• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.33 no.8
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• pp.18-25
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• 2005

This paper describes a supersonic separation of air-launching rocket from the mother plane. Three dimensional Euler equations were numerically solved to analyze steady/unsteady state fluid flows. The results of simulation clearly demonstrate effect of shock-expansion wave interaction between the rocket and the mother plane. Moreover, important influential factors at separating stage of the rocket were extracted with a comprehensive analysis. Finally, from the consideration of supersonic-separation, a guideline to safety-separation is given to the design of supersonic air-launching rocket.

• Applied Chemistry for Engineering
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• v.7 no.4
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• pp.757-767
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• 1996

Poly(alkyl acrylate-g-caprolactone) graft copolymers were prepared, and they were applied as compatibilizing agents for polycarbonate (PC) / poly(acrylonitrile-butadiene-styrene) (ABS) blends. The incompatible poly(alkyl acrylate) segment was incorporated into the graft copolymer in order to localize the copolymer at the PC/ABS interface. The blend containing 1 phr of the copolymer showed remarkable improvement in impact strength as well as in elongation at break. Impact improvement was more pronounced with a thinner test specimens of 1/8 inch thickness. Morphological study showed that the presence of the graft copolymer led to a smoother PC/ABS interface due to the interfacial enrichment of the graft copolymer.

• Applied Chemistry for Engineering
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• v.5 no.4
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• pp.624-629
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• 1994

Chitosan-g-poly(4-vinyl pyridine)membranes were prepared by crosslinking reaction using glutaraldehyde and glucose oxidase immobilized chitosan/acrylamide composite membranes were fabricated by chitosan-g-poly(4-vinyl-pyridine) copolymer and acrylamine. Water content and permeability of insulin through chitosan-g-poly(4-vinyl pyridine )membranes increased with decreasing the pH of the medium. Permeability of insulin through chitosan/acrylamide composite membranes increased with increasing the concentration of glucose.

• Applied Chemistry for Engineering
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• v.4 no.1
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• pp.188-195
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• 1993

Polyelectrolyte complexes and graft copolymers as biomaterials were synthesized from the water soluble cellulose derivatives. Polyelectrolyte complexes have been prepared from carboxymethyl cellulose (CMC) and gelatin. Graft copolymers(Mc-g-AA) were synthesized by grafting acrylic acid (AA) onto methyl cellulose(MC). (Mc-g-AA) and gelatin polyelectrolyte complexes were also prepared. The optimum conditions of each sample were investigated after chemical crosslinking or heat treatment. The preliminary results show that these materials might be interesting for biomedical applications.

• Polymer(Korea)
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• v.26 no.4
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• pp.543-550
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• 2002

We have synthesized a novel carrier transporting copolymer having triphenylamine moiety as a hole transporting unit and triazine moiety as an electron transporting unit in the polymer side chain. Single-layered organic electroluminescent (EL) devices consisted of ITO/copolymer and emitting materials (DCM, coumarin 6, DPvBi)/Al exhibited maximum external quantum efficiency when the ratio of hole transporting unit and electron transporting unit is 6:4 and the content of emitting material is 30 wt%. Especially, the devices emitted the light of red (620 nm), green (520 nm) and blue (450 nm) corresponding to the emitting materials, respectively. A maximum luminance of ITO/copolymer (6:4) and DCM (30 wt%)/Al EL device was about 500 cd/$m^2$ at a DC drive voltage of 12V.

• Journal of the Korean Chemical Society
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• v.39 no.1
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• pp.76-80
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• 1995

Polydimethylsiloxane(PDMS)-co-poly(2-hydroxyethyl methacrylate)(PHEMA) was prepared and the degree of swelling of solvents into the polymers was examined. It was confirmed that the solubility parameter of PHEMA homopolymer is 26 (J/cm3)1/2. Ethanol was significantly absorbed into copolymers containing large amount of PHEMA, while tetrahydrofuran was effectively absorbed into copolymers containing large amount of PDMS. Absorption of polar solvents into the copolymers were increased with the increase of PDMS content. The model drug, crystal violet (CV), was more absorbable into PDMS-HPEMA copolymers than PHEMA homopolymer. Absorption of CV was decreased with the increase of PDMS content of the copolymers.

• Polymer(Korea)
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• v.33 no.3
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• pp.230-236
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• 2009

Water soluble vinyl acetate/alkyl methacrylate copolymers were prepared by the emulsion copolymerization of vinyl acetate and various methacrylates such as methyl methacrylate (MMA) and ethyl methacrylate (EMA). Potassium persulfate (KPS) and ammonium persulfate (APS) were used as an initiator. Poly (vinyl alcohol) (PVA) was used as a protective colloid. The drying characteristics of the prepared poly(vinyl acetate-co-methyl methacrylate) (PVAc/PMMA), poly(vinyl acetate-co-ethyl methacrylate) (PVAc/PEMA) were studied using moisture meter at the temperature between 100 and $200^{\circ}C$. The significant results are described as follows. The activation energy of the isothermal drying process of the copolymers has the order of PVAc/PMMA> PVAc/PEMA> PVAc.

• Journal of the Korean Chemical Society
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• v.20 no.5
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• pp.424-430
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• 1976

Isocyanate-terminated SBR-prepolymers were prepared from SBR-diol and excess toluene diisocyanate. These prepolymers were then used as initiators for the sodium-catalyzed polymerization of ${\varepsilon}$-caprolactam. The resulting block copolymers, presumably the structure of nylon 6-SBR-nylon 6, were confirmed from their IR spectra. The viscosities of these polymers were measured in phenol/tetrachloroethane and the molecular weights were estimated. The polymerization reaction was not affected by the change in concentration of catalyst, but significantly faster at $185^{\circ}C$ than at $150^{\circ}C$. And the initiator concentration of 0.5 mole % gave good results.

• Proceedings of the Korean Association of Geographic Inforamtion Studies Conference
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• 2008.06a
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• pp.322-324
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• 2008

재난재해 등 긴급 상황이 발생했을 때 신속한 대응 체계 수립을 위해 비 접근 및 난접근 지대, 목표물 감시대상지역에 대한 공간정보를 신속하게 취득할 수 있는 실시간 공중모니터링 체계의 구축이 시급한 실정이다. 이에 본 연구에서는 긴급한 재난 상황과 혹은 이와 유사한 여러 상황에 신속하고 유연하게 운용될 수 있는 무인헬기 기반의 실시간 공중 모니터링 체계에 적용할 멀티 센서 시스템의 설계를 목표로 한다. 이를 위해 먼저 실시간 공중모니터링 임무 및 운용 시나리오를 크게 4가지로 설정하고 이에 적합한 디지털 카메라, 레이저 스캐너, GPS/IMU 및 무인헬기 플랫폼의 요구사항을 각각 도출하였다. 또한, 기술 동향 및 규격 조사결과를 바탕으로 도출된 요구사항에 가장 적합한 각각의 센서 및 플랫폼을 선정하였다. 마지막으로 시스템 설계의 최적화를 위하여 시뮬레이션을 통해 설정된 임무에 부합하는 품질의 공간정보 성과물이 선정된 멀티센서 시스템으로부터 취득 가능한가를 검증하였다. 본 연구를 통해 소형무인헬기기반의 멀티 센서시스템에 대한 최적 설계의 방법론을 정립할 수 있었고, 향후 설계의 결과는 임무로부터 도출된 요구사항에 최적화된 맞춤형 시스템 구축에 적용들 예정이다.

• Elastomers and Composites
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• v.48 no.1
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• pp.85-91
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• 2013

In this study, we synthesized a terpolymer consisting of ethylene, 1-hexene, and styrenic monomer using a metallocene catalyst and cocatalyst ststem. The styrenic monomers empolyed as the third monomer were styrene, p-methylstyrene, and 4-tert-butylstyrene. The structure and composition of the terpolymers were characterized using $^{13}C$ NMR and $^1H$ NMR. Catalytic activity, polymer yield, molecular weight and molecular weight distribution of the terpolymers were analyzed. We also determined the glass transition temperature(Tg), crystallinity and thermal properties of the terpolymers by DMA, WAXS and TGA.