\sim}1.5$ higher than control. But there was no significant difference. In conclusion, silicate might be grown as root growth stimulator of creeping bentgrass during summer in Korea. However, this study was conducted under one year. Accordingly, in-depth experiment should be done over several years.

Silicon Supply through Subirrigation System Alleviates High Temperature Stress in Poinsettia by Enhancing Photosynthetic Rate (저면공급한 규소에 의한 포인세티아의 광합성 능력 향상과 고온 스트레스 경감)

  • Son, Moon Sook;Park, Yoo Gyeong;Sivanesan, Iyyakkannu;Ko, Chung Ho;Jeong, Byoung Ryong
    • Horticultural Science & Technology
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    • v.33 no.6
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    • pp.860-868
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    • 2015
  • The effect of Si supplied during plant cultivation on tolerance to high temperature stress in Euphorbia pulcherrima Willd. 'Ichiban' was investigated. Rooted cuttings were transplanted into 10-cm pots and a complete nutrient solution, containing 0 or $50mg{\cdot}L^{-1}$ Si as either $K_2SiO_3$, $Na_2SiO_3$, or $CaSiO_3$, was supplied through subirrigation or weekly foliar applications. After two months of cultivation, plants were placed in an environment-controlled chamber and subjected to $35{\pm}1^{\circ}C$ (high temperature) conditions for 18 days. Enhanced specific activities of enzymatic antioxidants (APX) and suppressed specific activities of non-enzymatic antioxidants (ELP) were observed in the high temperature-stressed plants with Si application. The Fv/Fm (maximum quantum yield of photosystem II), photosynthetic rate, and Si contents in the shoot increased in the treatments of $K_2SiO_3$ and $Na_2SiO_3$ supplied through subirrigation. The Si-treated plants had more tolerance of high temperature stress than the control plants. Of the Si sources and application methods tested, $K_2SiO_3$ and $Na_2SiO_3$ supplied through subirrigation were found to be the most effective in enhancing tolerance to high temperature stress.

Varietal Differences in Physiological Characteristics Focussed on N. P. K and Si Uptake under Cold Temperature at Seedling Stage (묘대기(苗垈期) 수도품종별(水稻品種別) N, P, K, Si 함량(含量)에 미치는 저온처리와 질소(窒素) 및 인산증시의 영향(影響))

  • Seok, Soon-Jong;Ryu, In-Soo;Ha, Ho-Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.2
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    • pp.183-187
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    • 1983
  • The investigate the varietal differences is physiological characteristics related to nutrient uptake and response to nitrogen and phosphorus, a pot experiment was conducted in a temperature control chamber. Three varieties with different cold resistances were grown under normal ($23^{\circ}-25^{\circ}C$) and cold ($15^{\circ}C$) conditions with three nitrogen and phosphorus application levels. The cold temperature was treated for twelve days after thirty days from seeding. The results were summarized as follows: 1. Dry weight and nutrient contents were reduced in cold temperature treatment compared with control and the reduced ratio by low temperature were in order of dry weight 29.4% $P_2O_5$ 21.3%, N 15.3%, $K_2O$ 10.1%, $SiO_2$ 8.7%. 2. The reduced ratio of phosphorus contents of each varieties to normal condition were 13.5% in resistant, 19.5% in medium, 31.1% in susceptible variety, respectively. 3. The phosphorus and silicate contents of plants showed a good relationship with varietal differences in cold resistance but nitrogen and potassium didn't showed, therefore, phosphorus and silicate contents might be used as the index for physiological characteristics related with cold resistance. 4. Phosphorus content slightly increased with nitrogen application but silicate content decreased. Upon phosphorus application, nitrogen and silicate contents were increased.

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Effects of Silica and Compost Application on the Availability of Accumulated Phosphate in Paddy and Upland Soils (축적인산(蓄積燐酸) 유효화(有效化)에 미치는 규산(珪酸)과 퇴비(堆肥)의 시용효과)

  • Lee, Chun-Hee;Cheon, Seong-Gun;Shin, Won-Kyo;Ha, Ho-Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.23 no.4
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    • pp.281-286
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    • 1990
  • Field experiments were conducted to avail the accumulated phosphorus by silica 200kg/10a and compost 2,000kg/10a instead of phosphate fertilization in 1988 to 1989. Cultivated varieties were Dongjinbyeo in paddy soils of Av. $P_2O_5$ 233ppm, and Baegunkong in upland soils of Av. $P_2O_5$ 530ppm. The results were as follows. 1. Available phosphorus in the soil was increased about 60ppm in silica and compost application compared with control. Its increment rate by silica and compost application was higher in paddy soils than in upland soils. 2. Absorbed phosphorus by plant was increased in silica and compost application compared with control, whose difference was higher in soybean plant than in rice plant. 3. Amount of absorbed phosphorus in plant was negative in relation to soil DTPA-Fe, but was positive in relation to soil reduction and root nodule of soybean. 4. Persistence rate of phosphorus was about 80 percent in compost application and 100 percent in phosphate fertilization compared with control, and it was apt to decrease by silica. 5. The yield of rice was no difference between with and without phosphate fertilization, but the yield of soybean was increased 5 percent in none application compared with phosphate fertilization.

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Occurrence and Mineralogy of Serpentine Minerals in the Calc-silicate Rock Sheets from the Bonghwa Area, Kyungsangbuk-do (경북 봉화지역의 석회규산염층에서 산출되는 사문석광물의 산상 및 광물학적 특성)

  • Bae, Sung-Woo;Hwang, Jin-Yeon;Lee, Son-Kap;Kwack, Kyu-Won;Yoon, Ji-Hae;Cho, Sung-Hwi
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.1
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    • pp.85-98
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    • 2008
  • Calc-silicate rock sheet occurs within the Precambrian metasedimentary rocks in Bonghwa area, Kyungsangbuk-do, Korea. The calc-silicate rock runs parallel to bedding plane with $14{\sim}18$ meters in width. Calcite, dolomite, serpentine and tremolite are occurred as major minerals and talc is occurred as a miner mineral. Serpentine mainly occurs in the upper part and tremolite occurs in lower part of calc-silicate rock sheet. Colors of calc-silicate rock change to deeper green with increasing amounts of serpentine mineral. XRD, FT-IR analyses indicates that serpentine mineral is antigorite. Platy structure of antigorite is well observed by SEM analysis. EPMA data indicates that chemical composition of antigorite is very close to ideal ($SiO_2$: 44.3 wt% and MgO: 40.8 wt%). The chemical formula of antigorite is calculated as $Mg_{2.82}Al_{0.04}Fe^{3+}_{0.04}Si_{2.05}O_5(OH)_4$. From careful study by comparing mineralogical analysis data and occurrence, calc-silicate rock sheet was formed by metamorphism of calcareous sedimentary rocks having different mineralogical and chemical compositions. It is considered that the host rock of serpentine enriched upper part was more Mg-rich rocks than the host rocks of tremolite enriched lower part.

Influence of Silicate Application on Rice Grain Quality (규산 시용이 미입의 품질에 미치는 영향)

  • Kang, Yang-Soon;Lee, Jong-Hoon;Kim, Jeong-Ill;Lee, Jae-Saeng
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.6
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    • pp.800-804
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    • 1997
  • To evaluate the characters related to rice grain quality as affected by silicate application, the ripened color, appearence and physicochemical properties of rice grain which were produced at the silt-loam paddy field of National Yeongnam Agricultural Exeperiment Station with a little poor drainage for trials on long-term effects of continuous application of same fertilizer were analyzed comparing with the NPK fertilizer an the NPK+compost in 1995. The whiteness value and color space value in ripened color of rice hull by silicate application were higher than those in the plots of NPK and NPK+compost, because of low percentage of rusty grain and sooty grain, The percentage of perfect grain in brown rice and in milled rice by the silicate application increased by 6.1~7.5% and by 1.8~3.5% respectively, as compared with the NPK application and white core and white belly of milled rice were decreased, The amylose content, protein content and starch-iodine blue value of milled rice by silicate application were lower than those in the plots of NPK and NPK+compost, while the peak point and breakdown viscosity of gelatinized rice flour on amylograph, and tastes value evaluated as a indicater of pannel test by nireco tester were higher. By silicate application these factors could be affected toward better in eating quality.

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