• Journal of the Korea Institute of Building Construction
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• v.18 no.5
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• pp.403-412
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• 2018

Recently, needs for utilization of recycled aggregate have been increasing. However, its utilization has been limited due to its high alkalinity, which mostly came from the unremoved cement paste particles that were attached at the surface of recycled aggregate. Various efforts has been made to reduce its alkalinity by using $CO_2$, but currently available methods that uses $CO_2$ generate the problem with pH recovery. Considering the fact that supercritical $CO_2$ ($scCO_2$) can provide more rapid carbonation of cement paste than by normal $CO_2$, $scCO_2$ was utilized in this work. The reaction between $scCO_2$ and hydrated cement paste has been systematically evaluated. According to the results, it was found that powder type showed higher carbonation compared to that of cube specimens. It seems the carbonation by $scCO_2$ has occurred only at the surface of the specimen, and therefore still showed some amount of $Ca(OH)_2$ calcium aluminates after reaction with $scCO_2$. With powder type specimen, all $Ca(OH)_2$ was converted into $CaCO_3$. Moreover, additional calcium that came from both calcium aluminate hydrates and calcium silicate hydrates reacted with $scCO_2$ to form $CaCO_3$. After carbonation with $scCO_2$, the powder type specimen did not show pH recovery, but cube specimens did show due to the presence of portlandite.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.389-392
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• 2008

Electric-furnace-slag has the expansion, due to the reaction with water and free Cao. So compared with the blast-furnace-slag, the recycling range of EFS is subject to restriction. But the expansive reaction of EFS is removed, the it is possible to use aggregate for concrete. This study is the basic properties of concrete to used stabilized EFS(oxidized EFS). The EFS is used fine aggregate in concrete, and replaced by sea-sand(natural sand). The replacement ratio are 0%, 25%, 50%, 75%, 100%. The result of study, to used oxidized EFS-sand, the flowability and the compressive strength is increased. Also it is possible to reduce the Bleeding. It is necessary more study about using the EFS aggregate, like the durability, the mechanical property for concrete

• Journal of the Korean Geotechnical Society
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• v.40 no.1
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• pp.29-37
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• 2024

In this study, recycled concrete aggregates (RCA) were treated in a 5-kg-scale prototype reactor with carbon dioxide (CO₂) to enhance their material quality and geotechnical performance. The aggregate crushing value (ACV) and California bearing ratio (CBR) were measured on untreated RCAs and CO₂-treated RCAs. After CO₂ treatment, the ACV decreased from 35.6% to 33.2%, and the CBR increased from 97.5% to 102.4%. The CO₂ treatment caused a reduction of fine particle generation and an increase in bearing capacity through carbonation. When CO₂ treatment was performed with mechanical agitation, which provided additional enhancement in mechanical quality, the ACV was reduced further to 30.3%, and the CBR increased to 137.7%. If upscaled effectively, the proposed CO₂ treatment technique would be an effective method to reduce carbon emissions in construction industries.

• Journal of the Mineralogical Society of Korea
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• v.14 no.2
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• pp.85-98
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• 2001

This study deals with the petrographic examination of aggregates(ASTM C 295) which is one of the methods to diagnose the quality of aggregates for concrete artifacts. A number of examinations including size and sieve analysis, test on the coating material, description of the weathering and contamination condition, petrographic description, and qualitative and quantitative analyses on the rocks and minerals potential to alkali-aggregates reactivity are carried out to examine the quality of aggregates. Petrographic description method examined on the fluvial aggregates from Maewhacheon A, B area, Uljin-gun, Kyungnam province shows that weathering grade ranges from F(fresh) to WS(slightly weathered) and coating material and contamination are not in a harmful condition. The weight percentage of the alkali-aggregates reactive minerals or structurally unstable rocks of the aggregates from study area covers 26% and 19% of all aggregates, respectively. So it is necessary to further identify their quality through the chemical(ASTM C 289) and mortar-bar method (ASTM C 227).

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.2
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• pp.97-102
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• 2011

Amount of disposed construction materials like waste concrete is growing fast and use of the recycled aggregate for concrete has been seriously considered. But the use of the recycled aggregate is very limited because recycled aggregate has very low quality. Therefore, quality of recycled aggregate is very important in the manufacturing of recycled aggregate concrete. We have studied a series of research according to chemical processes and investigate the alkaline elimination effect of recycled aggregate and quality variation of recycled aggregate by sodium carbonate. Thereafter we have evaluated quality of recycled fine aggregate and experimented quality of this aggregate. As a results, we find that it is easy to eliminate the calcium hydroxide in recycled aggregate by sodium carbonate and the quality of recycled aggregate increase by elimination of alkaline.

• Proceedings of the Korea Concrete Institute Conference
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• 1993.10a
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• pp.103-107
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• 1993

The Alkali Aggregate Reaction(AAR), reported first by T. E. Stanton in 1940, is a reaction between certain siliceous aggregate and hydroxyl ions present in the pore fluid of a concrete. The damage of concrete structures, deteriorated by AAR, have been reported since using the crushed stones caused by the exhaustion of natural aggregates. This study was performed to investigate the AAR of crushed stones using chemical analysis, polarization microscope, XRD, chemical method(KS F 2545, ASTM C 289), mortar bar method(KS F 2546, ASTM C 227) and Scanning Electron Microscope(SEM) and Energy Dispersive X-ray Analysis (EDXA) of reaction products by AAR in mortar bar.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.22 no.5
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• pp.254-259
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• 2012

The mechanical property enhancement was studied using fly ash produced from fluidized bed type boiler in power plant, which contains a lot of Ca component being used to carbonate for $CO_2$ fixation in the lightweight aggregates made of cement and some portion of fly ash as a cement substitution under the supercritical condition. Specimens having various fly ash substitution rates and curing periods were carbonated under the supercritical condition at $40^{\circ}C$. The weight change rate, carbonation rate by TG/DTA analysis, 1% Phenolphthalein test, specific gravity and mechanical compression strength test were performed to observe the mechanical property enhancement of the cemented materials after carbonation under the supercritical condition and to make sure those could be classified as lightweight aggregates having specific gravity under 2.0.

• Cement
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• s.161
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• pp.62-66
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• 2003

• 레미콘
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• no.10 s.53
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• pp.82-86
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• 1997

• Cement Symposium
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• no.14
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• pp.55-62
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• 1986