• Title/Summary/Keyword: 구조 및 열적 성질

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Thermal Behaviour of Some Montmorillonites with related their Chemical Compositions (몬모릴로나이트의 화학조성과 열적성질의 관계)

  • Moon, Hi-Soo
    • Economic and Environmental Geology
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    • v.18 no.3
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    • pp.253-261
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    • 1985
  • Detailed chemical compositions of thirteen montmorillonites and their thermal behaviour by differential thermal and thermogravimetric analysis have been studied. Comparison of structural formulae with experimental results by thermal analysis gave evidence of that both substitutions of Fe for Al in octahedral and Al for Si in tetrahedral positions appear to affect dehydroxylation temperature, which is valid for the present samples. Further detailed study of this topic using well-known samples which have various degree of substitution will be justified.

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Microstructure and properties of HQEE-based PU (HQEE-based PU의 미세구조 및 특성)

  • 이정상;이한섭
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.350-351
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    • 2003
  • Polyurethane은 물리적, 화학적 성질이 매우 다른 두 segment(hard/soft)로 이루어진 block copolymer로서 hard segment의 화학적 구조가 hard segment의 packing정도에 영향을 미쳐, PU의 미세상분리 현상을 결정하며 결과적으로 PU의 물리적 성질에 큰 영향을 미치게 된다$^1$. 본 연구에서는 hard segment의 packing을 향상시켜 PU은 열적 기계적 특성을 향상시키기 위하여 방향족환으로 구성되어 있어 aromatic diol의 일종인 hydroxyquinone-di-(beta-hydroxyl)ether(HQEE)를 chain extender로 사용하여 PU를 합성하였다. (중략)

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Preparation and Properties of Liquid Crystalline Polyurethanes Containing No Mesogenic Unit (Mesogen을 포함하지 않은 액정 polyurethane의 합성과 열적성질에 관한 연구)

  • Lee, Jong Back;Choi, Dae Woong
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.339-346
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    • 1997
  • Liquid crystalline polyurethanes were prepared from 1,4-bis(6-hydroxyhexoxy)benzene (BHB6) and 2,5-tolylene diisocyanate (2,5-TDI) solution polymerization in dimethylformamide produced intrinsic viscosities in the range 0.26 and $0.42d{\ell}/g$. The polyurethanes were investigated by DSC, Polarizing microscopy, X-ray, $^1H$-NMR and IR spectroscopy. Polyurethanes of two different molecular weights were studied in detail and these will be referred to as low molecular weight and high molecular weight. Polyurethane 2,5-TDI/BHB6 with $[{\eta}]=0.26d{\ell}/g$ prepared from BHB6 and 2,5-TDI, exhibited monotropic liquid crystallinity, although these polyurethanes contained no mesogenic core unit. For example, LCPU-L(low molecular weight) exhibited $T_{I-LC}$ of $122^{\circ}C$ $T_{LC-K}$ $89^{\circ}C$.

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Syntheses of Colorless and Transparent Copolyimides and Comparison of the Properties of Their Copolyimides (무색 투명 폴리이미드 공중합체의 합성 및 물성 비교)

  • Ju, Jieun;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.275-280
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    • 2015
  • Two series of copolyimides (Co-PIs) were prepared by reacting 4,4'-(hexafluoroisopropylidene) diphthalic anhydride (6FDA) and 1,2,4,5-benzentetra carboxylic dianhydride (pyromellitic dianhydride) (PMDA), as dianhydrides based on 4,4'-biphthalic anhydride (BPA) and 2,2'-bis(trifluoromethyl)benzidine (TFB) by using thermal- and chemical imidizations. Co-PIs films with different dianhydride monomer compositions were compared in terms of their thermal properties and optical transparencies. The addition of PMDA was more effective than the addition of 6FDA for improving the thermal properties. Meanwhile, 6FDA is more effective in optical transparencies.

Poly(vinyl alcohol) Nanocomposite Films (II): Thermo-mechanical Properties and Morphology (폴리(비닐 알코올) 나노복합체 필름(II) : 열적-기계적 성질 및 모폴로지)

  • Ham, Shin-Kyun;Jung, Min-Hye;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.30 no.6
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    • pp.545-549
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    • 2006
  • Blends of poly(acrylic acid- co-maleic acid) (PAM) with poly (vinyl alcohol) (PVA) were pre -pared in distilled water PVA/PAM/saponite (PVA/PAM/SPT) nanocomposite films were prepared with various clay contents by using the solution intercalation method. The variations of the dispersion, morphology, and thermo-mechanical properties of the nanocomposites with clay content in the range 0 to 9 wt% were examined. Up to 3 wt% clay loading, the clay particles were homogeneously dispersed in the PVA/PAM blends. However, some agglomerated structures form in the polymer matrix above a clay content of 7 wt%. The thermal stability of the hybrids was increased linearly with increasing the clay loading up to 9 wt%. The maximum strength and modulus were obtained at a clay content of 7 wt%. Thus, the addition of small amounts of clay to the PVA/PAM blends produced PVA/PAM nano-composites with improved the thermo-mechanical properties.

Process of Optical Fiber for Optical Link In Multi-Oxide Glass (다성분계 유리를 사용한 광링크장치용 광섬유제조)

  • 이용수;이회관;강원호
    • Proceedings of the KAIS Fall Conference
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    • 2000.10a
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    • pp.169-172
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    • 2000
  • 본 실험에서는 광Link로 응용될 Core Glass와 Clad Glass 및 Clad용 Polymer의 조성을 개발하고, Core용 Glass 와 Clad용 Glass의 match 및 Core Glass와 Clad용 Polymer의 효과적으로 접합 성형하여 반도체제조 설비내의 모든 Data 송ㆍ수신 Link를 Optical Fiber로 대체하여 기존 전선케이블이 전자기장의 영향으로 인한 Noise 와 Data 송ㆍ수신 오류를 일으키는 것을 방지하고자 한다. 따라서, 이에 대한 연구로 우선 유리를 사용한 기초 실험을 실시하였다. 실험 과정에 있어서는 Batch 실험과 용해 실험 및 물성 측정을 통하여 최적 조건의 유리를 선정하였다. 제조된 모유리를 사용하여 유리의 열적, 기계적 성질을 측정하였다. 또한 Glass core/Glass clad 파이버를 제조하여 광학적성질, 기계적성질, 구조적 특성을 평가하였다.