• Title/Summary/Keyword: 공간적 유동성

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The Present and the Prospects for Batteries (전지기술의 국내외 연구동향)

  • 이주성
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1999.10a
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    • pp.1-2
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    • 1999
  • 시간과 공간의 구애를 받지 않는 양질의 음성, 화상, 문자정보의 교환을 위한 노력으로 디지털 휴대폰과 휴대용 컴퓨터가 등장하면서 음성과 문자정보의 교환분야에 커다란 진보를 이룩하였다. 그러나 현재는 휴대폰이 음성정보에 문자정보교환이 추가된 상황이기 때문에, 아직도 관련 정보교환기술 및 기기개발이 진행되고 있다. 앞으로 휴대폰과 휴대용 컴퓨터의 기능을 통합하고 화상정보까지 결합된 휴대용 정보기기를 위해서는 전자회로의 집적화 및 통신속도 증대가 필수적이다. 또한 이들 휴대용 정보기기를 구동시키기 위한 전력도 증가될 것으로 예측되기 때문에, 현재 전원으로 사용되는 2차전지보다 에너지 밀도가 더욱 증패된 전지가 요구될 것으로 예상된다. 그리고 내연기관의 배기에 의해 발생되는 환정오염문제를 해결하기 위한 방법중의 일환으로 전기자동차 개발이 진행되고 있으며, 이들 전기자동차에 2차전지를 장착하기 위해서 경제성이 있고, 고속충전이 가능하고, 안전성이 높은 고에너지 밀도의 2차 전지 개발이 요구되고 있다. 현재 2차전지는 음극재료나 양극재료에 따라 낚축전지, 니켈/카드륨(Ni/Cd) 전지, 니켈/수소(Ni/MH) 전지, 라륨 2 차전지등이 있으며, 전극재료의 고유특성에 의해 전위와 애너지 밀도가 결정된다. 특히 리튬 2차전지는 리튬의 낮은 산화환원전위와 분자량으로 인해 에너지 밀도가 높기 때문에 앞에서 언급한 휴대용 전자기기의 구동전원으로 많이 사용되고 있다. 리튬 2차전지는 음극 재료가 금속리튬인 경우는 리튬금속으로, 탄소재료인 경우는 리튬이온이라 하며, 한편으로 전해질이 고체 고분자이거나 혹은 역체 유기용매와 리튬염을 고분자와 혼성시킨 겔(gel)인 경우는 고분자로, 전해짙이 리튬염이 전리되어 있는 유동성 액체일 경우는 고분자를 생략하여 구분하고 있다. 즉 리튬금속 2 차전지(LB), 리튬이온 2 차전지(LIB), 리튬금속 고분자 2차전지(LPB), 리튬 이온 고분자 2차전지(LIPB)로 크게 구분된다. 금속리듐을 음극으로 사용하고 전해질로는 리튬염이 전리되어 있는 액체유기용매 를 사용한 리튬금속 2차전지는, 금속리튬전극이 충방전 과정을 반복하면서, 전리된 리튬이 균일하게 산화환원되지 못하고 표변에서 양극방향으로 성장하는 수지상 (dendrite) 현상으로 인해 안전성 확보에 문게가 있었다. 리튬과 알루미늄 합금형태로 음극에 사용한 동전형 전지는 상용화 되었지만, 이러한 단점을 개선하기 위해 리튬이온이 금속으로 석활되는 환원반응전위보다 높은 전위에서 전극재료가 충전되면서 리튬이온이 저장되고, 방전되면서 배출되는 탄소를 음극재료로, 그리고 리튬이온이 충방 전시 가역적으로 삼입 탈리되는 층상의 리튬금속산화물을 양극으로 구성하고, 엑체 전해질과 다공성 고분자 분리막을 사용한 것이 LIB이다. LIB에서 리튬이온의 이동이 가능한 액체전해질의 가능을 고분자 전해질이 대신함으로서 보다 높은 안정성을 확보 한 전지가 LIPB 이다. 또한 고분자 전해질을 사용한 경우 금속리튬상에서의 수지상 성장이 저하되는 현상이 관찰됨으로서, 이론용량이 3,860mAh/g 에 달하는 리튬금속 혹은 합금을 고분자 전지에서 음극으로 사용하고자 하는 2 차전지가 LPB 이다. 리튬 2차전지는 비록 1989년 액체전해질을 사용한 금속리튬 2차전지의 실패전력을 안고있지만 궁극적으로는 이론적으로 최대의 에너지밀도를 가지고 있는 LPB를 지 향할 것으로 예상되지만 가까운 장래에 실현되기는 어려울 것이다. 따라서 향후의 라튬 2차전지의 전개방향은 현재의 LIB를 고분자 전해질을 채용하는 LIPB로 진행시커면서 저가의 전극재료개발을 지속적으로 추진할 것으로 예상된다. 현재 리튬 2차전지는 소형전지에 국한되고 있지만 전기자동차나 전력저장용으로 이를 대형화시커기 위해서는 열적특성이 우수하고 저가인 전극재료개발이 선행되야하기 때문에, 저가의 탄소재료와 코발트산화물을 대신할 수 있는 철, 망칸 또는 니켈산 화물의 개발이 필요하다.

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Physical and Mechanical Properties of Magnesium Oxide Matrix depending on Addition Ratio of Magnesium Chloride (염화마그네슘 첨가율에 따른 산화마그네슘 경화체의 물리 및 역학적 특성)

  • Kim, Heon-Tae;Jung, Byeong-Yeol;Lee, Sang-Soo;Song, Ha-Young
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.4
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    • pp.308-313
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    • 2014
  • Recently, for longevity of resident building, the main trend is that the change of the inside space organization of resident building from wall construction to rhamen construction, which resulted in increase in use of lightweight composite panel. Thus, in this study, authors analyzed the engineering property of oxide of magnesium depending on the magnesium chloride addition ratio. The results of this research is expected to contribute on providing a fundamental material for the surface materials of lightweight composite panel. As the result of the experiment, as fluidity increased, air content decreased and initial set and final set as the magnesium chloride addition ratio increase. In the aspect of flexural strength and compressive strength, the test specimen showed the highest strength at 40% of the magnesium chloride addition ratio. At 20% of the magnesium chloride addition ratio, the test specimen showed the lowest water absorption rate. As the magnesium chloride addition ratio increases, the expansibility tends to increase as well in the aspect of shrinkage strain. After observing microstructure, we can see hydration products in the form of needle. It appeared high flexural strength because the hydration products have mineral fibrous tissue shape, which also contribute to the cause of the expansibility.

A Study of the Planning Process, Design Idea and Implementation of the Gwanghwamun Plaza (광화문광장 조성과정 및 설계 연구)

  • Shin, Hyun-Don;Zoh, Kyung-Jin
    • Journal of the Korean Institute of Landscape Architecture
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    • v.41 no.4
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    • pp.24-41
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    • 2013
  • This study aims to investigate the complex planning processes and design ideas of the Gwanghwamun Plaza which was opened in 2009. The opening of the plaza was significant as it was built in order to restore the symbolic meaning of axis in the historical Joseon Dynasty that was distorted during the Japanese Imperialism. The plaza itself attracts many citizens and tourists by providing the empty ground carrying historical ambiences around. In this paper, the story of the Gwanghwamun plaza will be summarized. Particularly, the background of promoting the project will be discussed and the whole planning process will be dealt with. The plaza was realized through several stages. First, the planning stage will be reviewed. The planning stage had been a quite long process since the initial idea was discussed. Since the early 90s, the political decision of making the plaza was made through the change of people's understanding toward public space. At this stage, the city government worked together with diverse citizens and professionals to share the vision and to realize the right decision in making the plaza. Second, the design stage will be elaborated in detail. This is the second design stage. The former was the idea competition and the latter was the turn-key base. The final design scheme emphasized the restoration of symbolic axis and the forgotten Yukjo Street. The scheme consists of four zones such as history restoration zone, prospect and history representation zone, culture zone, and the urban zone. Through the whole design process, the original idea remained as it was. The design concept was "a place of memory and prospect." It emphasizes the history representation, view corridor, cultural activities platform as well as the emptiness and flexibility of the basic premise of the plaza. Finally, the construction stage will be discussed. There were some additions and omissions in the construction process. The design chances in the construction stage will be reviewed in detail. After the opening of the plaza, there were some changes in the detail design. We will discuss how and why these modifications were made. In the end, the social and cultural implication of the plaza will be discussed. The storytelling of the Gwanghwamun Plaza will contribute to the clear understanding of planning and design process of pubic places. Based on this reflection, we are able to think about some suggestions of public projects for the future.

Mechanical and Germination Characteristics of Stabilized Dredged Soil (고화준설토의 역학적 특성과 식생 발아 특성)

  • Lee, Miji;Mun, Kyoungju;Yoon, Gillim;Eum, Hyunmi;Kim, Yuntae
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.3
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    • pp.33-40
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    • 2014
  • In this paper, mechanical and germination characteristics of stabilized dredged soils were investigated to recycle dredged soil in eco-friendly manner such as waterfront construction. Non sintering binder (NSB), which was developed by using interchemical reactions between slag, high-calcium fly ash, alkali activator on the dredged marine clay, was added to dredged soil. Ordinary portland cement was also used for the comparison of two binders. Experimental tests such as flow test and unconfined compressive test were carried out to evaluate characteristics of stabilized dredged soil. Leaching test, pH measure, vegetation germination test were also conducted to consider environmental applicability. The unconfined compressive tests shows that unconfined compressive strength (UCS) also increases with the increase of curing time and mixed ratio. UCS of NSB mixtures were higher than those of OPC mixtures. Germination tests showed that germination and sprouting date are better in NSB mixture than OPC mixture. It can be explained that germination decreased as pH and 7-day strength increased.

Experimental study on ultra-high strength concrete(130 MPa) (초고강도 콘크리트(130MPa)에 대한 실험적 연구)

  • Cho Choonhwan;Yang Dong-il
    • Journal of the Korea Institute of Construction Safety
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    • v.6 no.1
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    • pp.12-18
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    • 2024
  • High-rise, large-scale, and diversification of buildings are possible, and the reduction of concrete cross-sections reduces the weight of the structure, thereby increasing or decreasing the height of the floor, securing a large number of floors at the same height, securing a large effective space, and reducing the amount of materials, rebar, and concrete used for designating the foundation floor. In terms of site construction and quality, a low water binder ratio can reduce the occurrence of dry shrinkage and minimize bleeding on the concrete surface. It has the advantage of securing self-fulfilling properties by improving fluidity by using high-performance sensitizers, making it easier to construct the site, and shortening the mold removal period by expressing early strength of concrete. In particular, with the rapid development of concrete-related construction technology in recent years, the application of ultra-high-strength concrete with a design standard strength of 100 MPa or higher is expanding in high-rise buildings. However, although high-rise buildings with more than 120 stories have recently been ordered or scheduled in Korea, the research results of developing ultra-high-strength concrete with more than 130 MPa class considering field applicability and testing and evaluating the actual applicability in the field are insufficient. In this study, in order to confirm the applicability of ultra-high-strength concrete in the field, a preliminary experiment for the member of a reduced simulation was conducted to find the optimal mixing ratio studied through various indoor basic experiments. After that, 130 MPa-class ultra-high-strength concrete was produced in a ready-mixed concrete factory in a mock member similar to the life size, and the flow characteristics, strength characteristics, and hydration heat of concrete were experimentally studied through on-site pump pressing.

Comparative Studies on K2CO3-based Catalytic Gasification of Samhwa Raw Coal and Its Ash-free Coal (삼화 원탄과 무회분탄의 촉매(K2CO3) 가스화 반응성 비교 연구)

  • Kong, Yongjin;Lim, Junghwan;Rhim, Youngjoon;Chun, Donghyuk;Lee, Sihyun;Yoo, Jiho;Rhee, Young-Woo
    • Clean Technology
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    • v.20 no.3
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    • pp.218-225
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    • 2014
  • Catalytic gasification of raw coals at mild condition is not realized yet mainly due to deactivation of catalysts via their irreversible interaction with mineral matters in coal. In this work, the gasification behavior of ash-free coal (AFC) was compared with that of the parent raw coal. In order to modify the gasification conditions, the raw coal gasified with fixed variables (water supply, space velocity, temperature, catalysts) in a fixed bed reactor. When catalysts are added by physical mixing method with coal, $K_2CO_3$ was the most effective additives for steam gasification of coal. However, the activity of ash-free coal (AFC) was much less reactive than raw coal due to high temperature extraction in a 1-methylnaphthalene under 30bar at $370^{\circ}C$ for 1 h, almost removed oxygen functional groups, and increased carbonization. The addition of $K_2CO_3$ in AFC achieved higher conversion rate at low temperature ($700^{\circ}C$). At that time, the molar ratio of gases ($H_2/CO$ and $CO_2/CO$) was increased because of water-gas shift reaction (WGSR) by addition of catalysts. This shows that catalytic steam gasification of AFCs is achievable for economic improvement of gasification process at mild temperature.

Diversity of the Cretaceous basaltic volcanics in Gyeongsang Basin, Korea (경상분지내 백악기 현무암질 화산암류의 다양성)

  • 김상욱;황상구;이윤종;고인석
    • The Journal of the Petrological Society of Korea
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    • v.9 no.1
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    • pp.1-12
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    • 2000
  • The Cretaceous basaltic rocks in Gyeongsang Basin are temporally and spatially dispersed widely in thick sedimentary piles: Chilgog basaltic rock (CGB) and Cheongyongsa basaltic rock (CSB) in the Shindong Group, and Hakbong basaltic rocks (HBB), Osibbong basalt (OSB), Secheondong basaltic rocks (SCB), Haman basaltic rocks (HAB), Hama basaltic rocks (HMB), and Chaeyaksan basaltic rocks (CYB) in the Hayang Group, upwardly in their stratigraphy. Chilgog basaltic rock is merely identified as pebbles in the Shilla Conglomerate and its provenance has not been found, and it is characteristics that the volcanics except Osibbong basalt and Chaeyaksan basaltic rocks are very small in both of their thickness and extension. Petrochemical diversity of the basaltic rocks are revealed; OSB and SCB distributed in the Yeongyang Minor Basin preserve the calc-alkaline natures in major and immobile minor element geochemistry, but CGB, HBB, HAB, and CYB reflect that they might be originated from calc-alkaline basaltic magma of volcanic arc in continental margin area by trace elements and altered to alkaline suites in the viewpoint of their major element geochemistry. Major and trace element geochemistry of CSB and HMB suggests that they may be derived from within -plate alkaline magma contaminated by the upper continental crust, especially in the case of the former.

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Experimental Study on Effectiveness of Wave Reduction and Prevention Erosion of Nourishment Sand Using the Cell Group (Cell Group을 이용한 파랑저감 및 양빈사 유실방지에 관한 실험적 연구)

  • Park, Sang Kil;Park, Hong Bum;Kim, Young Hwan
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.29 no.5
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    • pp.269-277
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    • 2017
  • Recently, a submerged breakwater has been installing to prevent the erosion of shoreline everywhere. Artificially submerged breakwater is made to minimize the loss of nourishment sand beach erosion. For this reason, it has been indiscriminately constructed submerged breakwater that is planned in the country throughout. However, maintenance purposes to keep the shoreline of the beach is a method that is quite a few problems. There are also disadvantages such as expensive construction costs, ocean space utilization, water pollution and shoreline modification. In addition, person of utilizing the space of the ocean leisure does not like that because of the disconnection of ocean space. The beaches such as Gwanganri are artificially supplying nourishment sand to maintain the beach. The flexible construction method refers to a structure that is installed as a flexible material instead of submerged breakwater to prevent the loss of nourishment sand. In order to develop a new method to mitigate shoreline erosion, this study was carried out a hydraulic model experiment by installing a cell group as an example of the flexible method. Namely, in order to prevent the loss of nourishment sand, we decided to develop a new method that can mitigate the degree of beaches erosion by using cell group instead of submerged breakwater. In the two dimensional fixed hydraulic experiment, was carried out the effect reducing of wave height and the rate of low reflection due to the installation of the cell group. In movable bed experiment, the capture rate of the nourishment sand and the erosion prevention rate of the nourishment sand was performed for stability of shoreline. Therefore, according to the results of the hydraulic tests, it was possible to maintain the stable beaches due to installing the cell group on the erosion beaches, due to the effect of reducing wave height, the low reflection, the erosion prevention rate of nourishment sand, the high capture rate of nourishment sand.

A Study on the Landscape Architecture Historical Significance of Reung Chambong in the Joseon Dynasty (조선시대 능참봉직(陵參奉職)의 조경사적 의의)

  • Shin, Hyun-Sil;Lee, Won-Ho
    • Journal of the Korean Institute of Traditional Landscape Architecture
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    • v.29 no.2
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    • pp.139-148
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    • 2011
  • This study has a purpose of base study for ascertaining landscape architect's role of Reung Chambong through analyzing old literature include Kyungkukdae-Jeon, Sokdae-Jeon, Daejeonhoitong, Joseonwangjo-Sillok, Eugye, Reung-Ji, Ilsung-Rok, Reung Chambong's diary. Reung Chambong was a government post in the Joseon dynasty, who managed Royal Tombs of Joseon Dynasty that has promoted as a World Heritage of UNESCO. the conclusions drawn from this study are as follows. First, Reung Chambong was comprised of two Jong 9 pum Chanmbong members. a position of Reung Chambong was a Eumjik appointed Saengwon, Jinsa, Yuhak completed Sammang. the standards of appointment is a experienced person and too young. it became means for accessing a government post because it had a symbolic representation of Royal Tombs guardian. Second, The management system of Reung Chambong was approved on the basis of ranking. however, due to geographical reasons, they had much authority and various mission than is possible. for example, construction supervisor of the Reung and Bongsim, manager of the Reungsuhogun and filling out Reungji. they performed an important role in management of Royal Tombs in the Joseon dynasty. Third, One of tasks related in landscape architecture, a Bongshim reported Sukmul(stonework), Sacho, Jungja-Gak of Reungsang to Yejo periodically. formational system and method of Bongshim are provided in the Kyungkukdae-Jeon and Sokdae-Jeon detailedly. Fourth, Tree management and construction supervisor of Reungsang, positions among tasks related in landscape architecture, required basic understanding and management ability of botany, various eye for spatial perception includes civil and architectural projects. also, as a site management of Royal Tombs in the Joseon dynasty, Reung Chambong was empowered tacit authorization and responsibility in mobility preoccupancy of vertical relationship with local officials and handling by-product of site. there is a close correspondence with landscape architect of today. A follow-up research is required to ascertain landscape architect historical values of Royal Tombs in the Joseon dynasty and Reung Chambong's role as a site management of Royal Tombs in the Joseon dynasty through historical seeking and research old literature on Reung Chambong's role related in landscape architect.