• Title/Summary/Keyword: 교류임피던스

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Impedance Spectroscopic Properties of Mn Deposition on Al Oxide Layer (Al 양극산화피막에서 Mn전착에 관한 임피던스 연구)

  • Oh, Han Jun;Jang, Kyung Wook;Chi, Choong Soo
    • Journal of the Korean Chemical Society
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    • v.43 no.1
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    • pp.23-29
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    • 1999
  • The Al oxide layer formed in 1M $H_2SO_4$ solution and the influence of applied frequency for electrodeposition of Mn on Al oxide layer were characterized using by impedance spectroscopy. Mn compounds were electrodeposited at the base of pores during deposition with applied low frequency voltage. For the Mn deposited oxide layer at 6OHz and 5Hz in 1 g/L $KMnO_4$ solution, in equivalent circuit for interpretation, the resistance ($R_2$) and capacitance ($C_2$) were considered to be due to deposition of Mn on base of pore. The electrochemical behavior of barrier layer and porous oxide layer on Al have been characterized by capacitance ($C_b$) and Young capacitance ($C_Y$) in equivalent circuit model.

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Effects of Alloying Elements(Cr, Mo, N) on Repassivation Characteristics of Stainless Steels Studied by the Abrading Electrode Technique and A.C Impedance Spectroscopy (마멸 전극 기법과 교류 임피던스법으로 연구한 스테인리스강의 합금원소(Cr, Mo, N)가 재부동태 특성에 미치는 영향)

  • Ham Dong-Ho;Kim Suk-Won;Lee Jae-Bong
    • Journal of the Korean Electrochemical Society
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    • v.3 no.4
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    • pp.211-218
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    • 2000
  • The effects of alloying elements, Cr, Mo, and N on repassivation characteristics of stainless steels were investigated by using the abrading electrode technique and a.c impedance spectroscopy. The role of alloying elements on the stability of passive film and their repassivation characteristics were examined using alloy steels such as Fe-Cr, Fe-Cr-Mo, 304, 304LN, 316, and 316LN. The electrochemical characteristics of the passive film were investigated by in-situ d.c. and a.c. electrochemical methods. Localized corrosion resistance is believed to have much to do with the stability and repassivation characteristics of the passive film. The effects of alloying elements on the current transients and repassivation kinetics were systematically examined by using the abrading electrode technique and a.c. impedance spectroscopy. The experimental results were analyzed in order to elucidate the relationship between passive film stability, repassivation characteristics, and alloying elements.

Analysis on the Langmuir adsorption isotherm at the $Pt/H_2SO_4$ electrolyte interface using the ac impedance measurement and phase-shift method ($Pt/H_2SO_4$ 전해질 계면에서 교류임피던스 측정과 위상이동 방법에 의한 Langmuir 흡착등온식 해석)

  • Chun Jang Ho;Cho Sung Chil;Son Kwang Chul
    • Journal of the Korean Electrochemical Society
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    • v.2 no.1
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    • pp.23-26
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    • 1999
  • The Langmuir adsorption isotherm at the $(Pt)/0.1M\;H_2SO_4$ electrolyte interface has been qualitatively analyzed using the ac impedance measurement and phase-shift method. The phase shift $(\phi)$ depends on both the cathode potential (E<0) and frequency (f) and is inversely proportional to the factional surface coverage $(\theta)$. At an intermediate frequency band (ca. $1\~100$ Hz), the phase-shift profile $(\phi\;vs.\;E)$ can be related to the fractional surface coverage $(\theta\;vs.\;E)$. The phase-shift profile $(\phi\;vs.\;E)$ can be used as an experimental method to estimate and analyze the Langmuir adsorption isotherm $(\theta\;vs.\;E)$. The equilibrium constant (K) and the standard free energy $({\Delta}G_{ads})$ of the adsorbed hydrogen atom $(H_{ads})\;and\;3\times10^{-4}$ and 20.1 kJ/mol, respectively.

DC Residual Current Detection Algorithm based on Analysis of IEC60479 Impedance Model for Human Body (IEC60479 인체 임피던스 모델 분석을 통한 직류환경에서의 누설전류검출)

  • Lee, Jinsung;Kim, Hyosung;Wang, Yongpil
    • Proceedings of the KIPE Conference
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    • 2016.07a
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    • pp.353-354
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    • 2016
  • 본 논문은 IEC 60479 표준 "인체감전의 생리학적 현상"에 제시되어 있는 인체감전 현상에 대하여 교류환경과 직류환경에서 인체임피던스의 특성을 실험을 통하여 분석한다. 연구 결과, 적어도 상용주파수 이하에서는 IEC 60479 표준에서 제시하는 인체 임피던스 모델의 수정이 필요함을 발견하였다. 또한 도출된 실험 결과를 활용하여 직류 배전시스템의 TN 접지방식에서 인체 감전 및 설비 누전에 따른 사고에 대하여 구분동작이 가능한 직류전용 누설전류 검출(DC Residual Current Detection) 기법을 제안한다.

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A Study on the Designed Method of Low Voltage Feeder (저압 간선의 설계기법에 관한 연구)

  • 조계술;고만석;신강욱;원진희;최홍규
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2001.11a
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    • pp.167-172
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    • 2001
  • 본 연구는 저압간선의 굵기 산정에 있어서 체계적인 설계 흐름도를 분석하였고 Cable size별로 온도변화에 따른 직류 저항값 대비 교류 임피던스값의 변화에 대하여 전압강하를 고려한 간선의 선정기법을 제시 하였다.

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Effect of AC Loss on the Current Distribution in the Multi-stacked Superconducting Tapes (다중 적층 초전도선재의 전류분포가 교류손실에 미치는 영향)

  • Byun, S.B.;Lee, S.;Hwang, Y.I.;Chang, T.;Choi, K.D.
    • Proceedings of the KIEE Conference
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    • 2006.07d
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    • pp.2245-2246
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    • 2006
  • 병렬선재를 사용하여 권선을 제작할 경우 구성하는 초전도 선재의 임피던스의 차이에 의하여 통전전류 불균형이 발생하게 된다. 본 논문에서는 BSCCO 선재를 사용하여 제작된 병렬선재에서 전류불균형 분포에 따른 교류손실을 측정하였다. 4 가닥 병렬선재의 경우 전류 불균형이 발생한 선재에서의 교류손실이 전류 불균형이 일어나지 않을 때보다 2배 이상 증가함을 확인하였다.

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