• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.33-42
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• 2000

Adsorption onto the surfaces of solid particles is a well known phenomenon that causes the retardation effect of heavy metals in soils. For adequate remediation of soil and groundwater contamination, it is important to investigate the mobility of heavy metals that largely depends on pH conditions in the soil water since adsorption of heavy metals is pH-dependent. In this study, we investigated the transport of Zn ion under various pH conditions in a sandy soil by conducting batch and column tests. The batch test was performed using the standard procedure of equilibrating fine fractions collected from the soil with eleven different initial $ZnCl_2$ concentrations, and analysis of Zn ion in the equilibrated solutions using ICP-AES. The column test consisted of monitoring the concentrations of soil solutions exiting the soil column with time known as a breakthrough curve (BTC). We injected respectively $ZnCl_2$ and KCl solutions with the concentration of 10 g/L as a tracer in a square pulse type under three different pH conditions (7.7, 5.8, 4.1) and monitored the flux concentration at the exit boundary using an EC meter and ICP-AES. The resident concentration was also monitored at the 10cm-depth by Time Domain Reflectometry (TDR). The results of batch test showed that ion exchange process between Zn and other cations (Ca, Mg) was predominant. The retardation coefficients obtained from adsorption isotherms (Linear, Freundlich, Langmuir) resulted in the various values ranging from 1.2 to 614.1. No retardation effect but ion exchange was found for the BTCs under all pH conditions. This can be explained by the absence of other cations to desorb Zn ion from soil exchange sites under the conditions of ETC experiment imposing blank water as leachate in steady-state flow. As pH decreased, the peak concentration of Zn increased due to the competition of Zn with hydrogen ions ($H^+$) and the concentrations of other cations decreased. The peak concentration of Zn was increased by 12.7 times as pH decreased from 7.7 to 4.1.

• 한국해양학회지
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• v.30 no.2
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• pp.91-115
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• 1995

Air-sea heat fluxes in the East Sea were estimated from the various ship's data observed from 1961 to 1990 and the JMA buoy #6 data from 1976 to 1985. The oceanic heat transport in the sea was also determined from the fluxes above and the heat storage rate of the upper layer of 200m from the sea surface. In winter, The incoming solar radiation is almost balanced with the outgoing longwave radiation. but the sea loses her heat through the sea surface mainly due to the latent and sensible heat fluxes. The spatial variation of the net surface heat flux is about 100 Wm/SUP -2/, and the maximum loss of heat is occurred near the Tsugaru Strait. There are also lots of heat losses in the southern part of the East Sea, Korea Strait and Ulleung Basin. Particularly, the heat strong loss in the south-western part of the sea might be concerned with the formation of her Intermediate Homogeneous Water. In summer, the sea is heated up to about 120∼140 Wm/SUP -2/ sue to strong incoming solar radiation and weak turbulent heat fluxes and her spatial variation is only about 20 Wm/SUP -2/. The oceanic heat flux is positive in the southeasten part f the sea and the magnitude of the flux is larger than that of the net surface heat flux. This shows the importance of the area. In the southwestern part of the sea, however, the oceanic heat flux is negative. This fact implies cold water inflow, the North Korean Cold Water. The sigh of net surface heat flux is changed from negative to positive in March and from positive to negative in September. The heat content in the upper surface 200 m from the sea surface reaches its minimum in March and maximum in October. The annual variation of the net surface heat flux is 580 Wm/SUP -2/ in southwestern part of the sea. The annual mean values of net surface heat fluxes are negative, which mean the net heat transfer from the sea to the atmosphere. The magnitude of the flux is about 130 Wm/SUP -2/ near the Tsugaru Strait. The net surface fluxes in the Korea Strait and the Ulleung Basin are relatively larger than those of the rest areas. The spatial mean values of surface heat fluxes from 35$^{\circ}C$ to 39$^{\circ}$N are 129, -90, -58, and -32 Wm/SUP -2/ for the incoming solar radiation, latent hear flux, outgoing longwave radiation, and sensible heat flux, respectively.

• Applied Chemistry for Engineering
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• v.4 no.4
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• pp.731-738
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• 1993

This study showed the adsorption behavior of Cs and Sr into the inorganic ion-exchanger zeolites such as 4A, 13X, AW300, AW500 and natural. It was found that the best type of zeolite is AW500 for Cs and 13X for Sr in terms of ion-exchange capacity. The temperature effect was also examined for the following systems : AW500-Cs, AW300-Cs, natural zeolite-Cs, 4A-Sr and 13X-Sr. Experiments showed that the effect of temperature on the ion-exchange capacity is negligible in all cases except for the systems of 4A-Sr and natural zeolite-Cs. The enhancement in the ion-exchange capacity for 4A-Sr would be caused by the Sr ion movement and the multilayer adsorption due to the heterogeneous characteristics of ion-exchange site. The distribution coefficient was increased with pH of the solution which is in equilibrium with zeolite particles. The values of $K_d$ in the systems of AW500-Cs and 4A-Sr were found to be about $10^3cm^3/g$ and $10^3{\sim}10^4cm^3/g$ respectively.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.306-306
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• 2010

21 세기는 언제, 어디에서, 누구나가 정보를 자유롭게 염가에 이용할 수 있는 유비쿼터스 정보사회가 될 것으로 예상하고 있다. 이러한 유비쿼터스 사회가 실현되기 위해서는 필연적으로 대두되고 있는 과제가 에너지 공급원의 문제이다. 휴대용 전자제품이나 소형 에너지 공급원으로 지금까지 주로 전지가 사용되어 왔지만 이것들은 교환 및 충전이 불가피하다. 이러한 불편함을 개선하기위해 교환과 충전이 불필요하거나 아주 장시간동안 공급해주는 형태의 에너지 공급원의 필요성이 대두되고 있다. 이러한 에너지 공급원으로 최근에 많은 연구가 되고 있는 것이 주위의 환경으로부터 버려지는 에너지를 수확(harvesting)하여 전력으로 변환하는 에너지 하베스팅 (energy harvesting)기술이 연구 개발되고 있다. 에너지 하베스팅 응용을 위해서 사용되어지는 압전 세라믹스는 전압출력계수 ($g_{33}$)가 커야하는데 이것은 압전상수 ($d_{33}$)와 유전상수 (${\varepsilon}_{\tau}$)의 값에 영향을 받는 것으로 알려져있다. 그 중에서 우수한 전기적 특성 때문에 PZT를 기반으로 하는 압전 세라믹스가 사용되어져왔다. 그러나 Pb의 높은 유독성과 Pb를 포함하는 제품들의 처분문제들로 인해 제조에 관한 많은 문제점들을 지니고있다. 그리하여, Pb를 포함하지 않는 Pb-free계에 관한 연구가 전세계적으로 활발히 진행되고 있다. 다양한 Pb-free계 후보자들 가운데 $K_{0.5}Na_{0.5}NbO_3$ (KNN)는 높은 큐리온도와 좋은 강유전 특성 및 압전특성 때문에 PZT를 대체할 가장 장래성있는 대안들 중의 하나로 고려되고 있다. 그러나 고온에서 알칼라인 원소들의 높은 휘발성 때문에 보통의 소결공정으로는 소결이 잘되고 치밀한 세라믹스를 얻기가 어렵다. 많은 연구에서 KNN 세라믹스의 소결성을 개선하기 위하여 강유전 또는 반강유전체인 $SrTiP_3$와 $LiTaO_3$를 고용체 형성에 포함시키고 또한 $K_4CuNb_8O_{23}$, $MnO_2$, CuO등과 같은 소결조제를 첨가하여 압전 특성과 소결성을 개선시켰다. 따라서 본 연구에서는 비화학양론적 (1-X)[$[(K_{0.5}Na_{0.5}]_{0.97}(Nb_{0.96}Sb_{0.04})O_3]$ + 0.008CuO + 0.2wt% $Ag_2O$ + X $CeMnO_3$의 조성을 사용하여 A사이트와 B 사이트에 각각 Ce이온과 Mn 이온의 치환량을 변화하여 그에 따른 유전 및 압전특성을 조사하였다.

• Journal of the Korean Magnetics Society
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• v.13 no.3
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• pp.97-102
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• 2003

Synthetic ferrimagnetic layer (SyFL) with structure NiFe/Ru/NiFe which can be applied high density TMR device in free layer were prepared by an inductively coupled plasma (ICP) helicon-sputter. We proposed a model of predicting coercivity (H$\_$c/), spin-flopping field (H$\_$sf/), and saturation field (H$\_$s/) as a function of Ru thicknesses, from the equilibrium state of energies of Zeeman, exchange, and uniaxial anisotropy. We fabricated the samples of Ta(50 ${\AA}$)/NiFe(50${\AA}$)nu(4∼20${\AA}$)NiFe(30 ${\AA}$)/Ta(50${\AA}$), and measured the M-H loops with a superconduction quantum interference device (SQUID) applying the external field up to ${\pm}$ 15 kOe. The result was well agreed with the proposed model, and reveal K$\_$u = 1000 erg/㎤, J$\_$ex/ =0.7 erg/$\textrm{cm}^2$. We report that H$\_$c/ below 10 Oe is available, and R$\_$u/ thickness range should be in 4-10 ${\AA}$ for MRAM application. Our result implies that permalloy layers may lead to considerable magnetostriction effect in SyFL and intermixing in NiFe/Ru interfaces.

• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.503-507
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• 2007

지하수 유동 모델에 반영되는 유역의 수리지질학적, 수문학적 특징들은 지하수 유동 특성에 주요한 영향을 미칠 수 있는 현장 특성들이다. 상기 특징들을 최대한 반영하기 위하여 438개의 관정자료를 토대로 갑천 유역(유역 면적 $648.3km^2$)의 대수층 구조 특성을 분석하고, 24개의 하천 자료를 이용하여 지하수 유동 모델을 구축하였다. 그리고 검 보정된 준분포형 유출모형(SWAT)의 22개 소유역의 지하수 함양량 결과를 3차원 지하수 유동 모델(MODFLOW)과 연계하여 갑천 유역의 광역 지하수 유동 특성을 평가하였다. 모의된 지하수위와 86개 지하수 관측정의 지하수위 비교에서 결정계수는 0.9918, 유역 전체의 물교환량의 상대오차율이 약 0.57%로 갑천 유역의 지하수 유동 특성을 잘 반영하였다. 갑천 유역의 지하수는 지형 및 대수층 특성과 하천의 영향에 의하여 전반적으로 유역 남쪽에서 북쪽으로 유동하는데 산지 지역에 존재하는 하천들은 손실과 이득 하천의 형태를 반복하는 반면, 갑천 중 하류 부분과 갑천-유등천 합류 부근은 이득하천의 형태를 보이고 있다. 그리고 소유역별 지하수 물교환량 분석한 결과, 상기 지역을 포함하는 소유역의 하천 공급원이 해당 유역의 지하수 함양량보다 지하수 유동 체계에 따라 인근 소유역에서 공급되는 지하수 유입량 비율이 훨씬 높은 것으로 분석되었다. 반면 유등천 중 상류 지역의 소유역을 제외한 산지 지역의 경우는 하천 공급원이 지하수 유동 체계에 의한 유입량보다 해당 유역 내에서 공급되는 지하수 함양량 비율이 높은 것으로 분석되었다. 따라서 지표수와 지하수의 상호작용 및 하천 유출에 지하수 유동 특성이 주요한 영향을 미치는 것으로 평가되었다.ens 4.4% (2.19)로 나타났다. 4. 全모기類의 月別 捕獲個體數에 對한 百分率은 다음과 같다. 5月 : 0.1% (1981年), 0.0% (1982年); 6月 : 3.5%, 1.3%; 7月 : 50.0%, 33.9%; 8月 : 37.1%, 52.1%; 9月 : 8.8%, 11.9%; 10月 : 0.5%, 0.8%; 11月 : 0.1%. 5. 모기類의 出現은 1981年과 1982年 모두 5月初로서 共通性을 지니고 있으나 增加勢를 보이는 것은 다르게 나타났다. 즉, 1981年은 6月 첫째 週이고 1982年은 前年度보다 3週 앞당겨진 5月 둘째 週였다. 6. 發生最大 peak는 1981年이 7月 다섯째 週이고, 1982年은 2週가 늦은 8月 둘째 週였다. 7. Culex (Culex) pipiens pallens의 最大發生 peak는 1981年度에 7月 다섯째 週, 1982年度는 2週 앞당겨진 7月 셋째 週였다. 8. Culex (Culex) tritaeniorhynchus summoro년의 最大發生 peak는 1981年, 1982年 모두 8月 둘째 週였다. 9. Anopheles (Anopheles) sinensis의 最大發生 peak는 1981年에 7月 다섯째 週, 1982年은 2週 앞당겨진 7月 셋째 週였다. 10. 重要 3種의 最大 peak를 比城하면 Culex (Culex) pipiens pallens와 Anopheles (Anopheles) sinensis는 1981年과 1982年 모두 最大 peak時期가 同一하였으며, Culex (Culex) tritaeniorhynchus summoro년는 2年間 모두 8月둘째 週에 나타났다.osterior to manubrium and anterio

• Journal of Soil and Groundwater Environment
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• v.8 no.1
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• pp.17-26
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• 2003

The sorption experiment of cobalt was performed after the TRIGA soil was intentionally contaminated with cobalt was found that the sorption equilibrium coeficiency of soil decontamination was high when the ratio of soil mass to the volume of citric acid becomes 1:5 The TRIGA soil contaminated with 0.01 M, 0.001 M, and 0.0001 M of cobalt solution were decontaiminated with 0.01 M citric acid. The cobalt concentrtion in the wastewater were measured to be correspondingly 36.0, 14.0, 1.5 ppm. The results of wastewater recycling experiment by chemical precipitation method revealed that corresponding cobalt removal efficiency were 97% 88%. It was shown that the removal efficiency decreases as the cobalt concentration in the wastewater decreases. During the decontamination experiment, a lot of NaOH had to be added, and the volume of final solid waste reached almost 10% of that of the contaminated soil. The result of wastewater recyling experiment by ion exchange resin meted rethod revealed that to more the strong acid resins are used, the higher the cobalt removal efficiency becomes and the cobalt removal efficiency becomes and the lower the pH of recycling wastewater become. In order to obtain more than 95% removal efficiency, more than 0.625 g of strong acid resin was necessary in each of 3 experiments. There was an unexpected problem that a lot of strong acid resin waste was produced which amounts to 9.2% (volume) of the contaminated soil.

• Journal of Korea Water Resources Association
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• v.40 no.6 s.179
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• pp.431-446
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• 2007

Groundwater flow in a basin is greatly affected by many hydrogeological and hydrological characteristics of the basin. A groundwater flow model for the Kap-cheon basin ($area=648.3km^2$) in the Geum river basin was established using MODFLOW by fully considering major features obtained from observed data of 438 wells and 24 streams. Furthermore, spatial groundwater recharge distribution was estimated employing accurately calibrated watershed model developed using SWAT, a physically semi-distributed hydrological model. Model calibration using observed groundwater head data at 86 observation wells yielded the deterministic coefficient of 0.99 and the water budget discrepancy of 0.57%, indicating that the model well represented the regional groundwater flow in the Kap-cheon basin. Model simulation results showed that groundwater flow in the basin was strongly influenced by such factors as topological features, aquifer characteristics and streams. The streams in mountainous areas were found to alternate gaining and losing steams, while the streams in the vicinity of the mid-stream and down-stream, especially near the junction of Kap-cheon and Yudeong-cheon, areas were mostly appeared as gaining streams. Analysis of water budget showed that streams in mountainous areas except for the mid-stream and up-stream of Yudeong-cheon were mostly fed by groundwater recharge while the streams in the mid and down-stream areas were supplied from groundwater inflows from adjacent sub-basins. Hence, it was concluded that the interactions between surface water-groundwater in the Kap-cheon basin would be strongly inter-connected with not only streams but also groundwater flow system itself.

• Economic and Environmental Geology
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• v.51 no.2
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• pp.99-111
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• 2018

In this study three target radionuclides ($^{60}Co$, $^{137}Cs$, and $^{125}Sb$) were reacted with solid samples collected from the nuclear facility sites to investigate their sorption and mobility behaviors for preparing unexpected nuclear accidents. The highest sorption distribution coefficients ($K_{ds}$) of target radionuclides ($^{60}Co=947mL/g$, $^{137}Cs=2105mL/g$, $^{125}Sb=81.3mL/g$) were found in topsoil layer under groundwater condition, and the $K_d$ values of three radionuclides decreased in the order of fractured rock and bedrock samples under the same groundwater condition. High $K_d$ values of $^{60}Co$ in topsoil layer and fracture rock resulted from the clay minerals present, and the $K_d$ values decreased 58-69 % under seawater condition due to high ionic strength. $^{137}Cs$ sorption was controlled by the ion exchange reaction with $K^+$ on flayed edge sites (FES) of mica. The $^{137}Cs$ sorption was the most affected by seawater (89-97 % decrease), while $^{125}Sb$ sorption was not much affected by seawater. As the results of column and batch experiments, the retardation factors (R) of $^{137}Cs$, $^{60}Co$, and $^{125}Sb$ were determined about 5400-7400, 2000-2500, and 250-415, respectively, indicating no significant transport for these radionuclides even in fractured zone with groundwater. These results suggest that even in the case of severe nuclear accident at the nuclear facilities the mobility of released radionuclides ($^{60}Co$, $^{137}Cs$, and $^{125}Sb$) can be significantly retarded by the topsoil layer and fractured rock. In addition, the results of this study will be used for the safety and environmental performance assessment of nuclear facilities.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.2
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• pp.113-120
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• 2010

An experimental investigation was carried out to examine the evaporative heat transfer characteristics of R-134a in a micro-channel heat exchanger. The micro-channel heat exchanger used in this study was a sort of plate heat exchanger. Micro-channels were fabricated on the SUS304 plate by the photo-etching process: 13 sheets of plates were stacked and bonded by the diffusion bonding process. The effects of the evaporating temperature, mass flux of R-134a, and inlet temperature of water were examined. As the difference between the inlet temperatures of R-134a and water increased, the heat transfer rate increased. The evaporative heat transfer coefficients obtained in this study range from 0.67 to 6.23 kW/$m^2{\cdot}^{\circ}C$. The experimental correlation for the Nusselt number as a function of the Reynold number and $\Theta$ was suggested for the micro-channel heat exchanger.