• Title/Summary/Keyword: 공중

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Study on Ground Water Drop Pattern and Coverage Level by Helicopter (헬기에 의한 지상 물투하 형태 및 범위 실험)

  • Bae, Taek-Hoon;Lee, Si-Young;Son, Jung-Hun
    • Fire Science and Engineering
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    • v.27 no.2
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    • pp.54-61
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    • 2013
  • Aerial fire fighting is more effective on forest fire suppression than ground fire fighting. So, Aerial fire fighting is important to prevent large fire. United States suppression the joint fixed-wing and rotorcraft (Helicopter) but Helicopter only in Korea. At this point, we need to research about ground water drop pattern and coverage level for aerial fire fighting effectiveness by helicopter. In this study, we experimented water-dropping S-64E, Ka-32T, AS-350B2 of three of helicopter to operate the Forest Service and suggested efficient ground water drop pattern and coverage level. Using these study results, recognition of pilots who suppression more efficient aerial fire fighting at the scene of Forest fire.

Effect of Polymerization Condition on Atom Transfer Radical Copolymerization Behaviors of Styrene with Methyl Acrylate (스티렌과 메틸아크릴레이트의 원자 이동 라디칼 공중합에서 중합조건에 따른 중합 특성 연구)

  • Song, Seon-Ja;Ko, Young Soo
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.676-680
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    • 2011
  • Investigated was the effect of the crucial polymerization conditions such as methyl acrylate(MA) mole fraction in feed, polymerization temperature and time on Atom Radical Transfer Polymerization(ATRP) behavior of styrene and methyl acrylate(MA). As MA mole fraction in feed increased, molecular weight(MW) of the resulting copolymer increased. At polymerization time of 3 hrs the composition of MA in the resulting copolymer was shown to have a linear relationship with the mole fraction of MA in feed. MW was increased and the composition of MA in copolymer was decreased as the polymerization time increased, showing the characteristics of ATRP. MW was also increased as polymerization temperature increased, and the composition of MA in copolymer was shown to be increased drastically at polymerization temperature of $110^{\circ}C$.

Synthesis of ion Exchange Fiber Containing Amidoxime and Phosphoric Acid Groups and Its Uranium Adsorption Properties (아미드옥심기와 인산기가 함유된 이온 교환 섬유의 합성 및 우라늄 흡착 특성)

  • 황택성;박진원
    • Polymer(Korea)
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    • v.27 no.3
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    • pp.242-248
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    • 2003
  • PP-g-(AN/Sty) was synthesized by grafting with acrylonitrile (AN) and styrene (Sty) onto PP staple fiber using an electron beam accelerator and followed by amidoximination and phosphorylation. Mole fraction of AN in the graft chain increased with the increase of the AN content in the monomer mixture. The highest AN grafting yield of 45% was obtained at a monomer ratio of 40 vol% AN/60 vol% Sty. Mole fraction of AN in the graft chain decreased with the increase of methanol amount used its solvent. As reaction temperature increased, the grafting yield of copolymer increased and reached equilibrium at 50$^{\circ}C$. Amount of amidoxime group in fibrous ion exchanger was increased as increasing amount of hydroxylamine, and the maximum content of amidoxime group was observed at 5.8 mmol/g with the 9 wt% hydroxylamine concentration. Content of phosphorous group in fibrous ion exchanger increased up to 0.5 N phosphoric acid concentration, and then leveled off. The adsorption ability of the copolymer for uranyl ion by the chelating adsorbents was in the following order : bifunctional PP-g-(AN/sty) > amidoximated PP-g-(AN/Sty) > phosphorylated PP-g-(AN/Sty).

Poly(4-vinylpyridine)/Vinyl Acetate-Vinyl Alcohol Copolymer Blends : 9. Phase. Behavior (폴리(4-비닐피리딘)/비닐아세테이트-비닐알코올 공중합체 블렌드 :2. 상 거동)

  • Lee, Joon-Youl;Choi, Dong-Hoon;Lee, Hyeok
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.649-656
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    • 2001
  • Miscibility of poly(4-vinylpyridine) (P4VP) blends with poly(vinyl acetate-co-vinyl alcohol) (VAc-VAL copolymers) was investigated as a function of comonomer composition of VAc-VAL copolymers. Differential scanning calorimetry (DSC) and thermo-optical microscopic (TOM) analysis confirmed that P4VP is miscible with VAc-VAL copolymers containing more than 30 mole% VAL. Fourier transform inflated (FT-IR) spectroscopic analysis revealed that the strong intermolecular hydrongen bonding interaction between the vinylpyridine and VAL hydroxyl group was formed. Theoretical phase diagram was constructed by the calculation using the Association model, a thermodynamic model for hydrogen-bonded polymer blend systems developed by Coleman et al. The calculated theoretical binodal phase diagrams were in good agreement with the experimentally determined cloud point curves.

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Sequence Distribution and Thermal Properties of Poly(butylene succinate-co-butylene terephthalate) Copolyesters (Poly(butylene succinate-co-butylene terephthalate) 공중합물의 미세구조와 열적 성질)

  • Park, Sang Soon;Jeong, Jae Ho;Kim, Tae Jeong;Kim, Dae Jin;Im, Seung Soon
    • Journal of the Korean Chemical Society
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    • v.40 no.1
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    • pp.87-95
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    • 1996
  • The binary random copolyesters of poly(butylene succinate-co-butylene terephthalate) (PBS/PBT) were synthesized and their sequence distributions were investigated over the entire range for PBS/PBT copolyester compositions by 1H NMR spectroscopy. The melting point (Tm) of these copolyesters were depressed gradually with the increase of dimethyl terephthalate (DMT) mol% in composition and appeared an eutetic behaviour which appears a minimum at ST3 (DMT 65.8 mol%). The melting behaviour of PBS/PBT copolyester was not directly depended on molar fraction (Xa) but on only the sequence propagation probability (P) which occurs in triad fraction. It also can be seen that when the succinate units (or terephthalate units) were abundant enough, PBS/PBT Copolymers formed only PBS (or PBT) crystal with complete rejection of the terephthalate units (or succinate units).

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The Effects of Media Framing and Image Restoration Strategies on the Public's Crisis Perceptions (언론 프레이밍과 이미지 회복 전략이 공중의 위기 인식에 미치는 영향)

  • Park, Eun-Hae;Kim, Yung-Wook
    • Korean journal of communication and information
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    • v.38
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    • pp.73-118
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    • 2007
  • The purpose of this research is to figure out the effects of media framing and image restoration strategies on the public's crisis perceptions. The literature review revealed that the public perceives crises through the media lens and image restoration strategies heralded by the organization interact with media frames in the process of the public's perceiving the crisis. The news content analysis and the experiment were conducted to accomplish the research purpose. Also food-related crises were selected for a research case because they have a great impact on the society. The content analysis showed that image restoration strategies designed by the crisis organization tend to be conveyed through anecdote-type news frames. Most image restoration strategies were close to defensive communications and not differentiated by the crisis type. The experiment outcomes demonstrated that the organization's image restoration strategies were not consistent with what the public preferred in the crisis situation. Such public perceptions also were changed according to media frames. Media frames and image restoration strategies have an interaction effect on the public's crisis perception.

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Changes of Characteristic of Terpolymers according to the Chain Length of Incorporated High α-olefins (도입된 High α-olefin의 사슬길이 변화에 따른 삼원공중합체 특성 변화)

  • Jeon, Dong Gyu;Kim, Tae Wan;Kim, Jung Soo;Kim, Hyun Ki;Chang, Young Wook;Kim, Dong Hyun
    • Elastomers and Composites
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    • v.48 no.4
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    • pp.269-275
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    • 2013
  • In this study, we prepared poly(ethylene-ter-1-hexene-ter-divinylbenzene) using various metallocene catalysts with trityl tetrakis(pentafluorophenyl)borate/triisobutylaluminium cocatalysts system. We tried rac-$Et(Ind)_2ZrCl_2$, rac-$SiMe_2(Ind)_2ZrCl_2$, and rac-$SiMe_2(2-Me-Ind)_2ZrCl_2$ to choose optimum metallocene catalyst, comparing with catalytic activity, molecular weight, molecular weight distribution of the terpolymers. To study the effects of chain length of high ${\alpha}$-olefins on the terpolymerization, we synthesized the terpolymers using 1-hexene, 1-octene, 1-decene or 1-dodecene. We characterized chemical composition, thermal properties, and mechanical properties of the terpolymers.

Molecular Design and Characterization of Biodegradable Crosslinked Copolyesters (생분해성 가교 공중합에스테르의 분자설계 및 특성 연구)

  • Sung, Yong-Kiel;Han, Seung-Jun
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.108-114
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    • 2001
  • Crosslinked poly(glycerol-co-malate)s were synthesized from L-malic acid in Krebs cycle and glycerol. The synthesized polymer was identified by FT-IR spectroscopy. Swelling degrees of the copolymer hydrogels were increased with an increase in pH of the aqueous solution. Hydrolytic behaviors of the crosslinked copolymers were investigated in various pH buffer solutions at 37${\circ}C$. The Hydrolysis of the copolymers proceeded faster with increasing pH of the aqueous solution. Releasing behaviors of the model drug such as diclofenac monosodium salt were also measured in various pH aqueous solutions at 37${\circ}C$. The release concentration of diclofenac monosodium salt from the hydrogel systems was increased with increasing pH. These facts indicate that the unreacted carboxyl and hydroxyl groups in the copolymers are greatly affected by pH in the conditions.

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System Trade Study of the Air-launching Rocket Using Sequential Optimization Technique (순차적 최적화를 이용한 공중발사 로켓 시스템 대안 분석)

  • Choi, Young-Chang;Lee, Jae-Woo;Byun, Yung-Hwan
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.9
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    • pp.41-47
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    • 2005
  • Conceptual design process is defined for the air-launching rocket by including analysis modules like mission analysis, staging, propulsion analysis, configuration, weight analysis, aerodynamics analysis and trajectory analysis. As a result of the conceptual design, the supersonic(M=1.5) air-launching rocket with hybrid engine for first stage propulsion system is designed. For the best system alternative selection, trade study for the 1st stage engine type and launching speeds using sequential optimization and confirming feasibility of baseline air-launching rocket has been performed. As a result of trade study, all alternatives are competitive in total weight and show only small difference in total weight per unit payload weight. Therefore, it is confirmed that the baseline air-launching rocket which has advantage in system safety especially in supersonic launching is feasible.

Effect of Poly(propylene-co-octene) as a Compatibilizer on Mechanical Properties and Weldline Characteristics of Polypropylene/Poly(ethylene-co-octene) Blends (폴리프로필렌/에틸렌-옥텐 공중합체 블렌드의 기계적 성질 및 웰드라인 물성에 미치는 폴리프로필렌-옥텐 공중합체의 영향에 관한 연구)

  • Koo, Hyo-Seon;Son, Young-Gon
    • Elastomers and Composites
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    • v.46 no.3
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    • pp.251-256
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    • 2011
  • Effect of poly(propylene-co-octene) as a compatibilizer in toughened polypropylene/ poly(ethylene-co-octene) (EOC) was investigated. The EOCs used were metallocene catalyzed commercial linear low density polyethylene and they are elastomeric materials. The poly(propylene-co-octene) was synthesized by metallocene catalyst in our laboratory to be used as a compatibilizer in PP/EOC blends. PP/EOC blends without compatibilizer shows very low mechanical properties in specimens with weldlines while incorporation of a compatibilizer significantly increases the mechanical properties of specimens with weldlines. However, compatibilized PP/EOC blends does not show increased impact property in a weldline free specimen and it is attributed to low molecular weight of the poly(propylene-co-octene) synthesized in present study. It is expected that the poly(propylene-co-octene) having increased molecular weight provides very good performance as an effective compatibilizer in toughened polypropylene/EOC blends.