• Title/Summary/Keyword: 교류저항성

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Effect of Sulfuric Acid Addition on the Aluminum AC Etching in HCl Solution (염산용액내에 황산 첨가에 의한 알루미늄의 교류에칭 특성)

  • Kim, Hangyoung;Choi, Jinsub;Tak, Yongsug
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.463-468
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    • 1998
  • When sulfuric acid was added in HCl etching solution, corrosion of aluminum metal was inhibited by the chemical adsorption of sulfate ions. In the presence of $SO_4^{-2}$, cyclic voltammetry showed that the protective oxide film was formed on the inner surfaces of etch pits and, pit density was increased by nucleation on both the aluminum surface and the pits inside. Structure and distribution of etch pits found in AC etching of aluminum were strongly influenced by the concentration of $SO_4^{-2}$ and the amount of cathodic pulse charging. Below $0.8mC/cm^2$ of cathodic pulse charging, oxide films formed inside actively dissolving pits indicated the higher resistance to pit nucleation as the concentration of $SO_4^{-2}$ increases. However, the structural change of oxide films occurred above the $0.8mC/cm^2$ charging and the effect of $SO_4^{-2}$ was minimized, and it resulted in the rapid formation of etch pits.

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Effects of the Injected Number and Amplitude of 8/20 [μs] Impulse Current on the Life of ZnO Varistors (8/20 [μs] 임펄스전류의 인가횟수와 크기가 ZnO바리스터의 수명에 미치는 영향)

  • Lee, Bok-Hee;Li, Feng
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.21 no.1
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    • pp.118-124
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    • 2007
  • This paper presents the effects of the injected number and amplitude of impulse current on the service life of ZnO varistors for low voltages. To analyze the effects of lightning impulse currents on the performance of ZnO varistors, the measurements of resistive leakage current and power dissipation at the power frequency ac voltage before and after the injections of the $8/20[{\mu}s]$ impulse currents were made. As a consequence, the duration and amplitude of resistive leakage current flowing through ZnO varistor were increased with increasing the number of injections of the $8/20[{\mu}s]$ impulse currents. It is desirable that the service life of ZnO varistors should be evaluated as a function of the number and amplitude of lightning impulse current.

Corrosion Characteristics of Catenary Materials in Electric Railway System (전차선로 가선재료의 부식특성)

  • 김용기;윤상인;장세기;이재봉
    • Proceedings of the KSR Conference
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    • 2000.11a
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    • pp.535-542
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    • 2000
  • Pure copper, Cu-1.1wt%Cd and ACSR(Aluminum Conductor Steel Reinforced) have been used as Catenary Materials in Electric Railway System. Since these materials may have chance to be exposed to the corrosive environments like polluted air, acid rain and sea water, it is important not only to investigate the corrosion characteristics but also to measure corrosion rates in various corrosive environments. In order to examine corrosion characteristics according to the dissolved oxygen content, pH, chloride ion concentration ion, and the addition of Cd to Cu, a series of tests such as potentiodynamic polarization. a.c impedance spectroscopy and galvanic corrosion tests were carried out in these materials. Results showed that the addition of Cd to Cu and chloride ion in the solution have an adverse effect on the resistance to corrosion. Additionally, Galvanic currents between Al and steel wires of ACSR were confirmed by using ZRA(zero resistance ammeter) method.

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A Study on Speed Variable Proportional Resonant Current Controller of Single-Phase PMSM (단상 영구자석 동기전동기의 속도 가변형 비례공진 전류제어에 관한 연구)

  • Lee, Won-Seok;Hwang, Seon-Hwan;Park, Jong-Won
    • Journal of IKEEE
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    • v.24 no.4
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    • pp.954-960
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    • 2020
  • This paper proposes a speed variable proportional resonant current control method for a single-phase permanent magnet synchronous motor(PMSM). Due to the electromagnetic characteristics of a single-phase PMSM, negative and zero torques are generated in the part corresponding to the phase difference between the stator current and the back electromotive force. In addition, overcurrent limitation is required because of the low stator resistance and inductance in sensorless operation. When using the vector control for current control of single-phase PMSM under these conditions, processes of coordinate transformation, inverse coordinate transformation, and generation of virtual dq-axis components are required. However, the proposed variable speed proportional resonant current control method does not need the coordinate transformation used for AC motors. In this paper, we have confirmed stable maneuverability by using variable proportional resonant current control algorithm, and proposed sensorless control based on a mathematical model of a single-phase PMSM without a position sensor when reaching a constant speed. The usefulness of the current control method was verified through several experiments.

Electrode Characteristics of K+ Ion-Selective PVC Membrane Electrodes with AC Impedance Spectrum (AC 임피던스 분석법을 이용한 K+ 이온선택성 PVC막 전극 특성)

  • Kim, Yong-Ryul;An, Hyung-Hwan;Kang, An-Soo
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.870-877
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    • 1998
  • With impedance spectrum measurements, impedance was studied in the interface between sample solutions for $K^+-ion$ selective PVC membrane electrode containing neutral carriers [dibenzo-18-crown-6 (D18Cr6) and valinomycine (Val)]. Response characteristics of electrode were examined by measuring AC impedance spectra that were resulted from the chemical structure and the content of carrier, variation of plasticizer, membrane thickness, doping of base electrolytes, and concentration variation of sample solution. Transport characteristics of PVC membrane electrode were also studied. It was found that the equivalent circuit for the membrane in $K^+$ solution could be expressed by a series combination of solution resistance and a parallel circuit consisting of the bulk resistance and geometric capacitance of the membrane system. But the charge transfer resistance and Warburg resistance were overlapped a little in the low concentration and low frequency ranges. The carrier, D18Cr6 was best for electrode and impedance characteristics, and ideal electrode characteristics were appeared especially in case of doping of the base electrolyte[potassium tetraphenylborate(TPB)]. The optimum carrier content was about 3.23 wt% in case of D18Cr6 and Val. DBP was best as a plasticizer. As membrane thickness decreased the impedance characteristics was improved, but electrode characteristics were lowered for membrane thickness below the optimum. In the case of D18Cr6, the selectivity coefficients by the mixed solution method for the $K^+$ ion were the order of $NH_4{^+}>Ca^{2+}>Mg^{2+}>Na^+$.

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Geophysical Logging of Frequency-domain Induced Polarization for Mineral Exploration (광물탐사를 위한 진동수영역 유도분극 물리검층)

  • Shin, Seungwook
    • Geophysics and Geophysical Exploration
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    • v.24 no.3
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    • pp.73-77
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    • 2021
  • Induced polarization (IP) is useful for mineral exploration and hydrogeological studies by visualizing the electrochemical reactions at the interface between polarized minerals and groundwater. Frequency-domain IP (FDIP) is not actively applied to field surveys because it takes longer to acquire data, despite its higher data quality than conventional time-domain IP. However, data quality is more important in current mineral exploration as the targets gradually shift to deep or low-grade ore bodies. In addition, the measurement time reduced by automated instrumentation increases the potential for FDIP field applications. Therefore, we demonstrate that FDIP can detect mineral exploration targets by performing geophysical logging in the boreholes of a skarn deposit, in South Korea. Alternating current (AC) resistivity, percent frequency effect (PFE) and metal factor (MF) were calculated from impedance values obtained at two different frequencies. Skarn zones containing magnetite or pyrite showed relatively low AC resistivity, high PFE, and high MF compared to other zones. Therefore, FDIP surveys are considered to be useful for mineral exploration.

A Study on the Linear Counting Ratemeter (선형 계수율계에 관한 연구)

  • 이병선
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.8 no.6
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    • pp.8-16
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    • 1971
  • This paper describes the transistorized linear counting ratemeter which can be uses to indicate on the meter or record the counting rates of the nuclear radiations produced from the atomic reactor or from the radio isotopes. Tte feature of this ratemeter is the use of the transistor chopper for good stabilization. At the input stage of the a. c. amplifier a composite emitter follower buffer stage has been used to give the high input impedance. A hybrid parameter equivalent circuit was modeled for the analysis of this buffer stage. The counting rates can be linearly measured from few CPS up to 100KCPS in 4 ranges. The resolution is less than 0.5$\mu$sec and the output drift at the room temperature with 7-hour continuous operation is in the order of $\pm$0.5$\mu$A.

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Stability Evaluation of Series and Parallel Varistor Combination Using Thermal Image Analysis (열화상 분석을 통한 바리스터의 직렬과 병렬 조합의 안전성 평가)

  • Eom, Ju-Hong;Cho, Sung-Chul;Lee, Tae-Hyung;Han, Hoo-Sek
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.8
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    • pp.22-29
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    • 2006
  • According to the recent revision of KS on the basis of the IEC, equipotential grounding systems has been come into focus and the use of surge protective devices(SPD) has been increased radically in order to operate the power system stably. $Z_nO$ varistor with non-linear resistance, which has an outstanding voltage-current(V-I) characteristic, is mainly used in power system to limit surge voltage and divert surge current. $Z_nO$ varistors are packaged several types based on the circuit assembly to be connected to a.c. power line. When the user assemble the $Z_nO$ varistors into parallel or series circuit package, there are my things to be taken into consideration including functions and thermal stability because they are directly related to the safety. We compare stabilities of each assembly type by measuring residual voltage, discharge current, leakage current and surface temperature concerned to the protection performances between a single device with a 40[kA] of current capacity and parallel or series circuits type of varistor package.

Spectral Induced Polarization Characteristics of Rocks in Gwanin Vanadiferous Titanomagnetite (VTM) Deposit (관인 함바나듐 티탄철광상 암석의 광대역 유도분극 특성)

  • Shin, Seungwook
    • Geophysics and Geophysical Exploration
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    • v.24 no.4
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    • pp.194-201
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    • 2021
  • Induced polarization (IP) effect is known to be caused by electrochemical phenomena at interface between minerals and pore water. Spectral induced polarization (SIP) method is an electrical survey to localize subsurface IP anomalies while injecting alternating currents of multiple frequencies into the ground. This method was effectively applied to mineral exploration of various ore deposits. Titanomagnetite ores were being produced by a mining company located in Gonamsan area, Gwanin-myeon, Pocheon-si, Gyeonggi-do, South Korea. Because the ores contain more than 0.4 w% vanadium, the ore deposit is called as Gwanin vanadiferous titanomagnetite (VTM) deposit. The vanadium is the most important of materials in production of vanadium redox flow batteries, which can be appropriately used for large-scale energy storage system. Systematic mineral exploration was conducted to identify presence of hidden VTM orebodies and estimate their potential resources. In geophysical exploration, laboratory geophysical measurement of rock samples is helpful to generate reliable property models from field survey data. Therefore, we performed laboratory SIP data of the rocks from the Gwanin VTM deposit to understand SIP characteristics between ores and host rocks and then demonstrate the applicability of this method for the mineral exploration. Both phase and resistivity spectra of the ores sampled from underground outcrop and drilling cores were different of those of the host rocks consisting of monzodiorite and quartz monzodiorite. Because the phase and resistivity at frequencies below 100 Hz are mainly dependent on the SIP characteristics of the rocks, we calculated mean values of the ores and the host rocks. The average phase values at 0.1 Hz were ores: -369 mrad and host rocks: -39 mrad. The average resistivity values at 0.1 Hz were ores: 16 Ωm and host rocks: 2,623 Ωm. Because the SIP characteristics of the ores were different of those of the host rocks, we considered that the SIP survey is effective for the mineral exploration in vanadiferous titanomagnetite deposits and the SIP characteristics are useful for interpreting field survey data.

Flame Retardancy and Electrical/Mechanical Properties of LDPF/EVA Blend (LDPE/EVA Blend의 난연성 및 전기/기계적 특성)

  • Ryu, Boo-Hyung;Lee, Chung;Kim, Ki-Yup
    • Journal of the Korean Society of Safety
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    • v.23 no.4
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    • pp.99-104
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    • 2008
  • In this research, magnesium hydroxide as a flame retardant agents and zinc borate as a synergist were mixed with LDPF/EVA blended samples, in order to improve their flame retardancy. We attempted to select the best mixing ratio of the LDPF/EVA blend and the optimum amount of magnesium hydroxide and zinc borate by the comparison and analysis of the flame retardancy, the electrical properties such as the volume resistivity and dielectric loss tangent, and the mechanical properties such as the tensile strength and elongation at break. Particularly, specimen which is the 6phr of zinc borate and 10phr of magnesium hydroxide 70/30phr adding to the LDPF/EVA blended samples has been most excellent in flame retardancy and electrical/mechanical properties.