• Title/Summary/Keyword: 과냉각 액체

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Supercooled Liquid, Glass and Glass Transition (과냉각 액체, 유리 그리고 유리 전이)

  • Kim, Hack-Jin
    • Journal of the Korean Chemical Society
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    • v.53 no.2
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    • pp.99-110
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    • 2009
  • Characteristics of supercooled liquid and glass, which are the states involved in glass transition, are reviewed. These states are non-equilibrium states, therefore, the glass transition is different from the usual phase transitions. Theories of glass transition and related experimental methods are briefly summarized.

Liquid Oxygen Supercooling System in the 75 tonf-class Liquid Engine Combustion Test Facility (75톤급 액체엔진 연소시험설비의 액체산소 과냉각 시스템)

  • Seo, Daeban;Yoo, Byoungil;Lee, Jungho;Cho, Namkyung;Kim, Seunghan;Han, Yeoungmin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.1080-1083
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    • 2017
  • In the design of KSLV-II, there is a scenario in which supercooled liquid oxygen is supplied to prevent a geysering phenomenon in the oxidizer pipe and a cavitation phenomenon at the pump inlet. To verify this condition in the engine development test phase, a system that supplies supercooled liquid oxygen to the engine was applied in the engine combustion test facility. In this system, supercooling methods using a vacuum ejector and using helium injection to the tank were appied. Both tests were carried out for about 17 minutes. Supercooling results of about 3.3K for the ejector test and about 2.2K for the helium injection test were obtained at the 50% level of the tank.

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헬륨가스 분사에 의한 액체질소 냉각에 관한 연구

  • Chung, Yong-Gap;Cho, Nam-Gyeong;Kil, Kyeong-Seop;Song, Yi-Hwa;Kim, Yu;Cho, Gwang-Rae
    • Aerospace Engineering and Technology
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    • v.3 no.1
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    • pp.205-212
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    • 2004
  • In this paper, to satisfy the temperature requirement of turbopump-inlet condition, the cooling of cryogenic propellant is performed at the simulated suction-line of the Launch Vehicle. The cooling method is by using gas helium injection. This paper investigates the effect of helium injection on liquid nitrogen, which simulates the liquid oxygen. By using helium injection, subcooling of liquid nitrogen can be achieved and in the condition of v/vL≒0.8min-¹ approximately in four minutes subcooling temperature can be achieved.

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Experimental Study of Liquid Oxygen Sub-cooling by Helium Injection (헬륨분사를 통한 액체산소 과냉각에 관한 실험적 연구)

  • Kwon Oh-Sung;Cho Nam-Kyung;Chung Yong-Gahp;Ha Seong-Up;Lee Joong-Youp;Kim Hyun-Joong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • v.y2005m4
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    • pp.179-182
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    • 2005
  • Test of liquid oxygen sub-cooling by helium injection, which is one of the method of temperature conditioning of cryogenic propellant in liquid propulsion rocket, is performed. The sub-cooling effect at different He injection flow rate with the same initial liquid oxygen mass is compared. Test results showed liquid oxygen temperature decrease of $5\sim6^{\circ}C$ under test condition. And the required time for cooling is inversely proportional to He injection flow rate.

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A novel time scale of dynamic heterogeneity in a supercooled liquid system

  • Mun, Seok-Jin;Park, Gye-Hyeon;Park, Sang-Won;Jeong, Yeon-Jun
    • Proceeding of EDISON Challenge
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    • 2015.03a
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    • pp.138-146
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    • 2015
  • 액체 상태의 물질이 매우 급속하게 냉각되면 일반적으로 과냉각액체(supercooled liquid) 상태에 도달한다. 과냉각액체는 더 낮은 온도에서 유리상(glass phase)으로 상전이를 일으킨다고 알려져 있는데, 이때 나타나는 동역학적 불균일성(dynamic heterogeneity)은 상전이를 기술하는데 중요한 역할을 한다. 그러나 일반적인 액체의 상전이를 연구할 때 주로 사용되던 상관함수(correlation function)으로는 이러한 불균일성을 정량적으로 표현하기 어렵기 때문에 동역학적 민감도(dynamic susceptibility)나 multi-time correlation function 등 동역학적 성질(dynamic property)로부터 특징적인 시간 개념 및 거리 개념을 도출하려는 연구가 많이 진행되어 왔다. 본 논문에서는 일반적으로 특징적인 거리 개념을 도출해 내는데 사용되는 4점 밀도 상관함수(four-point density correlation function)인 dynamic susceptibility(${\chi}^4$)가 입자 밀도의 요동(fluctuation)의 상관관계(correlation)가 지속되는 특징적인 시간 개념에 대한 정보 또한 포함하고 있다는 점에 주목하였다. 이에 따라 ${\chi}^4$의 시간에 대한 적분인 ${\tau}_4$를 새롭게 도입하였으며 그 결과로 ${\tau}_4$는 three-time density correlation function으로부터 도출한 ${\tau}_{Dh}$와 같은 축척(scaling)을 가지는 것을 확인하였다. 과냉각액체에 대한 장난감 모형(toy model)의 일종인 "Lennard-Jones potential 하에서 운동하는 서로 다른 두 종류의 입자들"을 연구에 사용하였다.

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Investigation of helium injection cooling to liquid oxygen chamber (헬륨분사를 통한 액체산소 냉각의 이론적 고찰 및 해석과 시험의 비교)

  • Gwon, O-Seong;Jo, Nam-Gyeong;Jeong, Yong-Gap;Lee, Jung-Yeop
    • Aerospace Engineering and Technology
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    • v.5 no.2
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    • pp.134-142
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    • 2006
  • Sub-cooling of cryogenic propellant by helium injection is one of the most effective methods for suppressing bulk boiling and keeping sub-cooled liquid oxygen before rocket launch. In order to design the cooling system, understanding of the limitations of heat and mass transfer is required. In this paper, an analytical model for the helium injection system is presented. This model's main feature is the representation of bubbling system using finite-rate heat transfer and instantaneous mass transfer concept. With this simplified approach, the effect of helium injection to liquid oxygen system under several circumstances is examined. Experimental results along with simulations of single bubble rising in liquid oxygen and bubbling system are presented with various helium injection flow rates, and with change of oxygen chamber pressure.

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Powder Metallurgy Process in Bulk Amorphous Alloys (벌크 아몰퍼스 소재의 분말야금 공정기술 동향)

  • Kim, Hwi-Jun;Bae, Jung-Chan;Kim, Do-Hyang
    • Journal of Powder Materials
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    • v.13 no.6 s.59
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    • pp.387-395
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    • 2006
  • 본고에서는 고유한 원자구조에 기인한 우수한 특성으로 인해 구조재료 및 기능재료로서 그 활용이 기대되고 있는 벌크 아몰퍼스 소재에 있어 온간압출, 온간압연, 방전 플라즈마 소결(Spark Plasma Sintering)등 과냉각액체온도구간에서의 점성유동을 이용한 고화성형 공정의 최근 기술동향에 대해 간략히 소개했다.

Thermal Stability and Behavior of Isothermal Crystallization in Fe-P-C-B-(AI-Ge) Amorphous Alloys (Fe-P-C-B-(AI-Ge)계 비정질합금의 열적 안정성과 등온결정화 거동)

  • Jeon, U-Yong;Guk, Jin-Seon;Bae, In-Seong;Seol, Gyeong-Won
    • Korean Journal of Materials Research
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    • v.8 no.11
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    • pp.1026-1030
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    • 1998
  • Thermal properties of Fe- base amorpous alloys were investigated. $Fe_{80}P_6C_{12}B_{12}$ and $Fe_{73}P_{11}C_6B_4AI_4Ge_2$ amorphous alloys were fabricated by melt spinning method and thermal analysis was done by differential scanning calorimeter. After isothermal crystallization. the Avrami exponents of $Fe_{80}P_6C_{12}B_{12}$ and $Fe_{73}P_{11}C_6B_4AI_4Ge_2$ amorphous alloys were 1.8-2.2 and 2.5-4.0, respectively. It means the former alloy shows diffusion controlled growth and the latter one shows interface controlled growth. For $Fe_{80}P_6C_{12}B_{12}$ and $Fe_{73}P_{11}C_6B_4AI_4Ge_2$ amorphous alloys. the activation energies of isothermal crystallization was 353 and 371kJlmol. Also the activation energies of nucleation and growth were 301, 324kJlmol and 273. 30lkJ/mol, respectively. Thus $Fe_{73}P_{11}C_6B_4AI_4Ge_2$ amorphous alloy is considered to be more stable than $Fe_{73}P_{11}C_6B_4AI_4Ge_2$ amorphous alloy.

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Cooling of Cryogenic Liquids by Gas Helium Injection (I) (가스분사에 의한 극저온 액체의 냉각에 관한 연구 (I))

  • Song, Yi-Hwa;Choi, Young-Hwan;Kim, Yoo;Chung, Yong-Gahp;Cho, Nam-Kyung;Jeong, Sang-Kwon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2003.10a
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    • pp.141-144
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    • 2003
  • In this paper, to satisfy the temperature requirement of turbopump-inlet condition, the cooling of cryogenic propellant is performed at the simulated suction-line of the Launch Vehicle. The cooling method is by using Gas helium injection. This study investigates the effect of helium injection on the liquid nitrogen which simulates the liquid oxygen. By using helium injection, the subcooling of liquid nitrogen can be achieved within four minute when the ratio of gas volume flowrate to the volume of L$N_2$ is approximately v/v$_{L}$≒0.8min$^{-1}$ . .

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