• Title/Summary/Keyword: 고체연료화

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Performance Simulation of Planar Solid Oxide Fuel Cells Characteristics: Computational Fluid Dynamics (전산 유체 모델링을 이용한 평판형 고체산화물 연료전지 작동특성 전산모사)

  • Woo Hyo Sang;Chung Yong-Chae
    • Journal of the Korean Electrochemical Society
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    • v.7 no.2
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    • pp.69-79
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    • 2004
  • To correctly simulate performance characteristics of fuel cells with a modeling method, various physical and chemical phenomena must be considered in fuel cells. In this study, performance characteristics of planar solid oxide fuel cells were simulated by a commercial CFD code, CFD-ACE+. Through simultaneous considerations for mass transfer, heat transfer and charge movement according to electrochemical reactions in the 3-dimensional planar SOFC unit stack, we could successfully predict performance characteristics of solid oxide fuel cells under operation for structural and progress variables. In other words, we solved mass fraction distribution of reactants and products for diffusion and movement, and investigated qualitative and quantitative analysis for performance characteristics in the SOFC unit stack through internal temperature distribution and polarization curve for electrical characteristics. Through this study, we could effectively predict performance characteristics with variables in the unit stack of planar SOFCs and present systematic approach for SOFCs under operation by computer simulation.

Preliminary Properties and Combustion Behavior of Solidified Ethanol Fuel (고형 에탄올 연료의 기본 물성치 및 연소특성)

  • Kim, Hyemin;Jo, Min Kyung;Yang, Sung Ho
    • Journal of Aerospace System Engineering
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    • v.13 no.3
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    • pp.9-14
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    • 2019
  • Liquid and solid fuels currently in use have various pros and cons. As a result, researches are dedicated to produce a new form of fuel that utilizes the advantages and overcomes weakness of conventional fuels. In the present study, a new method for making solidified ethanol fuel is introduced, and its preliminary properties and combustion characteristic are observed. The solidified ethanol fuel was made through the production of agarose hydrogel, and its subsequent soaking into pure ethanol. The properties of the solidified ethanol fuel were quantitatively and qualitatively observed, and its validity and applicability discussed.

A Study on Fire Risk & Countermeasure of RDF(Refuse Derived Fuel) (생활폐기물 고형연료제품의 화재위험과 안전대책에 관한 연구)

  • Jeong, Ui-Su;Gang, Gyeong-Sik
    • Proceedings of the Safety Management and Science Conference
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    • 2009.04a
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    • pp.17-25
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    • 2009
  • 세계의 모든 나라가 화석연료를 대체하는 태양광, 풍력 등의 그린에너지 기술개발에 주력하고 있으며, 한편으로는 에너지의 효율제고 및 재생을 위하여 폐기물로부터의 자원순환을 이룩하는 폐기에너지 회수에도 많은 노력을 기울이고 있다. 그 하나의 방편이 버려지는 쓰레기에서 에너지를 회수하는 고형재생연료인 RDF(생활폐기물 고형연료 제품, Refuse Derived Fuel) 생산이다. 우리나라에서는 유일하게 강원도 원주시에서 하루 80톤을 생산하고 있으며 아직은 기술도입 초기단계에 있는 가연성폐기물의 연료화 기술이다. RDF의 특성은 불연성 성분이 제거된 일반 가연물을 분쇄하여 압출성형 가공한 펠릿형상의 고체연료로서의 열적 특성이 우수하나 화재안전 측면에서는 제조 및 취급공정에서의 일반적인 가연물 화재위험성을 가지고 있고, 저장과정에서는 축열발열에 의한 자연발화 위험성이 상존하며, 저장형태, 특히 사이로의 경우 구조특성으로 인하여 화재진압도 쉽지않다. 본 논문에서는 일본의 RDF 화재사례를 중심으로 그 화재 위험 특성과 안전대책을 고찰하고자 한다.

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Development of manufacturing technology for reliable parts for decentralized SOFC power generation system (고효율 분산발전 SOFC용 고신뢰성 소재/부품 양산기반 기술개발)

  • Park, Sang-Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.134-134
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    • 2009
  • 발전용 연료전지의 경쟁상황이 점점 치열해지고 있는 상황에서 경쟁력을 확보하기 위해서는 현재 상용화되어 있는 2세대 연료전지인 MCFC 관련 기술을 최대한 빨리 확보하고, 전세계적으로 R&D 단계에 있는 3세대 연료전지인 SOFC 관련 기술을 독자적으로 수행하여 가장 먼저 상용화하여야 할 것이다. 본 논문에서는 그 동안 MCFC 관련 사업 역량 및 응용 기술의 확보를 위하여 포스코 그룹이 수행한 사업 및 R&D 내용을 정리하고, 향후 SOFC 기술의 상용화를 위한 포스코 그룹의 전략을 발표하고자 한다. 또한 그 동안 SOFC 연구가 시스템 개발 위주로 진행되어 옴에 따른 문제점을 지적하고, SOFC 시스템 기술을 뒷받침할 수 있는 부품/소재 개발과 관련한 포스코파워의 연구 결과를 요약 발표하도록 한다.

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Air-independent Fuel Cell Power System (공기 불요 연료전지 동력 시스템)

  • Kim, Tae-Gyu
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.331-334
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    • 2009
  • An air-independent propulsion (AIP) system based on fuel cell technologies was developed for space and underwater applications in the present study. Hydrogen peroxide was selected as an oxidizer for space and underwater power applications where air independence is a must. Catalytic decomposition of hydrogen peroxide was used to generate oxygen and water. The pure oxygen was provided to a fuel cell and the water was stored separately. Sodium borohydride in the solid state was used as a hydrogen source in the present study. Pure hydrogen can be generated by a catalytic hydrolysis reaction. A fuel cell system was fabricated to validate the fuel cell based air-independent power system and was evaluated at the various conditions.

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The Effect of Air Impurities on the PEMFC Performances (공기에 포함된 불순물에 의한 PEMFC 운전 성능 변화)

  • Jang, Jong-Hyun;Kim, Yi-Young;Han, Jong-Hee;Lee, Sang-Yeop;Cho, Eun-Ae;Kim, Hyoung-Juhn;Lim, Tae-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.526-529
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    • 2008
  • The effect of air impurities on PEMFC performances were studied using electrochemical analysis, such as OCV monitoring, polarization, constant current operation, and electrochemical impedance spectroscopy. The nitrogen dioxide in air lowered the operation voltage at 1 A/$cm^2$ by 160 mV (10 ppm) and 227 mV (100 ppm), while the carbon monoxide effect was relatively not significant (30 mV at 100 ppm). For both nitrogen dioxide and carbon monoxide, the performances were largely recovered when pure air was provided again. Further study for additional air impurities and simulated air are under progress to provide fundamental data for the design of fuel cell vehicles.

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A Study on the Characteristics of Combustion and Manufacturing Process on Refuse-derived Fuel by Mixing Different Ratios with Organic and Combustible Wastes (유기성폐기물 고체연료화를 위한 연소 및 제조과정의 특성연구)

  • Ha, Sang-An
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.1
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    • pp.27-38
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    • 2009
  • To investigate the feasibility of refuse derived fuels (RDFs) combined of sewage sludge and combustible wastes such as substitutive fuels instead of a stone coal, several different RDFs made with different mixtures of sewage sludge and combustible wastes were analyzed by various experiments. The combustion characteristics for the RDFs were investigated by analyzing fuel gases, and heating values were also measured by a bomb calorimeter. The fundamental properties such as moisture contents, ratios of combustible materials, amounts of ashes, heavy metals, ratios of each chemical elements and heating values were analyzed in accordance with mixing ratios of wt(%) for researching the characteristics of the RDFs. $RDF_{k-1}$ was made of mixing materials which were dried sewage sludge, food wastes and combustible wastes. $RDF_{k-2}$ was made of mixing materials which were peat-moss, tar and sewage sludge. Combustion experiments were carried out at the optimal conditions which were m=2 under air-fuel condition and $850^{\circ}C$. The retention times in the combustor were set at 5, 10 and 15minutes. 50 g of RDFs was put in the combustor for each experiments. The ranges for heating values of $RDF_{k-1}$ with different mixing ratios were from 6,900 kcal/kg to 8120 kcal/kg. The ranges for heating values of $RDF_{k-2}$ with different mixing ratios were from 4,014 kcal/kg to 8,050 kcal/kg. As a result of this study, the heating values, moisture contents, components of chemical elements and mixing ratios of the materials in RDFs had big effects on the efficiency of the combustion. In $RDF_{k-1}$, the higher amounts of combustible wastes in the mixtures, the higher heating values, concentrations of $C_xH_y$ and amounts of ashes were produced. In $RDF_{k-2}$, the higher tar amounts in the mixtures caused the higher heating values, amounts of ashes, concentrations of CO gas and CxHy.