• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.225-230
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• 2002

중부 옥천대 구룡산층 분포지역에서, 채석장 지류는 특징적으로 낮은 pH와 높은 EC를 나타내는 산성광산폐수의 형태를 보이고 있었으며, 황갈색 철 침전물을 나타내고 있었다. 이들은 탄산염이 풍부한 화전리층(상층) 지류와의 혼합으로 백색 알루미늄 침전물을 형성시켰으며, 따라서 산성수의 영향 범위가 크게 나타나지 않는 것으로 확인되었다. 포화지수와 열역학 데이터를 이용한 결과, 본 연구지역 채석장 지류에 황갈색 침전물을 생성시키는 용존철은 래피도크로사이트와 침철석의 복합적인 작용에 의해 농도가 조절되고 있음을 확인하였다.

• Korean Journal of Microbiology
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• v.24 no.1
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• pp.57-61
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• 1986

In order to remove of cadmium from waste water an identification of a cadmium-ion tolerant yeast B-7 isolated from the sludge of zinc mining district was studied. By the taxonomecal characteristics of strain B-7 it was identified as Hansenula anomala B-7 or similar strain. The cadmium-ion tolerance of the strain B-7 was determined as $2,700{\mu}g/ml$ of cadmium-ion by density gradient agar plate method. The strain B-7 grew well in an aqueous medium containing $1,000{\mu}g/ml$ of cadmium-ion.

• Economic and Environmental Geology
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• v.37 no.1
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• pp.143-151
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• 2004

This study focused on examining the possibility of recycling mine solid waste as environmental materials, especially for porous media. Basic properties including mineralogical compositions, chemical compositions, and particle size distribution of the tailings from the Sangdong W mine were checked. The mineralogical and chemical compositions of the tailings samples were not much different in depth. According to Korean Standard Leaching Test for Wastes(KSLT), concentrations of heavy metals leached from the tailings were below the standard values. As a result of particle size analysis, the median diameter (d$_{50}$) of the tailings was in the range of 10 to 30 ${\mu}{\textrm}{m}$. The stable tailings slurry made up of 3 ${\mu}{\textrm}{m}$ in d$_{50}$ was prepared using Attrition Mill. The milling condition was 40 vol% in slurry concentration, 700 rpm in stirring speed, and 1 hour in milling time. PEI was added as dispersing agent. Concentrated slurry was extended to 3 times by foaming method. In the case of 3 times foamed slurry, the total and open porosity of ceramic supports sintered at 1,075$^{\circ}C$ for 90 minutes was about 80% and 72%, respectively. Pore size was in the range of 30∼350${\mu}{\textrm}{m}$. Therefore, the tailings could be recycled starting material for environmental materials such as macroporous ceramic support.

• Korean Journal of Environmental Agriculture
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• v.16 no.1
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• pp.55-60
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• 1997

Heavy metal-tolerant microorganisms, such as Pseudomonas putida, P. aeruginosa, P. chlororaphis and P. stutzeri which possessed the ability to accumulate cadmium, lead, zinc and copper, respectively, were isolated from industrial wastewaters and mine wastewaters polluted with various heavy metals. The distribution of heavy metal in the cell components, and amino acid compositions, was investigated. The distribution of heavy metal in the cell fractions of each heavy metal-tolerant microorganism grown for 20 hours in the basal medium containing 100mg/l of each heavy metal was investigated. In the case of cadmium-tolerant P. putida, lead-tolerant P. aeruginosa and copper-tolerant P. stutzeri, approximately $50{\sim}60%,\;30{\sim}40%$ and $10{\sim}17%$ of each heavy metal absorbed were distributed to cell wall, cell membrane and cytoplasm fractions, respectively. In the case of zinc-tolerant P. chlororaphis, approximately 32%, 55% and 13% of zinc were distributed to cell wall, cell membrane and cytoplasm fractions, respectively. These results indicated that the cell wall was a major adsorbing fraction of cadmium, lead and copper, and the cell membrane was that of zinc. Total amino acid content per gram of the cell grown in the culture media with heavy metal was higher than that of the cell grown in the culture media without heavy metal, and the content of acidic amino acids, such as aspartic acid(Asp.+Asn.) and glutamic acid(Glu.+Gln.) was higher than that of basic amino acids, such as histidine, lysine and arginine.

• Korean Journal of Environmental Agriculture
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• v.17 no.3
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• pp.246-253
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• 1998

Heavy metal-tolerant microorganisms, such as Pseudomonas putida, P. aeruginosa, P. chlororaphis and P. stutzeri which possessed the ability to accumulate cadmium, lead, zinc and copper, respectively, were isolated from industrial wastewaters and mine wastewaters polluted with various heavy metals. The binding sites of heavy metal in the cells were investigated by chemical modification of functional groups the cell walls. To determine the binding sites of heavy metal in the cells, electrochemical charge of amine and carboxyl groups in the cell walls of heavy metal-tolerant microorganisms were chemically modified. Chemical modifications of amine groups did not affect the heavy metal uptake as compared to native cell walls. In contrast, modifications of carboxyl groups drastically decreased heavy metal uptake as compared to native cell walls, and electron microscopy confirmed that the form and structure of the heavy metal uptake were different from those of native cell walls. The results suggested that the carboxyl groups were the major sites of heavy metal uptake in the heavy metal-tolerant microorganism cell.

• Journal of Animal Environmental Science
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• v.15 no.2
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• pp.155-160
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• 2009

This study was carried out to investigate the feasibility of Multi Process of Aerobic Digestion (MPAD) for recycling of swine manure slurry as fertilizer. MPAD consisted of three kinds of difference process which are thermophilic aerobic oxidation (TAO) system, lime solidification system, and reverse osmosis (R/O) membrane system. TAO system was studied well previously for decade. The chemical composition of the lime-treated solid fertilizer was as like that organic matter 17.4%, moisture 34.1%, N 0.9%, P 1.7%, K 0.3%, Ca 12.7%, and which was expected to be useful as acid soil amendment material. The concentrated liquid material produced by R/O membrane system was also expected as a good fertilizer for crops production and soil fertility improvement.

• Analytical Science and Technology
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• v.19 no.5
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• pp.383-388
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• 2006

Simple post-wash method by ion chromatography (IC) was established for the rapid and precise determination of fluoride ion in wastewater from mine in fluorite mineralized area. High sulfate in sample was retained in a pre-column and less strongly held fluoride ion was transferred to the principal separation system using modified conventional IC with switching technique. An analytical column with high capacity (AS 9 HC) was used as a pre-column to retain the amount of high sulfate. A guard column (AG 14) as a separation column was used to increase the response of fluoride and reduce the system pressure. According to the recovery of fluoride ion with one detector and the observation of sulfate peak with another conductivity detector, the optimum switching time of 10-port chromatographic injector was 4.3 min. The limit of detection (S/N = 3) of fluoride in synthetic solution containing $500mg\;L^{-1}$ sulfate was $2.4{\mu}g/L$, with $25{\mu}L$ sample volume.

• Membrane Journal
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• v.29 no.5
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• pp.237-245
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• 2019

Ammonia nitrogen is well known as a substance that causes the eutrophication with a phosphorus in the water, because it is contained in the industrial wastewater, agricultural and the stockbreeding wastewater. In addition, manganese (Mn) and arsenic (As) are included in the mine treated water, etc., and are known as a source of water pollution. Natural zeolites are used to remove ammonia nitrogen in water but it have a low adsorption capacity. In order to improve the low adsorption capacity of the natural zeolite, ion substitution was carried out with $Na^+$, $Ca^{2+}$, $K^+$ and $Mg^{2+}$. The adsorption capacity and removal rate of ammonia nitrogen ($NH_4-N$) were the highest at 0.66 mg/g and 89.8% in $Na^+$ ion exchanged zeolite. Adsorption experiments of Mn and As were performed using ion exchanged zeolites. Ion exchanged zeolite with $Mg^{2+}$ showed high adsorption capacity and removal rates of Mn and As.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.09a
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• pp.164-167
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• 2001

본 연구에서는 포항제철소에서 제철부산물로 발생되는 제강분진을 전처리 없이 산화촉매로 사용하여 김포 수도권 매립지의 침출수 처리공정에서 펜톤산화조에 유입되는 원수를 대상으 로 과산화수소를 이용한 연속식 산화처리 실험을 수행하였다. 먼저 회분식 실험결과를 바탕 으로 최적 반응조건에서 lab-scale 연속식 기초반응실험과 자체 설계.제작한 연속산화공정에서의 처리실험을 수행하였다. 또한 기존의 펜톤산화공정에서 Fe 공급원으로 사용되고 있는 FeSO$_4$.7($H_2O$)와의 반응성 비교실험도 수행하였다. 반응기간동안 일정 pH를 유지하기 위해 pH controller를 사용하였으며 침출수 수질은 CODcr로 나타내었다. 반응 pH 3.5, 체류시간 1 hr, 과산화수소 주입량 1,500mg/1에서 제강분진과 FeSO$_4$.7($H_2O$)를 각각 주입하여 수행한 연속처리 기초실험에서는 제강분진을 산화반응촉매로 사용한 경우에 침출수CODcr 처리율 62%, 과산화수소의 분해율 52%를 나타내었다. FeSO$_4$.7($H_2O$)를 산화반응 촉매로 사용한 경우에는 약 65-70%정도의 다소 높은 처리효율을 나타낸 반면에 과산화수소의 소비량은 제강분진의 경우보다 약 20%이상의 높은 값을 나타내었다. 연속산화공정 실험에서는 운전 3시간 이후에 유출수 중의 CODcr과 $H_2O$$_2$의 농도가 안정된 값을 나타내었다. 이 때 산화 반응조의 침출수 CODcr 제거효율은 약 43%이었으며, 처리수의 농도는 현재의 침출수 방류기준 이하로 나타났다. 결론적으로 침출수의 연속식 산화처리 실험결과, 처리효율과 경제성에서 제강분진의 산화촉매활용 공정의 개발 가능성이 매우 높은 것으로 나타났다.ell에 의해 완전분해 되었으며, 함께 존재시 TC는 Fe$^{\circ}$만으로는 분해가 되지 않았지만 cell에 의해 완전분해 되었으며, 함께 존재시 TCE분해에 저해작용을 미치는 것으로 나타났다.술의 첨가가 요구되고 있다. 따라서, 산성광산배수 오염지대에 대해 획일적으로 같은 처리방법을 채택하여 사용하는 것보다 각 지역 또는 광산산성폐수가 유출되어 나오는 광산폐기물의 특성 등을 고려하여 거기에 맞는 기술들을 복합적으로 또는 단독으로 사용하되 처리방법 채택 시 신중을 기할 것이 요망된다.정시에는 SeaWiFS 위성과 관련된 global algorithms 중에서 490nm와 555nm의 복합밴드를 포함하는 OC2 알고리즘(ocean color chlorophyll 2 algorithm)을 사용하는 것이 OC2 series 및 OC4 알고리즘보다 좋은 추정 값을 도출할 수 있을 것으로 기대된다.환경에서는 5일에서 7월에 주로 이 충체의 유충이 발육되고 전파되는 것으로 추측되었다.러 가지 방법들을 적극 적용하여 금후 검토해볼 필요가 있을 것이다.잡은 전혀 삭과가 형성되지 않았다. 이 결과는 종간 교잡종을 자방친으로 하고 그 자방친의 화분친을 사용할 때만 교잡이 이루어지고 있음을 나타내고 있다. 따라서 여교잡을 통한 종간잡종 품종육성 활용방안을 금후 적극 확대 검토해야 할 것이다하였다.함을 보이고 있다.X> , ZnCl$_{3}$$^{-}$같은 이온과 MgCl$^{+}$, MgCl$_{2}$같은 이온종을 형성하기 때문인것 같다. 한편 어떠한 용리액에서던지 NH$_{4}$$^{+}$의 경우 Dv값이 제일 작았다. 바. 본 연구의 목적중의 하나인 인체유해 중금속이온인 Hg(II), Cd(II)등이 NaCl같은 염화물

• Economic and Environmental Geology
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• v.28 no.3
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• pp.213-220
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• 1995

Geochemistry of stream water and sediment collected in the vicinity of the Donghae coal mine in the Samchuk coalfied were investigated in order to evaluate the environmental impacts of acid mine drainage. The pH of stream water ranges from 2.85(at 2 km away from the mine) to 7.92(at uncontaminated tributary). The main cation and anion species in the upper stream are $Ca^{2+}$ and $SO_{4}{^2-}$, respectively. The level of pH and the amount of $HCO^{3-}$ in stream water increase to the downstream and where uncontaminated small tributaries are joining, and in the area covered with limestone. From the results of thermodynamic calculation, the main forms of iron in stream water are estimated as $Fe^{2+}$ and $FeSO_{4}{^0}$, and most of them could be precipitated as FeO(OH) with increase of pH. The white precipitates in stream sediments particularly found around the coal mine are proved to be $Al(OH)_3$ by XRD and XRF analysis. As a result of investigation for seasonal variation of AMD, the level of pH decreased and conductivity increased in dry season.