• Journal of Korean Society of Environmental Engineers
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• v.31 no.12
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• pp.1151-1160
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• 2009

Perfluorinated compounds (PFCs) have been recognized as emerging environmental pollutants and are widely distributed all over the world. These compounds are hardly degradable and cause bioaccumulation and biomagnification during present for a long time in the environment: thereby after adversely biota and human bodies. It is difficult to remove PFCs using conventional water/wastewater treatment because of resistant property to photodecomposition, biodegradation and chemical decomposition. Moreover, domestic literature data on the pollution of PFCs in rivers and lakes are limited. In this paper, species, sources and risk of PFCs as well as behavior properties in drinking water/wastewater and treatment processes are demonstrated to encourage the domestic concern about PFCs.

• Proceedings of the Korea Water Resources Association Conference
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• 2020.06a
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• pp.286-286
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• 2020

인공함양은 대수층함양관리 중 하나의 기법이며 하수처리장 방류수의 영향을 직·간접적으로 받은 물을 지하대수층에 함양하여 수질의 향상을 기대할 수 있다. 그러나 방류수의 영향으로 인해 다수의 미량유해물질들이 대수층으로 유입됨에 따라 함양 후 회수할 때 이들의 검출이 빈번해졌다. 이에 따라 이 미량유해물질의 제거를 위해 인공함양의 후속 공정으로 나노막 여과를 고려하여 인공함양과 나노막 공정을 통하여 미량유해물질의 거동을 파악하고자 하였다. 본 연구에서는 인공함양 지하저수지 모사 컬럼을 설계하여 실험하였다. 서울특별시 탄천 하류에서 샘플링한 물을 원수로 사용하였으며 인공함양에 앞서 염소, 과망간산염, 오존의 3종류 산화 전처리를 통하여 그 영향을 확인하고자 하였다. 함양기간은 2.5일이었으며 함양 후 나노막 장치를 통하여 최종 유출수를 획득하였다. 인공함양 결과 용존유기물은 45%~63% 수준에서 제거가 되어 인공함양시 용존유기물의 제거가 가능함을 확인하였다. 산화 전처리에 따른 동화가능유기탄소의 증가로 인하여 생분해가 주요 기작인 인공함양 처리를 통하여 동화가능유기탄소의 제거율이 유기용존탄소의 제거율에 직접적으로 영향을 주었음을 알 수 있었다. 미량유해물질로 알려진 과불화화합물의 경우 산화 전처리에 따른 제거는 관찰되지 않았으며 잔류의약물질의 경우 대상 물질의 물리·화학적 특성에 따라 산화시 제거가 가능함을 확인하였다. Iopromide와 같은 조영제의 경우 오존 산화를 통하여 98% 이상 제거되어 산화를 통한 제거가 가능함을 확인하였다. 인공함양시 과불화화합물은 분자량이 큰 PFNA, PFDA, PFOS 등이 제거되었으며 그 제거율은 각각 최대 >99%까지 도달하였다. 분자량이 작은 과불화화합물의 경우 인공함양을 통과하는 경향을 보였다. 잔류의약물질의 경우 생분해가 용이한 물질은 제거가 됨을 확인하였으며 carbamazepine 등 제거가 안 되는 물질은 제거율이 18% 미만으로 확인하였다. 나노막 여과 결과 과불화화합물이 최대 >99%까지 제거됨을 확인하였으며 미량유해물질의 경우에도 대부분의 물질이 제거됨을 확인하였다.

• Analytical Science and Technology
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• v.23 no.4
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• pp.331-346
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• 2010

Perfluorinated compounds have characteristics of resistance to heat, acidic, basic conditions and also resist water, oil, grease, pollutant. Futhermore they are used by various industrial material, nowadays, they produced in large scale for indutrial and commercial areas. However, they also resist metabolizing and degrading in environmental system (plant, animal, even human body). Moreover, in animal's bodies, PFCs can be accumulated in organ (eg; liver) and lead to liver cell necrosis even oncogenesis. Perfluorinated compounds are newly registered as new persistent organic pollutants (POPs) on Stockholm convention in 2009. Therefore necessity for analytical methodology for determination of PFCs in various environmental samples is even more increased. This study discussed sample preparation and instrumental conditions for the analysis of PFCs in environmental and biota samples.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.5
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• pp.326-334
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• 2012

To determine the concentrations and the mass flow of selected 10 perfluorinated compounds (PFCs), a field study was conducted in a wastewater treatment plant. Raw influent, primary influent, primary effluent, aeration tank effluent, secondary effluent, final effluent, dehydration liquor, primary sludge, thickened sludge, final sludge were collected over 3 days in the summer and the winter respectively. Collected samples were equally mixed and then served as an analytical sample. Total 10 compounds were analyzed. In terms of treated water, the concentration of perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA) were in range of N.D.~26.29 ng/L and N.D.~38.15 ng/L respectively. Perfluorononanoate (PFNA) and perfluorohexanesulfonate (PFHxS) were ranged from N.D. to 36.79 ng/L and from N.D. to 24.36 ng/L. In terms of sludges, a concentration of PFOS, PFOA, and perfluorodecanesulfonate (PFDS) were detected from 6.82 to 59.37 ng/g, from 0.13 to 0.37 ng/g, from N.D. to 0.83 ng/g respectively. Mass loading for PFCs increased during wastewater treatment except for PFNA. The observed increase in mass flow of PFCs may have resulted from biodegradation of precursor compounds.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2016.10a
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• pp.262-262
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• 2016

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.18 no.3
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• pp.39-43
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• 2004

국제적인 환경 규제 문제($CO_2$, SF$_{6}$(육불화황), PFC (과불화화합물) 등)가 새로운 무역장벽으로 등장하여 우리나라 주요 산업 부문에 미치는 영향이 점차 현실로 나타나고 있다. 이러한 환경 규제에 적절한 대처를 하기 위해 에너지 소비 증가와 이에 따르는 에너지 소비 패턴 및 인식에 대한 새로운 접근 방법이 요구되고 있다. 그동안 전력기기의 고효율화, 에너지 효율 향상과 수요관리 강화, 미활용 에너지원의 이용률 제고, 집단에너지 보급 확대 등 하드웨어적인 기술개발에 중점을 두고 추진되었으나, 앞으로는 전원설비, 전력전송 설비, 부하설비 등의 최적 설계기술을 통한 에너지절약 기술개발과 같은 소프트웨어적인 기술 개발이 요청되고 있다. (중략)

• Journal of Korean Society of Environmental Engineers
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• v.35 no.2
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• pp.84-93
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• 2013

The aims of this study were to investigate and confirm the occurrence and distribution patterns of perfluorinated compounds (PFCs) in Nakdong River basin (mainstream and its tributaries). 7 (PFOS, PFHpA, PFOA, PFNA, PFDA, PFUnDA and PFDoDA) out of 11 PFCs were detected in 29 sampling sites and PFOA and PFHpA were predominant compounds in upstream, but PFUnDA, PFDoDA and PFOS were predominant compounds in middle stream of Nakdong River basin. The total concentration levels of PFCs on February 2009 and on August 2009 in surface water samples ranged from 4.3. to 1168.2 ng/L and 16.4 to 627.8 ng/L, respectively. The highest concentration level of PFCs in the mainstream and tributaries in Nakdong River were Goryeong and Jincheon-cheon, respectively. The sewage treatment plants (STPs) along the river affect the PFCs levels in river and the PFCs levels decreased with downstream because of dilution effects.

• Analytical Science and Technology
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• v.27 no.3
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• pp.167-171
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• 2014

Hydrofluoric acid (HF), a typical inorganic acid, has been used in the industry for its various usage and classified as the toxic compound, because it can cause the pneumonia and pulmonary edema when it was exposed to respiratory organs. The official environmental analytical method for fluorine and its compound in waste has not been developed. For this reason, we have faced some problem to treat the contaminated wastes by the HF leakage from industrial process. In this study, prepared for analytical method for combustible waste (crop, trees, etc.) generated from HF leaking accident and to be applied as the official analytical method for fluorine contaminated waste when the fluorine and its compound will be regulated as a hazardous material by the waste management law later.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.5
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• pp.303-311
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• 2015

To determine the concentrations of selected 10 perfluorinated compounds (PFCs), a field study was conducted in the water body of Yeongsan River Water System. Raw water samples were collected in the spring and the fall, respectively, which included 18 sampling sites. Collected samples were equally mixed and then served as an analytical sample. The concentration of perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA) were in range of 20.80-92.0 ng/L and ND-28.40 ng/L respectively. Perfluorononanoate (PFNA) and perfluorohexanesulfonate (PFHxS) were ranged from ND to 42.20 ng/L and from ND to 11.47 ng/L. The detection frequencies of other PFCs selected in this study were very sparse at very low concentrations, except for PFOS, PFOA, PFNA and PFHxS. PFOS was higher detection frequency and concentration in both spring and fall, PFOA and PFNA were in spring, and PFHxS was in fall. As a result, the observed concentrations of PFCs in the downtown water area of Gwangju, located in the wastewater treatment plants, were relatively higher than other sampling points.

• Journal of the Korean GEO-environmental Society
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• v.18 no.11
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• pp.5-12
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• 2017

Perfluorinated compounds (PFCs) as environmental pollutants are an important environmental issue. However, little is known on the PFCs monitoring of sea waters around estuaries on the East and West Coasts of Korea. This study shows the monitoring results of PFCs in sea waters in these Coasts. Among 10 PFCs selected in this study, concentrations of perfluorooctanesulfonate (PFOS), perfluorooctanoate (PFOA), perfluorobutane sulfonate (PFBS), and perfluorohexane sulfonate (PFHxS) in the East Coast were 9.6-50.7 ng/L (total mean${\pm}$standard deviation: $26.14{\pm}12.66ng/L$), 13.79-44.58 ng/L ($27.95{\pm}11.41ng/L$), limit of quantification (LOQ)-2.6 ng/L ($0.96{\pm}1.15ng/L$), and 2.95-11.05 ng/L ($4.25{\pm}2.57ng/L$), respectively. In the West Coast, concentrations of PFOS, PFOA, PFBS, and PFHxS were 27.66-51.71 ng/L ($36.27{\pm}7.79ng/L$), 8.97-22.53 ng/L ($14.47{\pm}4.25ng/L$), LOQ-2.27 ng/L ($1.63{\pm}0.93ng/L$), and 3.0-7.66 ng/L ($4.27{\pm}1.49ng/L$), respectly. Other PFCs were below LOQ. The result of this study provides the distribution pattern of PFCs for assessing environmental pollution in two coastal areas of Korea.