• Journal of the Korean Electrochemical Society
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• v.8 no.2
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• pp.88-93
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• 2005

Anode-supported solid oxide fuel cell (SOFC) was investigated to increase the cell power density at intermediate temperature through control of the cathode structure. The anode-supported SOFC cell were fabricated by wet process, in which the electrolyte of $8mol\%\;Y_2O_3-stabilized\;ZrO_2 (YSZ)$ was coated on the surface of anode support of Ni/YSA and then the cathode was coated. The cathode has two- or three- layered structure composed of $(La_{0.85}Sr_{0.15})_{0.9}MnO_{3-x}(LSM),\;LSM/YS$ composite (LY), and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3{LSCF)$ with different thickness. Their single cells with different cathode structures were characterized by measuring the cell performance and ac impedance in the temperature range of 600 to $800^{\circ}C$ in humidified hydrogen with $3\%$ water and air. The cell with $LY\;9{\mu}m/LSM\;9{\mu}m/LSCF\;17{\mu}m$ showed best performance of $590mW/cm^2$, which was attributed to low polarization resistance due to LY and to low interfacial resistance due to LSCF.

• Applied Chemistry for Engineering
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• v.32 no.1
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• pp.68-74
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• 2021

Gas diffusion layer (GDL) compression is important parameter of polymer electrolyte membrane fuel cell (PEMFC) performance to have an effect on contact resistance, reactants transfer to electrode, water content in membrane and electrode assembly (MEA). In this study, the effect of GDL compression on fuel cell performance was investigated for commercial products, JNT20-A3. Polarization curve and electrochemical impedance spectroscopy was performed at different relative humidity and compression ratio using electrode area of 25 ㎠ unit cell. The contact resistance was reduced to 8, 30 mΩ·㎠ and membrane hydration was increased as GDL compression increase from 18.6% to 38.1% at relative humidity of 100 and 25%, respectively. It was identified through ohmic resistance change at relative humidity conditions that as GDL compression increased, water back-diffusion from cathode and electrolyte membrane hydration was increased because GDL porosity was decreased.

• Korean Journal of Materials Research
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• v.9 no.11
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• pp.1075-1082
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• 1999

Composite air electrodes of 50/50 vol% LSM- YSZ where LSM =$\textrm{La}_{1-x}\textrm{Sr}_{x}\textrm{MnO}_{3}$(0$\leq$x$\leq$0.5) were prepared by colloidal deposition technique. The electrodes were then examined by scanning electron microscopy (SEM) and studied by ac impedance spectroscopy in order to improve the performance of a solid oxide fuel cell (SOFC). Reproducible impedance spectra were confirmed by using the improved cell, consisting of LSM- YSZ/YSZ/LSM-YSZ. These spectra were a strong function of operating temperature and the stable conditions for the cells were typically reached at $900^{\circ}C$. The typical spectra measured for an air//air cell at $900^{\circ}C$ were composed of two arcs. Addition of YSZ to the LSM electrode led to a pronounced decrease in cathodic resistivity of LSM-YSZ composite electrodes. Polishing the electrolyte surface to eliminate the influences of surface impurities could further reduce cathode resistivity. The cathodic resistivity of the LSM-YSZ electrodes with catalytic interlayer (Ni or Sr) was much smaller than that of LSM-YSZ electrodes without catalytic interlayer. In addition, the cathodic resistivity of the LSM-YSZ electrodes was a strong function of composition of electrode materials, the electrolyte geometry, and applied current.

• Journal of the Korean Magnetics Society
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• v.11 no.3
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• pp.104-108
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• 2001

The effect of specular electron scattering on natural oxidation of free layer in NiO spin valves have been investigated. The magnetoresistance (MR) ratio and the exchange biasing field ( $H_{ex}$) of NiO(600 $\AA$)Ni$_{81}$$Fe_{19}$(50$\AA$)/Co(7 $\AA$)/Cu(20 $\AA$)/Co(7 $\AA$)Ni$_{81}$$Fe_{19}$(70 $\AA$) spin valves were increased from 4.9 % to 7.3 %, and 110 Oe to 170 Oe after natural oxidation in the atmosphere for 80 days, respectively. The sheet resistivity p decreased from 28$\mu$$\Omega$m to 17$\mu$$\Omega$m, but $\Delta$$\rho$ did not almost change after the oxidation. The spin valves enhanced by the specular electron scattering in the natural]y Co/NiFe/NiFe $O_{x}$ free layer were confirmed from the depth profiles using Auger electron spectroscopy.scopy..

• Journal of the korean Society of Automotive Engineers
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• v.17 no.3
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• pp.11-18
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• 1995

본 논문에서는 주철 라이너를 삽입한 알루미늄 블럭 엔진 개발과정에서 주조 불량이 발생하였을때, 냉각계에 일어나는 제반 현상을 분석하고, 이를 해결해 나가는 과정을 기술하였다. 이를 위하여 주철 블럭과 알루미늄 블럭을 장착한 엔진의 피스톤 온도와 블럭의 열유속, 열정산을 측정하였다. 측정한 결과는 다음과 같다. 1. 알루미늄 블럭 제작시 주철 라이너와 알루미늄 블럭 사이에 공기층이 크거나, 용탕 충진이 불완전한 주조 불량이 발생하면 열접촉 저항이 커져 엔진 열전달 경로에 큰 영향을 준다. 2. 알루미늄 블럭 제작시 주조 불량이 발생하면 피스톤에서 라이너로의 전열량이 줄어듦에 따라 냉각수로의 전열량은 감소하는데, 6,000rpm, 전부하에서 알루미늄 블럭의 출력 대비 냉각수로의 방열량의 비는 38.3%이고, 주철 블럭은 44.1%이다. 3. 알루미늄 블럭 제작시 주조 불량이 발생하면, 피스톤 온도가 15-20.deg.C 정도 상승하여 피스톤 손상을 유발시킬 수 있다. 4. 알루미늄 블럭의 주조가 완벽하게 되어 주철 라이너와 알루미늄 몸체 사이에서의 열접촉저항이 없어지면, 스토로크 방향에 따른 금속면 온도 분포가 균일하게 된다. 5. 실린더 라이너의 주조상태 개선없이 오일젯을 사용한 결과 피스톤의 온도를 만족할 만한 수준으로 감소시켰다. 6. 6000rpm, 전부하에서 오일젯 적용시 출력 대비 냉각수로의 방열량의 비가 38.3%에서 36.2%로 감소하고, 출력대비 오일로의 방열량의 비는 9.6%에서 11.2%로 증가한다. 7. 오일젯 작용시 오일 펌프의 용량 증대와 오일 쿨러의 장착이 필수적이다.

• Journal of the Korea Institute of Military Science and Technology
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• v.21 no.2
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• pp.195-203
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• 2018

Among the techniques of reducing the drag to increase the speed of underwater moving bodies, we studied on the drag reduction method by gas injection. Researches on gas injection method have been paid much attention to reduce the drag of vessels or pipe inner walls. In this study, we used a sintered metal mesh that can uniformly distribute fine bubbles by gas injection method, and applied it to a cylindrical underwater moving body. Using the KRISO medium-sized cavitation tunnel, we measured both the bubble size on the surface of the sintered mesh and the bubble distribution in the boundary layer. Then, drag reduction tests were performed on the cylinder type underwater moving models with cylindrical or round type tail shape. Experiments were carried out based on the presence or absence of tail jet injection. In the experiments, we changed the gas injection amount using the sintered mesh gas injector, and changed flow rate accordingly. As a result of the test, we observed increased bubbles around the body and confirmed the drag reduction as air injection flow rate increased.

• Proceedings of the Membrane Society of Korea Conference
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• 1997.10a
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• pp.71-72
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• 1997

1. 서론 : 공기중의 산소분리용 고분자막은 높은 선택도를 동시에 요구한다. 이 두가지 조건을 만족시키는 소재 개발과 기존의 고분자물질을 수식하는 연구가 진행되고 있다. 고분자막에 대한 수식방법으로는 UV처리, plasma처리등이 있으나, 이들 방법은 선택도는 증가시키나 투과도를 감소시키는 경향이 있다. 기체의 투과저항을 줄이기 위하여 다공성 지지체 위에 박막을 입힌 복합막과 박막의 skin layer와 sub-layer를 갖는 비대칭막은 투과저항을 줄일수 있으나 선택도는 고분자 고유의 80%정도까지 감소되는 것으로 알려졌다. 본 연구의 목적은 고분자 복합막의 투과분리특성을 향상시키기 위한 것으로 지지층의 세공과 표면에 실리카/고분자를 충전, 피복시켜 투과분리특성을 조사하였다. 현재까지의 연구는 낮은 투과계수와 높은 선택도를 갖는 고분자물질이 사용되었으나, 본 연구에서는 폴리이미드로는 폴리이미드 중에서 투과계수가 가장 높다고 알려진 6FDA-p-TeMPD[{(3,3',4,4'-dicarboxyphenyl)hexafluoropropanedianhydride}-{2,3,5,6-Tetra-methyl-1,4-phenylenediamine}] 폴리이미드를 택하였으며 다공성지지체는 aluminum oxide를 사용하였다 . 본 실험에서는 선택도와 투과속도에 주로 영향을 미치는 폴리이미드와 실리카의 양에 대하여 고찰하였다.

• Journal of the Korean Society for Nondestructive Testing
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• v.23 no.4
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• pp.322-327
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• 2003

Giant magnetoresistance(GMR) NiO multilayer, which has been used to reading head of highly dense magnetic recording, was fabricated, and oxidized in an air during 80 days to study the dependence of magnetoresistance properties on residual stress in the interfaces. The magnetoresistance ratio and the exchange biasing $field(H_{ex})$ of $NiO(60nm)/Ni_{81}Fe_{19}(5nm)/Co(0.7nm)/Cu(2nm)/Co(0.7nm)/Ni_{81}Fe_{19}(7nm)$ spin valves were increased from 4.9% to 7.3%, and 110 Oe to 170 Oe after natural oxidation in the atmosphere for 80 days, respectively. The sheet resistivity ${\rho}$ decreased from $28{\mu}{\Omega}m$ to $17{\mu}{\Omega}m$, but ${\Delta}p$ did not almost change after the oxidation. Therefore, the increase of MR ratio is due to the decrease in the sheet resistivity. the reduced resistance may result from the increase in the reflection of conduction electrons at the oxidized top surface. Also, the increase in the exchange biasing field is originated from the reduction of residual stress at the interface of $NiO/Ni_{81}Fe_{19}$ according as the aging time increases.

• Journal of the Society of Naval Architects of Korea
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• v.58 no.3
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• pp.144-157
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• 2021

Brake Horse Power (BHP) reduction ratios by air injection to the underside of the hull surface in an actual ship are predicted using an unstructured finite-volume CFD solver and compared with the sea trial results. In addition, air lubrication system installed on the existing vessel is investigated to find a good solution for additional drag reduction. As a results, it is found that the thickness of the air layer should be minimized within a stable range while securing the area covered by the air layer as much as possible. Furthermore, the amount of frictional drag reduced by air injection is found to be independent of surface roughness and still effective on rough surface. Based on the results of this study, it is expected that systematic and reliable air lubrication system can be designed and evaluated using the proposed method.

• Membrane Journal
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• v.14 no.1
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• pp.66-74
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• 2004

Total resistance of membrane in a micro-filtration system using a metal membrane was mainly attributed to the permeate resistance of cake layer($R_c$), which was formed by deposited particles from the physico-chemical interactions of solids on membrane surface. Intermittent back ozonation was highly effective than the air backwashing for fouling reduction. As far the operational effect, under same ozone injection, the increase of gas flow-rate was more favorable than the increase of injection time far the recovery of permeation flux. As the filtration time was longer, the effect of flux recovery by intermittent back-ozonation decreased. Therefore, it is preferable to operate membrane cleaning before the foulant is consolidated on membrane surface.