• Title/Summary/Keyword: 공극크기

Search Result 315, Processing Time 0.027 seconds

Autogenous Shrinkage of Cement Paste Considering Disjoining Pressure in Thin Adsorbed Region (흡착 영역 분리 압력을 고려한 시멘트페이스트의 자기 수축)

  • Lee, Chang-Soo;Park, Jong-Hyok
    • Journal of the Korea Concrete Institute
    • /
    • v.18 no.2 s.92
    • /
    • pp.213-218
    • /
    • 2006
  • Meniscus, adsorbed layer thickness, capillary pressure and disjoining pressure was deduced in extended meniscus region in cement paste pore by hydrostatic equilibrium. From the results, the relationship between pore size and adsorbed layer thickness could be derived and adsorbed layer thickness represents $0.299{\sim}2.700nm$ according to pore size $1nm{\sim}1{\mu}m$. Especially, disjoining pressure rapidly Increased in less than 10 nm pore size according to adsorbed layer thickness. Therefore, it is interpreted that autogenous shrinkage of cement paste is highly increases in formation of less than 10 nm pore size. Predictions of autogenous shrinkage in cement paste considering driving force for autogenous shrinkage with capillary pressure and disjoining pressure was low in comparison with experiment values between $1{\sim}4$ days and high in later period. These tendency could be thought that pore damage by mercury injection in early age makes shrinkage driving force underestimate and assumption for unsaturated independent pore makes overestimate. These interactions might be needed corrections considering on hydration or pore replacement model.

Kinetic Study on Carbon Dioxide and Methane Hydrate in Silica Gel Pores (실리카겔 공극에서의 이산화탄소 및 메탄 하이드레이트 생성속도)

  • Kang, Seong-Pil;Lee, Jae-Goo
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2007.11a
    • /
    • pp.590-593
    • /
    • 2007
  • 물을 함유한 공극 크기 6, 30, 100 nm의 실리카겔에 이산화탄소 및 메탄을 반응시켜 온도$0{\sim}4$ $^{\circ}C$, 압력 $15{\sim}40$ bar 의 범위에서 가스 하이드레이트 생성속도를 측정하였다. 공극 크기가 작아짐에 따라 특정 온도에서의 평형압력이 높아지는 열역학적 특성을 감안하여 통일한 압력차 (평형압력과 실험압력의 차)를 얻을 수 있도록 조건을 설정하였다. 이산화탄소의 경우 통일 온도에서 하이드레이트 생성속도는 일반적으로 압력이 높아짐에 따라 가속되는 것을 알 수 있었다. 단위 물 당 포집되는 이산화탄소의 양은 최대 1.0을 넘지 못하였다. 또한 하이드레이트 생성을 위해 필요한 유도시간 (induction time)이 2내지 8시간 수준으로 매우 길었다. 공업적인 하이드레이트 이용을 위해서는 빠른 생성속도가 필요한 만큼 유도시간을 단축, 없애기 위해 계면활성제로 황산 도데실 나트륨 (sodium dodecyl sulphate)이 첨가된 수용액을 이용하였다. 계면활성제가 포함된 수용액에서의 하이드레이트 생성은 유도시간이 사라져 매우 빠르게 바뀌었고, 포집되는 이산화탄소도 15% 정도 증가되었다. 메탄의 경우에는 공극 크기가 작아질수록 하이드레이트 생성속도 및 가스 포집도가 저하되는 결과를 보였다. 이산화탄소의 경우와는 다르게 유도시간이 나타나지 않았으며 비교적 높은 가스 포집도를 얻기 위해서는 평형압력과 실험압력의 차이가 최소 2.0MPa 이상이어야 했다.

  • PDF

Non-destructive evaluation technology using infrared thermography and near infrared heating for detecting inside-defects of concrete structures (근적외선과 열화상 기법을 이용한 콘크리트 내부 공극 검출)

  • Sim, Jun-Gi;Zi, Goang-Seup;Lee, Jong-Seh
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2008.04a
    • /
    • pp.1021-1024
    • /
    • 2008
  • Near infrared heating as an alternative to the conventional heating techniques for thermography -NDT is tried in this paper. A concrete specimen containing a defect was heated by the near infrared ray and the thermography-NDT technique was applied. Using a dimensinless temperature, the defects were detected. It was found that the near infrared ray could efficiently heat up the concrete specimen compared to others conventional methods like lamps, heat flow, etc.

  • PDF

Estimation on Affecting Factors and Contribution Rate for Air Permeability of Sawdust as Bulking Agent on Composting (퇴비화 첨가재인 톱밥의 공기투과성에 미치는 영향요인 및 기여도 평가에 관한 연구)

  • Kim, Byung Tae
    • Journal of the Korea Organic Resources Recycling Association
    • /
    • v.23 no.4
    • /
    • pp.52-62
    • /
    • 2015
  • This study estimated the contribution rates of inlet air flow, moisture content, air-filled porosity and particle size on the total pressure drop for the sawdust used as the bulking agent in the composting. The statistical model for pressure drop including the affecting factors was proposed.($R^2=0.998{\sim}0.950$) While the laminar air flow(v) and particle size(SIZE*v) had the positive relations to the total pressure drop, the turbulent air flow($v^2$), moisture content(MC*v) and air-filled porosity(AFP*v) had the negative relations. Total pressure drop sharply increased with increasing of the inlet air flow. And the most significant factors affecting to total pressure drop were the particle size(SIZE*v) as positive factor and air-filled porosity(AFP*v) as negative factor. The contribution rate to total pressure drop by the particle size(SIZE*v) was continuously increased with increasing of the inlet air flow, but the contribution rate by air-filled porosity(AFP*v) was decreased. And total pressure drop was little changed even though the increasing of moisture content above the range of dry moisture content 0.25. The contribution rates of affecting factors had the different tendencies with increasing of the moisture content, especially in the negative factors as air-filled porosity(AFP*v) and moisture content(MC*v). For effective composting process, it is preferable to select the sawdust with higher air-filled porosity as bulking agent to enhance the air permeability.

Relationship between Hydraulic Conductivity and Electrical Resistivity of Standard Sand and Glass Bead (표준사와 유리구슬을 이용한 수리전도도와 전기비저항의 관계)

  • Kim, Soodong;Park, Samgyu;Hamm, Se-Yeong
    • Economic and Environmental Geology
    • /
    • v.46 no.3
    • /
    • pp.215-220
    • /
    • 2013
  • We estimated the hydraulic conductivity of the sediments using constant-head permeability tests and electrical resistivity measurements with Jumoonjin standard sand of a uniform size and glass beads of different grain sizes. In this study, we determined the variations of the porosity, the hydraulic conductivity, and the resistivity in case 1 (changing the packing of the Jumoonjin standard sand) and in case 2 (varying the size of the glass beads). The results of case 1 showed that the hydraulic conductivity decreased with an increase in the electrical resistivity. This occurred because the sand grain while packing became rhombohedral with the a decrease of both the pore size and porosity. The results of the case 2 showed that the hydraulic conductivity increased due to the increase in the pore size as caused by the increased glass bead size. In addition, the porosity decreased and the electrical resistivity increased. Therefore, the relationship between the hydraulic conductivity and the electrical resistivity is negatively proportional as regards the grain packing with a change from cubic to rhombohedral whereas this relationship is positively proportional to the increase in the grain size.

Effect On the Air Permeability of Composting Bulking Agent (퇴비화 첨가제의 공기투과성에 대한 분석)

  • Kim, Byung Tae
    • Journal of the Korea Organic Resources Recycling Association
    • /
    • v.20 no.3
    • /
    • pp.71-82
    • /
    • 2012
  • Common bulking agents in composting system include woody materials such as sawdust and woodchips. These bulking agents are mainly used for the purpose of the proper control of C/N ratio and moisture content in the composting. The topic for the effect on air permeability of bulking agents has far received relatively little attention in the composting field. This study investigated the effect of bulk density, moisture content, air-filled porosity, particle size and air flow rate on air permeability of several mixture ratios of sawdust and woodchip bulking agent. Increasing the moisture contents, the air-filled porosity was decreased and the particle size was increased for all kinds of bulking agent mixtures. Especially, with the increasing of mixing ratio of woodchip, these effects were sharply magnified. The air permeability respond to air-filled porosity was very similar to that for moisture content which was anticipated the linear relationship between air-filled porosity and moisture content. Above the region of moisture content 0.25 or 0.43(d.b.)(20 or 30% w.b.), the pressure drop decreased even though air-filled pore spaces were filling with water. Especially, to the particle size of 5 mm the pressure drop was decreased exponentially, so the air permeability was dramatically improved. By the water had the role of binding of the small particles, the macropores less resistances to air flow were created in the matrix. The effect of particle size on air permeability was much stronger than that of air-filled porosity or moisture content. And it is needed the preparing of initial particle size above 5 mm for efficient composting.

Study on the Properties of Porous Concrete According to the Aggregate Shape and Size (골재 입형 및 크기에 따른 포러스 콘크리트의 특성에 관한 연구)

  • Lim, Seo-Hyung;Kang, Hyun-Sik;Jee, Nam-Yong
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.9 no.3
    • /
    • pp.93-100
    • /
    • 2005
  • The purpose of this study is to investigate the physical properties of porous concrete according to the aggregate shape and size which is produced by con crusher and impact crusher. For this purpose, the selected test variables were the aggregate size and shape, the ratio of water to cement and the ratio of paste to aggregate. The results of this study showed that its economic performance and physical properties were improved using the aggregate made by impact crusher. The coefficient of permeability and compressive strength of porous concrete had a close correlationship with the void ratio, and it was suggested as a function of void ratio.

Preparation, Characterization and Gas Permeability of Asymmetric Porous Membranes of Poly(carbobenzoxyl-L-Lysin) (비대칭 다공성 폴리(카르보벤족시-L-리신)막의 제조, 평가 및 기체투과)

  • Kawai, Tohru;Lee, Young Moo;Fujita, Hiroshi
    • Membrane Journal
    • /
    • v.6 no.2
    • /
    • pp.96-100
    • /
    • 1996
  • In order to improve the permeability of the homogenous membrane of poly(carbobenzoxy-L-lysin)(PCLL), which has very high selectivity of helium gas to nitrogen gas, asymmetric porous membranes of PCLL were prepared by casting from 20% solutions in dioxane and dimethylformamide(DMF), respectively. The membranes were characterized by measuring the number of the pores, the pore size distribution of the surface(the skin layer) and the thickness of the skin layer by scanning electron microscope and transmission electron microscope. The mean pore size and the pore density were lower for the membrane cast from dioxane than that from DMF, which was explained by the mechanism of the formation of the pores in the asymmetric porous membrane. The permeability coefficient observed could be roughly explained by the viscous flow through the skin layer. However, the selectivity observed was against the theory of the viscous flow.

  • PDF

Porosity and Strength Properties of Permeable Concrete Using Limestone Mine Wastes as Coarse Aggregate for Concrete (폐석회석 굵은골재를 사용한 투수 콘크리트의 공극 및 강도특성)

  • 최연왕;임학상;정지승;문대중;신화철
    • Resources Recycling
    • /
    • v.12 no.2
    • /
    • pp.11-20
    • /
    • 2003
  • Limestone mine waste was used as a aggregate far permeable concrete. Void ratio, continuous void ratio, coefficient of permeability, compressive strength and flexural strength of concrete were measured and then the relationship between porosity and strength properties was investigated. Void ratio, continuous void ratio and strength properties of permeable concrete were greatly influenced by the grain size of aggregate and void filling ratio in comparison with the containing ratio of limestone mine waste. Furthermore, void ratio showed a good relation with continuous void ratio, and porosity of permeable concrete indicated a good relation with strength properties also. The coefficient of permeability of permeable concrete using limestone waste was over 0.2 cm/sec and was excellent result in comparison with normal concrete. Therefore, it could be expected that the limestone mine waste would be utilized as aggregate for pavement concrete, green concrete and water resource specie concrete in the results of this study.

Effect of Fractionated Organic Matter on Membrane Fouling (분류된 천연유기물질을 이용한 막 오염 특성 평가)

  • Lee, Byung-Gu;Son, Hee-Jong;Roh, Jae-Soon;Hwang, Young-Do;Jung, Chul-Woo;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.27 no.12
    • /
    • pp.1321-1326
    • /
    • 2005
  • As a results of this research, the Nakdong River consisted of 43% of hydrophobic fraction, 39% of hydrophilic fraction, and 18% of transphilic fraction. The hydrophobic fraction in this raw water was mostly fulvic acid. Fulvic acid comprised of 62% and the rest was humic acid(38%). There was more carboxylic acid functional roup(64%) than phenolic group(36%). HPI-N and HPI-C comprised of 17% and 22% in the hydrophilic portion, respectively. The results of the membrane fouling test using UF membrane according to NOM fractions. HPI-N caused more fouling than HPI-C. Humic acid caused more fouling than fulvic acid probably due to higher adsorption capacity. Since humic acid has higher adsorption capacity than fulvic acid, it would be more adsorbed onto the membrane pores. The carboxylic acid functional group caused more fouling than the phenolic group.