• Title/Summary/Keyword: 공해물질

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The Product properties of Bituminous Coal in Two-Stage Pyrolysis (유연탄의 이단 열분해에 따른 생성물의 특성)

  • 송광섭;이상남;윤형기;김상돈
    • Journal of Energy Engineering
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    • v.2 no.2
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    • pp.208-214
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    • 1993
  • Pyrolysis of bituminous coal has been carried out in a two-stage fixed bed reactor to produce high heating value gas(7000 kcal/N㎥) for industrial or town gas usage. The effects of coke catalyst, pyrolysis temperature (468∼565$^{\circ}C$), and catalytic cracking temperature (700∼850$^{\circ}C$) on the product gas properties from pyrolysis of bituminous coal have been determined. From pyrolysis of Dong Jin coal with coke, the carbon deposition on catalyst is found to be less than 5% of product tar and approximately 15% of total energy iii the parent coal can be recovered as high heating value gas. Oil composition in the product tar from the two-stage pyrolysis is higher than that from low-temperature pyrolysis. The tar produced from pyrolysis below 516$^{\circ}C$ can be easily catalytically cracked but, the tar produced above 565$^{\circ}C$ cannot be cracked easily with catalyst. From the product gas analysis, the catalytic cracking temperature should be maintained below 800$^{\circ}C$ since cracking speed of ethylene increases remarkably with the cracking temperature above 800$^{\circ}C$.

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Dose-Response Relationship of Micronucleus Frequency in Pollen Mother Cells of Tradescantia (자주달개비 화분모세포 미세핵 생성률의 방사선량-반응 관계)

  • Kim, Jin-Kyu;Song, Hi-Sup;Hyun, Soung-Hee
    • Journal of Radiation Protection and Research
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    • v.24 no.4
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    • pp.225-230
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    • 1999
  • This study was carried out to investigate the radiation dose-response of micronucleus frequencies in Tradescantia pollen mother cells. The number of micronuclei increased in the tetrads as a result of chromosome deletion after irradiation. The maximal frequency of micronuclei showed a good dose-response relationship in the range of dose $0{\sim}50$ cGy. On the basis of the relationship, a dose of 1 cGy results maximally in two additional micronuclei in 100 tetrads. The radiation dose-response relationship of micronucleus occurrence is prerequisite to biological monitoring of radiations. The micronucleus assay can be applied to biological risk assessment of environmental toxicants, and to integrity test of water or soils of interest.

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Numerical Study on Auto-ignition and Combustion Emissions Using Gasoline/Ethanol Surrogates (휘발유/에탄올 혼합연료의 자연발화 및 연소배기가스 특성에 관한 수치적 연구)

  • Lee, Eui Ju
    • Fire Science and Engineering
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    • v.30 no.3
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    • pp.1-6
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    • 2016
  • More than five thousands transportation fires occurannually in Korea and the resulting destruction of property and loss of life is huge and results in traffic and environmental pollution. The recent development of automobile technology such as the hybrid concept and use of bio fuels makes fire protection even more difficult due to a lack of understanding of the new adapted system including vehicle engines. In this study, a numerical simulation was performed on a PSR (perfectly Stirred Reactor) to simulate an automobile engine and to clarify the effect of gasoline/ethanol surrogates as a fuel. The temperature, NOx and soot emissions were predicted to decrease with increasing ethanol content, but that of unburned hydrocarbons was found to increase dramatically. The result will provide not only the basic thermal characteristics for engines and their after-treatment systems, but also make it possible to assess the potential for fire events in these systems when an ethanol mixed fuel is used in gasoline vehicles.

A Parametric Study on the Catalytic Combustion of Gaseous Methane, Ethane and Propane Fuels (메탄, 에탄 및 프로판 가스 연료의 촉매연소에 관한 매개변수 연구)

  • Jung, Min-Seung;Kim, Chong-Min;Kim, Man-Young
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.4
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    • pp.309-315
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    • 2012
  • Catalytic combustion is generally accepted as one of the environmentally preferred alternatives for heat and power from fossil fuels, as it has the advantage of stable combustion under very lean conditions with such low emissions as UHC, CO, and NOx. In this work, therefore, comparative numerical studies on the catalytic combustion behaviors over Pd-based catalysts have been conducted with the gaseous $CH_4$, $C_2H_6$, and $C_3H_8$. In the following, after introducing the governing equations with 1D channel and Langmuir-Hinshelwood models, numerical investigations on the catalyst performance are conducted by changing such various parameters as inlet temperature, excess air ratio, and space velocity. The numerical results show that outlet temperature and conversion of $C_3H_8$ are highest among others because of its chemical structure and reactivity.

Development of New Techniques of Electrostatic Separation for Using of Clean Coal (청정석탄(淸淨石炭) 이용(利用)을 위한 정전선별(靜電選別) 기술개발(技術開發))

  • Baek, Sang-Ho;Jeon, Ho-Seok;Han, Oh-Hyung
    • Resources Recycling
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    • v.14 no.5 s.67
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    • pp.54-61
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    • 2005
  • In 2006, the coal usage that is used as energy source of power plant will meet 16,000 MW which is 30% of the whole energy usage. A Coal deposits among the fossil fuels is very plentiful in natural resources and has high economical efficiency but application technique is very inconvenient. Also when burned for utilization, it generate various toxic and untoxic air pollution materials; fly ash, bottom ash, sulfurous acid gas etc. In this study, we could establish a preparation of clean coal by triboelectrostatic separation. In this study, we made a bench-scale's triboelectrostatic separation equipment using electrostatic technology, and got an optimum conditions of various factors for increasing recovery rate and purification in separation. A test result, we got a clean coal that recovery rate is 68.10%, rejection rate of ash and sulfur content is 31.23% and 28.33%.

A Numerical Study Of Flow Control Valve to Flow Characteristics by Pressure Difference for Hydrogen Station (수소충전소용 유량제어 밸브의 차압에 따른 유동특성에 대한 수치해석적 연구)

  • Nam, Chung-Woo;Kim, Rak-Min;Kim, Hyun-Hyo
    • Journal of the Korean Institute of Gas
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    • v.25 no.2
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    • pp.28-33
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    • 2021
  • With the recent growing interest in eco-friendly cars, as interest in eco-friendly cars increases, interest and purchase of hydrogen fuel cell vehicles that do not emit pollutants are increasing. Recently, the government is supporting the expansion of hydrogen charging station and localization of core parts according to the government's hydrogen energy dissemination policy. In this study, the flow characteristics of the hydrogen flow control valve were investigated. As the differential pressure increases, the mass flow rate and flow coefficient tend to be different from the volume flow rate. And it was confirmed that it affects the hydrogen temperature due to the nozzle effect in the bottleneck section, and the change in density affects the mass flow rate.

Study for Zero Emission Vehicle Technology : Current Status and Recent Trends (무공해 자동차 기술의 현 상태와 발전방향)

  • Lee, Sunguk;Park, Byungjoo
    • The Journal of the Convergence on Culture Technology
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    • v.5 no.1
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    • pp.377-384
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    • 2019
  • To cope with severe global warming and environmental pollution problem regulations on automobile emissions and fuel efficiency has been tightened around the world. Therefore zero emission vehicles which do not use fossil fuels such as electric vehicles have attracted attention by government and both industry and academia at developed countries. In the market, electric vehicles are being selected from more and more consumers because of technological advances and policy support. Recently another zero emission vehicle, hydrogen fuel cell vehicle, is drawing attention and is expected to become deployed widely. This paper reviews technology, current status and global trends of zero emission vehicle. The economical analysis of zero emission vehicles are also presented.

Molecular Dynamics Study of Anion Conducting Ionomer under Excessive Water Condition (과량의 수화상태에서 음이온 전도성 이오노머의 분자동역학 전산모사 연구)

  • Hoseong, Kang;So Young, Lee;Hyoung-Juhn, Kim;Chang Hyun, Lee;Chi Hoon, Park
    • Membrane Journal
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    • v.32 no.6
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    • pp.475-485
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    • 2022
  • The continuous excessive consumption of fossil fuels is causing global warming, climate, and environmental crisis. Accordingly, hydrogen energy attracts attention among alternative energies of fossil fuels, because it has the advantage of not emitting pollutants and not having resource restrictions. Therefore, various studies are being conducted on a water electrolysis system for producing hydrogen and a fuel cell system for producing electricity by using hydrogen energy as a fuel. In this study, 3D ionomer models were produced by reflecting the excessive water condition of an anion-conductive ionomer material, which is one of the core materials of water electrolysis systems and fuel cells. Finally, by analyzing the structural stability and performance of the ionomer under an excessively hydrated condition, we suggested a performance improvement factor in the design of an anion conductive ionomer, a key material for water electrolysis systems and fuel cells.

Experimental studies of 1.0T/D Entrained Flow Coal Gasifier (1.0T/D 가압 분류층 석탄 가스화기 운전 특성)

  • Ra, Howon;Hong, Jaichang;Choi, Youngchan
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.115.1-115.1
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    • 2010
  • 석탄 가스화기술은 기존의 연소 방식에서 발생하는 공해 물질은 줄이면서 발생되어지는 합성가스를 이용하여 직접 사용하거나, IGCC나 CTL 공정등에서 원료로서 사용할 수 있다는 장점을 가지고 있어 석탄의 환경친화적인 이용을 위하여 오래전에 개발된 기술임에도 불구하고 최근 각광받고 있는 기술이다. 분류층 가스화기는 미분화된 석탄을 고온에서 가스화하는 방식으로 용량의 대형화가 가능하여 석탄가스화복합발전(IGCC)용으로 이용되고 있다. 석탄슬러리를 원료로 사용하는 습식 분류층 가스화기는 기술적으로 상당히 안정적이어서 가장 많이 보급되어진 가스화기 형태이다. 본 연구에서는 1.0T/D급 습식 분류상 가스화 장치의 가압 운전 특성 및 가스화 특성, 운전 조건을 파악하기 위하여 실험을 실시하였다. 실험에 사용된 반응기는 운전 압력 30bar로 설계되었으며, Fuel의 공급량은 50~70kg/hr로 공급하였으며, $O_2$/fuel Ratio를 0.7~1.1까지 변경하여 Fuel 주입량에 따른 내부온도 분포와 $O_2$/Fuel 비율에 따른 합성가스의 조성, 탄소 전환율, 냉가스효율 변화 특성을 알아보았다.

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Behavior analysis using pressure fluctuations in a pressurized fluidized bed (가압유동층에서 압력변동을 이용한 거동해석)

  • Kang, Suk-Hwan;Han, Keun-Hee;Yi, Chang-Keun;Jin, Gyoung-Tae;Son, Jae-Ek;Kang. Yung
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2002.05a
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    • pp.179-183
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    • 2002
  • 가압유동층은 복합발전이 가능하며, 총괄열효율이 높을 뿐만 아니라 가압에 의한 장치의 소형화 및 탈황효율의 증대 그리고 배가스 중의 NOx 농도를 줄일 수 있기 때문에 공해 배출 물질의 감소 등 상압유동층 연소에 비하여 많은 장점들을 가지고 있어 선진 국가들에서도 이미 상당한 진전을 보이고 있으며, 중국이나 일본에서도 차세대 연소기술로 이에 대한 연구가 활발히 진행되고 있다.(중략)

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