• Title/Summary/Keyword: 공기층 형성

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Hydrate Phase Equilibria for the Gas Mixtures Containing HFC (수소불화탄소를 포함하는 혼합기체의 가스 하이드레이트 상평형)

  • Seo, Yong-Won;Lee, Seung-Min;Lee, Ju-Dong;Lee, Gang-Woo;Yamasaki, Akihiro;Kiyono, Fumio
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.581-584
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    • 2007
  • (HFC(hydrofluorocarbon, 수소불화탄소)는 오존층 파괴 지수가 낮기 때문에 CFC(chlorofluorocarbon)의 대체 물질로 냉매와 발포제로 널리 사용되고 있는 물질이다. 하지만 HFC는 지구온난화 지수가 높은 기체이므로 대기중으로 방출되는 것을 막기 위해 분리/회수하여 재활용하는 것이 중요하다. 본 연구에서는 공기와 HFC의 혼합기체로부터 HFC만을 분리해 내는 방법으로 가스 하이드레이트 형성법을 제안하였다. 이 방법의 열역학적 타당성을 검증하기 위하여 질소+HFC-134a 혼합기체에 대하여 275-285 K의 온도 범위와 1-27 bar의 압력범위에 걸쳐서 가스 하이드레이트 상평형을 측정하였다. 질소는 가스 하이드레이트를 형성하기 위하여 0 $^{\circ}C$에서 150 bar 이상의 높은 압력이 필요한 반면 HFC-134a는 대기압에 가까운 낮은 압력이 필요하다. 두 기체의 평형 압력의 차가 크다는 것은 가스 하이드레이트 형성법을 이용할 경우 기체의 분리 효율이 매우 높다는 것을 나타낸다. 그리고, 본 실험을 통해서 얻어진 혼합기체의 하이드레이트상(H)-액상($L_W$)-기상(V)의 3상 평형선이 순수한 HFC-134a의 3상 평형선에 가깝게 위치하였다. 이는 가스 하이드레이트를 이용한 분리법이 낮은 압력에서 운전될 수 있음을 나타낸다. 이 분리법은 낮은 압력에서 운전되어 경제적일 뿐만 아니라 물 이외의 다른 매개체를 사용하지 않기 때문에 환경 친화적인 공정이라 할 수 있다.

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An Application of Construction Sequence Analysis for Checking Structural Stability of High-Rise Building under Construction (초고층 건물의 시공 중 구조적 안정성 검토를 위한 시공단계해석의 적용)

  • Eom, Tae-Sung;Kim, Jae-Yo
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.22 no.3
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    • pp.211-221
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    • 2009
  • With recent trends of super-tallness, atypical plan shapes and zoning constructions in high-rise buildings, a structural stability of the building under construction is arising as a key issue for design and construction plan. To ensure the structural stability under construction, the differential column shortening of vertical members, the lateral displacement of tower frames, and differential settlement of raft foundation by unbalanced distributions of a tower self-weight before the completion of a lateral load resisting system should be checked by construction sequence analysis, which should be performed by systematic combinations with structural health monitoring, construction compensation program, and construction panning. This paper presents the scheme of zone-based construction sequence analysis by using the existing commercial analysis program, to check the stability of high-rise building under construction. This scheme is applied to 3-dimensional structural analysis for a real high-rise building under construction. The analysis includes real construction zoning plans and schedules as well as creep and shrinkage effects and time-dependent properties of concrete. The simplified construction sequence and assumed material properties were continuously updated with the change on construction schedule and correlations with in-situ measurement data.

Morphology Controlled Cathode Catalyst Layer with AAO Template in Polymer Electrolyte Membrane Fuel Cells (AAO를 사용한 고분자전해질 연료전지의 공기극 촉매층 구조 제어)

  • Cho, Yoon-Hwan;Cho, Yong-Hun;Jung, Nam-Gee;Ahn, Min-Jeh;Kang, Yun-Sik;Chung, Dong-Young;Lim, Ju-Wan;Sung, Yung-Eun
    • Journal of the Korean Electrochemical Society
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    • v.15 no.2
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    • pp.109-114
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    • 2012
  • The cathode catalyst layer in polymer electrolyte membrane fuel cells (PEMFCs) was fabricated with anodic aluminum oxide (AAO) template and its structure was characterized with scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) analysis. The SEM analysis showed that the catalyst layer was fabricated the Pt nanowire with uniform shape and size. The BET analysis showed that the volume of pores in range of 20-100 nm was enhanced by AAO template. The electrochemical properties with the membrane electrode assembly (MEA) were evaluated by current-voltage polarization measurements and electrochemical impedance spectroscopy. The results showed that the MEA with AAO template reduced the mass transfer resistance and improved the cell performance by approximately 25% through controlling the structure of catalyst layer.

Effect of Aeration Mechanism on Livestock Manure Liquid Fertilization (폭기형태가 돈분뇨 액비 부숙특성에 미치는 영향)

  • Jeong, Kwang-Hwa;Khan, Modabber Ahmed;Kim, Chang-Hyun;Lee, Dong-Hyun;Choi, Dong-Yoon;Yu, Yong-Hee
    • Korean Journal of Organic Agriculture
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    • v.20 no.4
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    • pp.703-713
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    • 2012
  • Three types of aeration system were installed in experimental liquid fertilization tanks to investigate the change of characteristics of pig slurry used as a raw material for making livestock liquid fertilizer. The aeration systems of the reaction tanks were composed of three major part: the air suppling part (blower), the air pipe part, and the air diffuser part. In the first tank (reactor A), the air was supplied from the bottom of the reaction tank through air pipe system connecting air diffuser with commercial ordinary blower. In the second tank (reactor B), the air diffuser was located 10cm above the bottom of the reactor. In the third tank (reactor C), the pure air was supplied with circulating pjg slurry. The oxygen content of pure air was about 90%. The pure air was mixed with pig slurry by mechanically in the air suppling part (blower) and the air pipe part. The agitation effect was highest in the reactor C than other reactors. The contents of SS, COD, T-N and T-P of each samples collected at middle part of all reactors were 8,500, 4,188, 694 and 422mg/L; 9,000, 4,247, 813 and 356mg/L; 8,667, 6,910, 973 and 269mg/L, respectively.

Nanophase Catalyst Layer for Direct Methanol Fuel Cells

  • Chang Hyuk;Kim Jirae
    • Journal of the Korean Electrochemical Society
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    • v.4 no.4
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    • pp.172-175
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    • 2001
  • Nanophase catalyst layer for direct methanol fuel cell has been fabricated by magnetron sputtering method. Catalyst metal targets and carbon were sputtered simultaneously on the Nafion membrane surface at abnormally higher gas (Ar/He mixture) pressure than that of normal thin film processing. They could be coated as a novel structure of catalyst layer containing porous PtRu or Pt and carbon particles both in nanometer range. Membrane electrode assembly made with this layer led to a reduction of the catalyst loading. At the catalyst loading of 1.5mg $PtRu/cm^2$ for anode and 1mg $Pt/cm^2$ for cathode, it could provide $45 mW/cm^2$ in the operation at 2 M methanol, 1 Bar Air at 80"C. It is more than $30\%$ increase of the power density performance at the same level of catalyst loading by conventional method. This was realized due to the ultra fine particle sizes and a large fraction of the atoms lie on the grain boundaries of nanophase catalyst layer and they played an important role of fast catalyst reaction kinetics and more efficient fuel path. Commercialization of direct methanol fuel cell for portable electronic devices is anticipated by the further development of such design.

Real-time Observation of Evolution Dynamics of Ge Nanostructures on Si Surfaces by Photoelectron Emission Microscopy (자외선 광여기 전자현미경을 이용한 Si 표면 위에 Ge 나노구조의 성장 동역학에 관한 실시간 연구)

  • Cho, W.S.;Yang, W.C.;Himmerlich, M.;Nemanich, R.J.
    • Journal of the Korean Vacuum Society
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    • v.16 no.2
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    • pp.145-152
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    • 2007
  • The evolution dynamics of nanoscale Ge islands on both Si (001) and (113) surfaces is explored using ultraviolet photoelectron emission microscopy (UV-PEEM). Real-time monitoring of the in-situ growth of the Ge island structures can allow us to study the variation of the size, the shape and the density of the nanostructures. For Ge depositions greater than ${\sim}4$ monolayer (ML) with a growth rate of ${\sim}0.4\;ML/min$ at temperatures of $450-550^{\circ}C$, we observed island nucleation on both surfaces indicating the transition from strained layer to island structure. During continuous deposition the circular islands grew larger via ripening processes. AFM measurements showed that the islands grown on Si (001) were dome-shaped while the islands on Si (113) were multiple-side faceted with flat tops of (113)-orientation. In contrast, for Ge deposition with a lower growth rate of ${\sim}0.15\;ML/min$ on Si(113), we observed the shape transition from circular into elongated island structures. The elongated islands grew longer along the [$33\bar{2}$] during continuous Ge deposition. The shape evolution of the islands is discussed in terms of strain relaxation and kinetic effects.

A study on the fabrication technology of ceramic interconnect for the SOFC by wet process (습식법을 이용한 고체산화물 연료전지용 세라믹 연결재 제조 특성연구)

  • 이길용;김종희;송락현;백동현;정두환;신동열
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.200-200
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    • 2003
  • 고체산화물 연료전지(SOFC)에서 사용되는 연결재의 주 기능은 각 단위 셀의 연료극과 다음 셀의 공기극을 전기적으로 연결하여, 공기와 사용연료의 분리역할을 하기 위하여 사용된다. SOFC용 연결재는 다른 구성요소 소재보다, 높은 전자 전도성, 낮은 이온전도성, 우수한 기계 적강도가 요구되며, SOFC는 고온에서 작동되기 때문에, 상온에서 작동온도까지 다른 요소 소재들과 유사한 열팽창계수와 물리, 화학적으로 안정성이 요구된다. 현재 연결재 제조기술은 EVD, CVD, plasma spraying, tape casting 등 다양하게 연구되고 있으며, 본 연구는 세라믹 연결재 증착방법 중 저렴한 비용으로 대량 생산이 용이한 습식법(dip coaling)을 적용하여, 연료극 지지체식 flat-tube형 고체산화물 연료전지의 지지체를 위해 세라믹 연결재를 제조하고, 그 특성을 연구하였다. 세라믹 연결재로써 선정한 합성조성은 LaCr $O_3$에 Ca이 치환 고용된 L $a_{0.6}$C $a_{0.41}$Cr $O_3$으로 pechini법으로 합성하였다. 합성된 조성은 100$0^{\circ}C$에서 5시간 하소후 가속 Ball Milling하여 0.5$\mu\textrm{m}$의 평균입자크기를 얻을 수 있었다. XRD 상분석결과 perovskite상 (L $a_{1-x}$ Ca/x/Cr $O_3$)과 CaCr $O_4$를 얻을 수 있었다. slurry를 제조하여 막의 밀착성을 증진시키기 위해 sand blasting시킨 flat tube지지체에 진공펌프를 이용하여 소재내부와 외부의 압력차로 dip coating한 후, 140$0^{\circ}C$로 소결 하였다. coating 결과 박리현상은 없었으나, 표면과 단면의 SEM분석결과 다소 porous한 박막층이 형성되었으며, Ca이온이 지지체로 permeation되는 현상이 발생하였다. 이와 같은 결과로부터 보다 치밀한 박막생성을 위해, slurry 제조조건을 변화시켰으며, Ca이온의 migration을 막기 위해 barrier layer를 이용하였다 완전 소결된 지지체는 가스투과도와 전기전도도측정을 통하여 특성을 평가하였다.였다.다.

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Development and Commercialization of Warm Covers Using Natural Fabric (천연 소재를 이용한 보온덮개 개발 및 사업화 방안)

  • Choi, Ju-Hyun;Beak, Hyun-Kuk;Cho, Yun-Jin
    • Journal of Convergence for Information Technology
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    • v.8 no.1
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    • pp.227-233
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    • 2018
  • The purpose of this study was to develop a warm cover for greenhouse with excellent thermal insulation and to propose ways of commercialization of the product. Feathers were used as filling materials because they formed the air layer to enhance insulation. Instead of downs for clothing or other textile products, we used disposed feathers. The developed product covers the outside of the greenhouse to keep the crops warm. It has multiple layers including feathers as filling materials, padding, inside fabric, heat insulation materials and outer fabric. It has proven to improve the insulation ratio. We developed other kinds of warm covers that are applicable to the inside of the greenhouse or the small houses in the greenhouse. Also, R&D system of educational industrial complex enables us to commercialize the products and building marketing strategies for them. This technology contributes to the expansion of energy-saving facilities for farmers, and it can serve the development and spread of various products utilizing feather.

A Study of Scattered Radiation Effect on Digital Radiography Imaging System (디지털 방사선영상 시스템에서 산란선이 영상 품질에 미치는 영향)

  • Baek, Cheol-Ha
    • Journal of radiological science and technology
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    • v.40 no.1
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    • pp.71-78
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    • 2017
  • Scattered radiation is inherent phenomenon of x-ray, which occurs to the subject (or patient). Therefore it cannot be avoidable but also interacts as serious noise factor because the only meaningful information on x-ray radiography is primary x-ray photons. The purpose of this study was to quantify scattered radiation for various shooting parameters and to verify the effect of anti-scatter grid. We employed beam stopper method to characterize scatter to primary ratio. To evaluate effect on the projection images calculated contrast to noise ratio of given shooting parameters. From the experiments, we identified the scattered radiation increases in thicker patient and smaller air gap. Moreover, scattered radiation degraded contrast to noise ratio of the projection images. We find out that the anti-scatter grid rejected scattered radiation effectively, however there were not fewer than 100% of scatter to primary ratio in some shooting parameters. The results demonstrate that the scattered radiation was serious problem of medical x-ray system, we confirmed that the scattered radiation was not considerable factor of dig ital radiog raphy.

A Study on Analysis of Electrostatics Destruction of Electronic Equipment (전자부품의 정전파괴(ESD) 분석에 관한 연구)

  • Lee, Du-Young
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.10 no.6
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    • pp.235-241
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    • 2010
  • The static electricity generated by friction of two objects is called frictional electricity. The main cause of troubles in electronic components for military and civil use as well as in military radar appliances is found mostly in parts like LSI memories, particularly when they lose information of function momentarily while in operation, which usually leads to a fatal cause of troubles in the equipment. Troubles occur if electric noise is caused by the spark effected from discharge of static electricity from the equipment that is used nearby.