• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.277.2-277.2
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• 2016

현재 화합물 반도체 나노구조는 광학적, 전기적 특성을 기반으로 하는 단전자 트랜지스터, 적외선 검출기, 레이저, 태양전지와 같은 분야에 응용하기 위한 많은 연구가 진행되고 있다. 특히 양자점은 3차원으로 구속되어 있는 상태 밀도를 갖고 있어 레이저 응용 시 낮은 문턱 전류 밀도, 높은 이득, 높은 열적 안정성을 기대되고 있지만 양자점의 운반자 수집과 열적 안정성의 한계가 여전히 존재한다. 이러한 문제를 해결하기 위해 다양한 방법이 연구되고 있으며, 그 중 단층 양자점에 비해 운반자 수집과 열적 안정성이 뛰어난 다층 양자점이 결합된 구조에 대한 연구가 활발히 이루어지고, 다층으로 성장된 양자점 구조는 양자점의 크기 분포 조절이 용이하고 양자점 층간의 전기적 결합력이 강한 특성이 있다. 본 연구에서는 분자 선속 에피 성장법(Molecular Beam Epitaxy; MBE)과 원자 층 교대 성장법(Atomic Layer Epitaxy; ALE)으로 CdTe/ZnTe 다층 양자점을 ZnTe 장벽층의 두께를 변화하면서 성장 후 광학적 특성을 연구하였다. 저온 광루미네센스 측정(Photoluminescence; PL)을 통하여 ZnTe 장벽층 두께가 증가할수록 양자점의 PL 피크가 높은 에너지로 이동함을 알 수 있었는데, 이는 ZnTe 장벽층의 두께가 증가할수록 양자점 층간의 결합력이 감소하면서 양자점의 크기가 작아졌기 때문이다. 그리고 ZnTe 장벽층의 두께가 증가할수록 PL 세기가 커지는 것을 알 수 있었는데, 이는 ZnTe 장벽층의 두께가 증가할수록 더 많은 운반자가 양자점으로 구속되기 때문이다. 또한 온도 의존 광루미네센스 측정 결과 ZnTe 장벽층의 두께가 증가할수록 열적 활성화 에너지가 커지는 것을 관찰하였고, 시분해 광루미네센스 측정을 통해 ZnTe 장벽층의 두께에 따른 운반자 동역학에 대해 연구하였다. 이와 같은 결과 CdTe/ZnTe 다층 양자점 구조에서 장벽층의 두께에 따른 광학적 특성에 대해 이해 할 수 있었다.

• Polymer(Korea)
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• v.29 no.2
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• pp.122-126
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• 2005

The effect of Al-MCM-41 preparation methods on the catalytic degradation of linear low density polyethylene (LLDPE) was investigated. Al-MCM-41 catalysts were synthesized by direct method (Al-MCM-41-D) and post treatment method (Al-MCM-41-P) and their characteristics were elucidated by XRD, BET, $NH_3\;TPD,\;^{27}Al$ MAS NMR. TGA kinetic analysis showed that the catalytic activation energies of Al-MCM-41-D and Al-MCM-41-P were 191.54 and 114.26 kJ/mol, respectively. The higher catalytic activity of Al-MCM-41-P would be attributed to its smaller pore size as well as higher number of acid sites that are accessible.

• Applied Chemistry for Engineering
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• v.33 no.2
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• pp.151-158
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• 2022

In this paper, parameter characteristics such as pH effect, isotherm, kinetic and thermodynamic parameters and competitive adsorption of dyes including malachite green (MG), direct red 81 (DR 81) and thioflavin S (TS), which have different functional groups, being adsorbed onto activated carbon were investigated. Langmuir, Freundlich and Temkin isotherm models were employed to find the adsorption mechanism. Effectiveness of adsorption treatment of three dyes by activated carbon were confirmed by the Langmuir dimensionless separation factor. The mechanism was found to be a physical adsorption which can be verified through the adsorption heat calculated by Temkin equation. The adsorption kinetics followed the pseudo second order and the rate limiting step was intra-particle diffusion. The positive enthalpy and entropy changes showed an endothermic reaction and increased disorder via adsorption at the S-L interface, respectively. For each dye molecule, negative Gibbs free energy increased with the temperature, which means that the process is spontaneous. In the binary component system, it was found that the same functional groups of the dye could interfere with the mutual adsorption, and different functional groups did not significantly affect the adsorption. In the ternary component system, the adsorption for MG lowered a bit, likely to be disturbed by the other dyes meanwhile DR 81 and TS were to be positively affected by the presence of MG, thus resulting in much higher adsorption.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.83-83
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• 2012

본 강연에서는 방사광 연X-선 분광현미경학(spectro-microscopy) 중에서, 표면에서 방출되는 광전자를 이용하는 SPEM (Scanning Photoelectron Microscopy)과 PEEM (Photoemission Electron Microscopy)을 소개하고자 한다. SPEM은 입사하는 X-선을 작은 크기로 집속하여 특정의 작은 공간에서 광전자분광학(XPS) 데이터를 얻거나 특정 광전자에너지의 공간분포를 얻게 해주며, PEEM은 입사한 X-선에 의해 발생한 광전자를 전자렌즈 원리로 영상을 맺히게 하여 광전자의 발생 분포를 구하게 한다. 이들은 균일하지 아니한 이종의 표면 연구에 매우 유용한 측정기법들이지만, 그 원리 및 구성은 많은 차이점들을 가지고 있다. 예를 들어, SPEM은 시료를 scanning하면서 XPS에 보다 충실한 타입이고 PEEM은 full field imaging 타입으로 표면변화의 동역학 연구에 강점이 있다. 본 강의에서는 이들 각각의 원리, 장점들에 대해서 설명하고, 활용 예를 제시하고자 한다. 활용 분야에 있어서, SPEM의 경우는 포항가속기연구소의 SPEM으로 수행되었던 DMS, graphene, nano-lithography, OLED, 등 반도체 및 나노 소재, 소자에의 활용에 대한 예를 제시할 것이다. PEEM의 경우는 포항가속기연구소의 응용 예와 박막 형태의 magnetic material에 대한 예들을 제시할 것이다.

• Journal of Environmental Science International
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• v.11 no.10
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• pp.1089-1096
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• 2002

The objectives of this study were to investigate the desulfurization kinetics of paper sludge and limestone in a fluidized bed reactor according to bed temperature and air velocity. The experimental results were presented as follows ; First, the bed temperature had a great influence on the desulfurization efficiency of limestone and paper sludge. In paper sludge, the optimum condition in desulfurization temperature was at 80$0^{\circ}C$ and in limestone, that was at 850 $^{\circ}C$ or 900 $^{\circ}C$ Second, as air velocity increased, the desulfurization efficiency(or the absorbed amount of sulfur dioxide) by limestone and paper sludge decreased. And the absorbed amount of sulfur dioxide by paper sludge was larger than that of by limestone. Third, as the velocity increased and the optimum desulfurization temperature became, ks and the removal efficiency increased. So, ks, kd highly depended on the air velocity and bed temperature.

• Journal of the KSME
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• v.33 no.10
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• pp.871-883
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• 1993

차량의 승차감 및 조안 성능을 결정하는 중요한 인자인 현가장치(Supension System) 설계의 최적화를 기하며 실차육성기간을 줄이고 설계 업무의 효율성을 높이기 위하여 각종 차량 특성 인자의 수치화를 통해 여러 가지 해석을 수행하게 된다. 이러한 해석 과정으로는 크게 현가장 치의 기구학적 특성-Kinematic Analysis-과 부시 (Bush)와 스프링 (Spring) 등의 컴플라이언스 (Compliance) 효과 - 쿼지스테틱 어낼러시스 (Quasistatic Analysis)-와 전체차량의 주행 시뮬 레이션 (simulation)을 통한 설계차량의주행안정성 검토-풀 비클 어낼러시스 (Full Vehicle Analysis)- 등이 있다. 이 글에서는 승용차의 현가장치중 대표적인형인 맥퍼슨 스터러트형에 대 하여 1) 기구학적 특성, 2) 부시와 스프링 등의 컴플라이언스 효과, 3) 전체차량의 주행 시뮬레 이션을 통한 차량의 주행 안정성 검토의 순으로 각 단계별 주요 검토 항목과 인자, 그리고 실제 차량에서의 현상에 대하여 소개한다.

• Journal of the Korea Society for Simulation
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• v.19 no.3
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• pp.37-43
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• 2010

In field, one can observe without difficulties that two flocks are intersected or combined with each other. For example, a fish flock in a stream separates into two part by obstacles (e.g. stone) and rejoins behind the obstacles. The dynamics of two flocks guided by their leader were studied in the situation where the flocks cross each other with a crossing angle, ${\theta}$, between their moving directions. Each leader is unaffected by its flock members whereas each member is influenced by its leader and other members. To understand the dynamics, I investigated the order parameter, ${\phi}$, defined by the absolute value of the average unit velocity of the flocks' members. When the two flocks were encountered, the first peak in ${\phi}$ was appeared due to the breaking of the flocks' momentum balance. When the flocks began to separate, the second peak in ${\phi}$ was observed. Subsequently, erratic peaks were emerged by some individuals that were delayed to rejoin their flock. The amplitude of the two peaks, $d_1$ (first) and $d_2$ (second), were measured. Interestingly, they exhibited a synchronized behavior for different ${\theta}$. This simulation model can be a useful tool to explore animal behavior and to develop multi-agent robot systems.

• Phonetics and Speech Sciences
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• v.13 no.2
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• pp.1-7
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• 2021

Speech is a spatiotemporally coordinated structure of constriction actions at discrete articulators such as lips, tongue tip, tongue body, velum, and glottis. Like other human movements (e.g., reaching), each action as a linguistic task is completed by a synergy of involved basic elements (e.g., bone, muscle, neural system). This paper discusses how speech tasks are dynamically related to joints as one of the basic elements in terms of robotics of speech production. Further this introduction of robotics to speech sciences will hopefully deepen our understanding of how speech is produced and provide a solid foundation to developing a physical talking machine.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.24 no.2
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• pp.117-122
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• 2014

A novel method to reduce the vibration of drum type washing machine is proposed. Recently, as the capacity of the drum-type washing machine gets expanded and its washing performance is improved, its market share is increasing in the whole world. But, the capacity of washing machine is limited because of door size and built-in washing machine size. The vibration of washing machine is caused by unbalanced cloths in high spining drum, and the displacement of tub is maximized at transient range about 3 Hz(180 rpm). Previous researches were concerned about steady-state vibration in spinning. In this study, concerned about transient vibration and the displacement of tub is decreased by using gyroscope system. Mutibody dynamic model of washing machine include gyroscope is designed and the vibration of tub have been reduced by 44.7 % over original.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2007.05a
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• pp.387-392
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• 2007

Turbomachinery such as turbines, pumps and compressors, which are installed in transportation systems such as warships, submarines and space vehicles, etc., often perform crucial missions and are exposed to potential dangerous impact environments such as base-transferred shock forces. To protect turbomachinery from excessive shock forces, it may be needed to accurately analyze transient responses of rotors, considering the dynamics of mount designs to be applied with. In this study a generalized FE transient response analysis model, introducing relative displacements, is firstly proposed to accurately predict transient responses of a flexible rotor-bearing system with mount systems to base-transferred shock forces. In the transient analyses the state-space Newmark method of a direct time integration scheme is utilized, which is based on the average velocity concept. Results show that for the identical mount systems considered, the proposed FE-based detailed flexible rotor model yields more reduced transient vibration responses to the same shocks than a conventional simple model or a Jeffcott rotor. Hence, in order to design a rotor-bearing system with a more compact light-weighted mount system, preparing against any potential excessive shock, the proposed FE transient response analysis model herein is recommended.