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열화학싸이클 수소를 제조를 위한 (Cu0.5Mn0.5)Fe2O4의 열적 거동 (Thermal Behaviors of (Cu0.5Mn0.5)Fe2O4 for H2 production by thermochemical cycles)

  • 김진웅;최승철;주오심;정광덕
    • 한국수소및신에너지학회논문집
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    • 제15권1호
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    • pp.32-38
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    • 2004
  • Thermal behaviors of $(Cu_{0.5}Mn_{0.5})Fe_2O_4$, prepared by a solid method, were investigated for $H_2$ production by a thermochemical cycle. The thermal reduction of $(Cu_{0.5}Mn_{0.5})Fe_2O_4$ started from $300^\circ{C}$ and the weight loss was 1.3 wt% up to 1200. XRD shows the prepared ferrite has the spinel structure with a lattice constant of $8.414{\AA}$ and changed to the oxygen deficient structure by thermal reduction. Oxygen and hydrogen can be separately produced by the cycles of thermal reduction and water oxidation of the oxygen deficient ferrite.