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Biological production of 1,3-propanediol using crude glycerol derived from biodiesel process (바이오디젤 부산물인 폐글리세롤을 이용한 생물학적 1,3-propanediol 생산)

  • Jun, Sun-Ae;Kang, Cheol-Hee;Kong, Sean-W.;Sang, Byoung-In;Um, Young-Soon
    • KSBB Journal
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    • v.23 no.5
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    • pp.413-418
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    • 2008
  • The production of 1,3.propanediol (1,3-PD) was investigated with Klebsiella pneumoniae DSM2026 and K. pneumoniae DSM4799 using crude glycerol obtained from biodiesel industry. Crude glycerol was used without prior purification to investigate effects of impurities in crude glycerol on 1,3-PD production. In the batch cultures, 1,3-PD production with crude glycerol was $1.1{\sim}2.5$ times higher than that with pure glycerol, indicating that crude glycerol is even a better substrate than pure glycerol for 1,3-PD fermentation. When glucose was added, 1,3-PD production and yield decreased in spite of enhanced cell growth. Furthermore, the addition of glucose was found to increase 2,3-butanediol, a by-product, significantly because of the change in metabolism in the presence of glucose. In semi-batch cultures without glucose addition, 26 g/L 1,3-PD was produced with crude glycerol, which was $2{\sim}3$ times higher than that with pure glycerol. Based on our results, it was clearly shown that crude glycerol is an effective substrate for biological 1,3-PD production, making it more feasible to produce 1,3-PD at a lower price.

The Effects of Zeolite-Type Catalysts on the Pyrolysis Reaction of PP to Produce Fuel-oil (폴리프로필렌 수지 이용 연료유 생성을 위한 열분해 반응에서 제올라이트계 촉매의 영향)

  • Bak, Young-Cheol;Choi, Joo-Hong;Oh, Se-Hui
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.442-448
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    • 2012
  • The effects of zeolite-type catalysts addition on the thermal decomposition of the PP resin have been studied in a thermal analyzer, a Pyrolyser GC-mass, and a small batch reactor. The zeolite type catalysts tested were natural zeolite, used FCC catalyst, and ZSM-5. As the results of TGA experiments, the pyrolysis starting temperature for PP varied in the range of $330{\sim}360^{\circ}C$ according to the heating rate. Addition of the zeolite type catalysts in the PP resin increased the pyrolysis rate in the order of used FCC catalyst> natural zeolite> ZSM-5 > PP resin. Adding the used FCC catalyst in the PP reduced most effectively the pyrolysis finishing temperature. In the PY-G.C. mass experiments, addition of zeolite type catalysts decreased the molecular weight of pyrolyzed product. In the batch system experiments, the mixing of used FCC catalyst enhanced best the initial yield of fuel oil, but the final yield of fuel oil was 2% higher in the case of mixing of natural zeolite. Also in the carbon number analysis, used FCC catalyst was the most useful one in this experiments for fuel oil.

Sound Absorption Capability and Anatomical Features of Oak Mushroom Bed Log (버섯폐골목의 흡음성능과 구조적 특징)

  • Kang, Chunwon;Kang, Wook;Jeong, Insoo;Park, Heejun;Jun, Sunsik
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.1
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    • pp.54-60
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    • 2008
  • Sound absorption coefficients of oak (Quercus mongolica) wood and oak mushroom bed log were measured by the two microphone transfer function method and anatomical features of oak mushroom bed log examined by stereo scope and SEM observations. The sound absorption coefficients of oak mushroom bed log seemed to be higher than those of normal oak wood specimen over all estimated frequency range. Especially, in the frequency range of 2 to 6 kHz, they were about 2~3 times higher than those of normal wood specimen. Due to fungi degradation, the specific gravity of oak mushroom bed log decreased about 70% than that of normal wood. For oak mushroom bed log, abundant pores occurred on the radial, tangential and cross sectional surface and it was considered that the pores behaved as a sound absorbing pore.

Friction Characteristics of Geogrid -Light Weight Soil Mixed with Small Pieces of Waste EPS (지오그리드-폐 EPS조각 혼합경량토의 마찰특성)

  • 김홍택;방윤경
    • Geotechnical Engineering
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    • v.12 no.6
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    • pp.163-184
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    • 1996
  • In this study, physical and geotechnical properties of the light weight mixed soil( weathered granite soil mixed with small pieces of waste EPS) were analyzed by laboratory experiments to examine its suitability for backfill materials of the reinforced-earth walls. Friction characteristics of geogrid-light weight sized soil were also investigated by performing the pullout tests for two types of geogrids having different flexural rigidity. Also a procedure was proposed to evaluate friction strength between geogrid and light weight miffed soil by using a stress-strain relationship of the orthotropic composite material subjected to both longitudinal and vertical loadings. By the procedure proposed in this study, values of the calibration coefficients ul and uf applicable for the evaluation of friction strengths between two types of geogrids and light weight mixed soils were further presented.

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An Experimental Study to Determine the Mechanical Properties of Recycled Aggregate Separated from Demolished Concrete and Recycled Aggregate Concrete (폐 콘크리트에서 분리된 재생골재와 재생콘크리트의 공학적 특성규명을 위한 실험적 연구)

  • 전쌍순;이효민;황진연;진치섭;박현재
    • The Journal of Engineering Geology
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    • v.13 no.3
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    • pp.345-358
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    • 2003
  • Recently, the reuse of coarse aggregate derived from demolished concrete was introduced into practice with two environmental aspects: protection of natural sources of aggregate and recycling of construction waste. However, recycled aggregate has been used for the very limited application such as subbase material for pavement and constructional filling material because it was considered as low quality constructional materials. In the present study, in order to examine the possibility that recycled aggregate can be used for concrete mixing, we conducted various experimental tests to identify mineralogical, chemical and mechanical properties of recycled aggregate and to determine the workability and mechanical properties of recycled aggregate concrete (RAC). The cement paste and mortar contained in recycled aggregate significantly affect the basic mechanical properties of aggregate and the workability and mechanical properties of RAC. However, RCA mixed with the proper replacement ratio of recycled aggregate shows the comparable compressive strength and freeze and thaw resistance to those of normal concrete. Therefore, it is considered that recycled aggregate can be widely used for concrete if the cement paste and mortar can be efficiently removed from recycled aggregate and/or if the effective replacement ratios of recycled aggregate are applied for mixing concrete.

Multi-Shape Retrieval Using Multi Curvature-Scale Space Descriptor (다중 곡률-단계 공간 기술자를 이용한 다중형상 검색)

  • Park, Sang Hyun;Lee, Soo-Chahn;Yun, Il-Dong
    • Journal of Broadcast Engineering
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    • v.13 no.6
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    • pp.962-965
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    • 2008
  • 2-D shape descriptors, which are vectors representing characteristics of shapes, enable comparison and classification of shapes and are mainly applied to image and 3-D model retrieval. Existing descriptors have limitations that they only describe shapes of single closed contours or lack in precision, making it difficult to be applied to shapes with multiple contours. Therefore, in this paper, we propose a new shape descriptor called Multi-Curvature-Scale Space that can be applied to shapes with multiple contours. Specifically, we represent the topology of the sub-contours in the multi-contour along with Curvature-Scale Space descriptors to represent the shapes of each sub-contours. Also, by allowing the weight of each component to be controlled when computing the distance between descriptors the weight, we deal with ambiguities in measuring similarity between shapes. Results of various experiments that prove the effectiveness of proposed descriptor are presented.

Stability Assessment of Abandoned Gangway for Commercial Utilization of Services (서비스업 활용을 위한 광산 폐갱도의 안정성 평가)

  • SunWoo, Choon;Chung, So-Keul;Lee, Yun-Su;Kang, Sang-Soo;Kang, Jung-Seok
    • Tunnel and Underground Space
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    • v.22 no.5
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    • pp.297-309
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    • 2012
  • The stability assessment of abandoned gangway for the purpose of services was performed. Among the many factors that affect the stability of openings, the span of the opening in a given rock mass condition provides an important element of design. In this paper, the stability of gangway was assessed by the critical span curves proposed by Lang, the modified Mathews'stability graph method and using support measures of the Q system. In the evaluation of stability as a whole the gangway is considered as stable. But the rockfalls of wedge-shaped blocks were expected in the area in which the horizontal joints of low angle appear. The support measures such as local rock bolts are required to use for commercial purposes of the abandoned gangway. And entrance section may require the particular attention as unstable section. Since there are so many spalling due to bad blasting in the roof and sidewall of gangway, the scaling operations should be followed primarily.

Synthesis of Zeolite Using Discharged Fly Ash in an Industrial Complex in Ulsan (울산지역 공단에서 발생되는 비산재를 이용한 제올라이트 합성)

  • Lee, Chang-Han;Park, Jong-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.5
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    • pp.301-306
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    • 2011
  • In this study, zeolite was synthesized by hydrothermal, fusion, and fusion/hydrothermal methods with fly ash, coal fly ash, and a waste catalyst discharged from thermal power plants and incinerator in Ulsan area. Coal fly ashes (CFAs) and a waste catalyst containing amounts of $SiO_2$ and $Al_2O_3$ ranging from 60.29 to 89.62 wt%. CFAs were mainly composed of quartz and mullite which were assayed by a XRD pattern. Zeolite could be synthesized by CFAs and the waste catalyst when all methods were used. Na-A zeolite (Z-C1, Z-C2, and Z-W5) are mainly synthesized by the fusion method from CFAs and the waste catalyst. Z-C1 and Z-C2 formed by-products, calcite peaks, which is caused by the content of CaO in CFAs and the addition of $Na_2CO_3$ for a synthetic process.

Stability Analysis and Design of Slope Reinforcing Method Using Anchored or Waste Tyre Wall (앵커 또는 폐타이어 벽체를 이용한 사면보강공법의 안정해석 및 설계)

  • 김홍택;강인규
    • Geotechnical Engineering
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    • v.10 no.2
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    • pp.69-84
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    • 1994
  • In the present study, the application of a method of anchored or waste tyre wall in reinforcing the unstable slope is investigated. For design purposes a method of external stability analysis of the reinforced slope, together with a method of internal stability analysis of a wall itself, is presented. In order to predict the passive resistance expected in the anchor or waste tyre Meyerhof's bearing capacity theory is moapaed and experimental results of stress distribution of a pile section under lateral loading is used. Hurray's pull-out teat results are compared with the passive resistances of anchors predicted by the proposed method, and alto the advantages in design are compared with a method of reinforced earth wall with steel strips. Finally a design example of reinforced slope using anchored or caste tyre wall is presented and the overall stability is analyzed in detail by the proposed method of analysis. The efficiency of a method of anchored or waste tyre wall is further analyzed, comparing with a method of changing geometry of the origin리 unstable slope.

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Leaching Characteristics of Foundry Sands When Used as Reactive Media in Permeable Reactive Barriers (반응벽체에 쓰인 주물사의 용출특성에 관한 연구)

  • ;Benson, Craig H
    • Journal of the Korean Geotechnical Society
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    • v.18 no.5
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    • pp.179-193
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    • 2002
  • Waste foundry sands were tested to determine their leaching characteristics when used as reactive media in permeable reactive barriers (PRBs). Water leach tests and column leach tests were performed on twelve foundry sands and three reference materials such as Peerless iron, a local fill material, and torpedo sand. The latter three materials were tested to compare concentrations of heavy metals and anions found in other materials commonly placed below the groundwater table with those from the foundry sands. Results of water leach tests md total elemental analyses showed that all of the laundry sands are Category 2 materials per Section NR 538 of the Wisconsin Administrator Code. However, tests on Peerless iron, torpedo sand, and a typical fill material indicate that these materials, which are commonly placed below the groundwater table, also are Category 2 materials. Thus, using foundry sand as a PR3 medium should pose no greater risk than that imposed using conventional construction materials.