• Photocatalyst Technology
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• v.1
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• pp.18-20
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• 2004

• Photocatalyst Technology
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• v.1
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• pp.89-93
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• 2004

• Photocatalyst Technology
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• v.1
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• pp.70-85
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• 2004

• Photocatalyst Technology
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• v.1
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• pp.67-69
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• 2004

• Photocatalyst Technology
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• v.1
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• pp.55-64
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• 2004

• Photocatalyst Technology
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• v.1
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• pp.51-54
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• 2004

• Photocatalyst Technology
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• v.1
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• pp.43-50
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• 2004

• Photocatalyst Technology
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• v.1
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• pp.21-24
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• 2004

• Transactions of the Korean hydrogen and new energy society
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• v.16 no.2
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• pp.111-121
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• 2005

이 연구는 광화학적 물분해 수소제소 기술의 일환으로 수행 중인 광촉매와 바이오촉매를 복합한 시스템 활용 기술에서 광촉매가 갖는 물리적 특성의 영향을 파악하고자 진행되었다. 다양한 물리적 특성을 갖는 광촉매 얻기 위하여 상용광촉매, 수열화법(HT-TiON), 리고 저온합성법(LT-TiON) 등을 이용하여 샘플을 준비하였다. 가시광 감응을 위하여 암모니아나 triethylamine 처리를 하여 질소를 도핑도 시도하였다. 시도된 복합시스템은 인위적인 전자주개 없이 수소를 발생시키는 결과를 보여주었으나, 광촉매로부터 엔자임으로의 전자전달 부분이 율속단계로 확인되었다. 사용된 광촉매 샘플에 따라 수소발생량에 차이가 나타난 결과로 광촉매의 미세구조 (결정상, 결정도, 기공 크기 및 비표면적 등)이 중요한 역할을 하는 것으로 판단되었다. 얻어진 결과들을 활용하여 재료들이 고정화된 새로운 시스템 구성을 제안하였다.

• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.952-959
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• 2012

The photocatalytic reactor was designed to have improved efficiency by enhancing a light intensity of photocatalytic reactor using a reflector coated on the surface at the outer radius of annular shaped photocatalytic reactor. The improved photocatalytic reactor performed to treat waste air containing malodor and VOC with the enhanced light intensity, of which the effect on their removal efficiency was investigated. The intensities of illumination of the improved photocatalytic reactor filled with porous silica-based media and nonporous glass bead media carrying photocatalyst were observed to increase by 28.5% and 30.1%, respectively, compared to those of photocatalytic reactor without any reflector. Using the improved photocatalytic reactor filled with porous silica-based media and nonporous glass bead media carrying photocatalyst, the removal efficiencies were enhanced by 2~3% and insignificantly, respectively. The removal efficiencies of the optimized photocatalytic reactor with reflectors, filled with porous silica-based media carrying photocatalyst, were observed to increase by 26% and 60%, compared to those of photocatalytic reactor (i.e., 19% and 53%), without any reflector, filled with nonporous glass bead media carrying photocatalyst, for hydrogen sulfide and toluene, respectively. The roughness of used reflector surface was measured to be ca. four times as big as that of a commercial mirror. However, their removal efficiencies are expected to be enhanced by increasing an light intensity resulting from lowering the roughness of used reflector coated on the improved photocatalytic reactor in the future.