• Tunnel and Underground Space
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• v.14 no.6 s.53
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• pp.429-439
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• 2004

The deep underground High Level Waste (HLW) repository to dispose of 36,000tons of spent fuel from the reactors in Korea needs about $4km^2$ repository area. In this study, the deep undergrond repository layout was optimized to minimize the excavation rock volume as well as underground repository area. In the optimization, the results from thermal analysis were used to define the influence of tunnel and deposition hole spacings on repository layout. The repository area and excavation rock volume could be reduced with longer disposal tunnel length. When it is necessary to reduce the repository area with satisfying thermal criteria, it is better to reduce tunnel spacing and increase deposition hole spacing. In contrast, the excavation rock volume can be reduced by increasing the tunnel spacing and decreasing the hole spacing.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.16 no.2
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• pp.233-242
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• 2018

To overcome the low mechanical strength and corrosion behavior of a carbon steel canister at high temperature condition of a deep borehole, SiC ceramics were studied as an alternative material for the disposal canister. In this paper, a design concept for a SiC canister, along with an outer stainless steel container, was proposed, and its manufacturing feasibility was tested by fabricating several 1/3 scale canisters. The proposed canister can contain one PWR assembly. The outer container was also prepared for the string formation of SiC canisters. Thermal conductivity was measured for the SiC canister. The canister had a good thermal conductivity of above $70W{\cdot}m^{-1}{\cdot}K^{-1}$ at $100^{\circ}C$. The structural stability was checked under KURT environment, and it was found that the SiC ceramics did not exhibit any change for the 3 year corrosion test at $70^{\circ}C$. Therefore, it was concluded that SiC ceramics could be a good alternative to carbon steel in application to deep borehole disposal canisters.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.06a
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• pp.399-406
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• 2004

본 연구에서는 국내 원전이 위치한 지역의 토양에서 $Cs^{137}$의 축적 경향을 파악하기 위하여 원전이 위치한 영광군 관내의 평지와 고산지대인 금정산, 불갑산 및 영광원전으로부터 원거리에 위치한 내장산 등을 대상으로 토양 중 $Cs^{137}$의 화학적인 특성과 고도에 따른 $Cs^{137}$의 축적 경향을 평가하기 위하여 실험을 통한 연구를 수행하였다. 일반적으로 국내 토양 중 $Cs^{137}$의 농도는 불검출 - 2523q/kg-dry의 범위 내에 포함되었으며 본 연구에서 수행한 평지부분과 고산지대인 원전으로부터 2km 떨어진 금정산, 약 20km 떨어진 불갑산 및 원거리에 위치한 내장산에서도 지금까지의 $Cs^{137}$ 농도 범위에 들었다. 그러나 고산지대는 평지에서와는 다르게 고도가 증가함에 따라 $Cs^{137}$ 농도도 증가하는 경향을 보이고 있고, 정상 부분보다 $Cs^{137}$의 농도가 하부 부분보다 더 높게 나타났고 영광원전 인근 일반평지부분보다는 $Cs^{137}$의 방사능 농도가 2~6배 정도의 높은 경향을 나타내었다. 연구결과 $Cs^{137}$의 분포는 지형적 요인(고도, 강수량 등)과 토양의 화학적 요인(양이온치환용량)과 상관성이 근 것으로 나타났다. 지형적 요인으로는 주로 고도를 들수가 있는데 높은 고도의 산의 경우 대기중 $Cs^{137}$이 토양에 침투되는 기회가 커짐으로 동일한 토질 조건의 평지 토양에 비해 높은 $Cs^{137}$ 준위를 나타내었다. 토양의 화학적 요인으로는 양이온치환용량이 주요 인자임이 규명되었다. 양이온치환용량은 침적된 $Cs^{137}$을 토양에 고정시키는 능력을 나타내며 같은 지형조건에서 높은 양이온치환용량을 가진 시료가 낮은 양이온치환용량을 가진 토양에 비해 $Cs^{137}$ 농도가 높은 값을 보였다.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.4 no.3
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• pp.235-243
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• 2006

In this study, an experimental study on the sorption properties of uranium(VI) onto a bentonite colloid generated from Gyeongju bentonite which is a potential buffer material in a high-level radioactive waste repository was performed as a function of the pH and the ionic strength. The bentonite colloid prepared by separating a colloidal fraction was mainly composed of montmorillonite. The concentration and the size fraction of the prepared bentonite colloid measured using a gravitational filtration method was about 5100 ppm and 200-450 nm in diameter, respectively. The amount of uranium removed by the sorption reaction bottle walls, by precipitation, and by ultrafiltration was analyzed by carrying out some blank tests. The removed amount of uranium was found not to be significant except the case of ultrafiltration at 0.001 M $NaClO_4$. The ultrafiltration was significant in the lower ionic strength of 0.001 M $NaClO_4$ due to the cationic sorption onto the ultrafilter by a surface charge reversion. The distribution coefficient $K_d$ (or pseudo-colloid formation constant) of uranium(VI) for the bentonite colloid was about $10^4{\sim}10^7mL/g$ depending upon pH and ionic strength of $NaClO_4$ and the $K_d$ was highest in the neutral pH around 6.5. It is noted that the sorption of uranium(VI) onto the bentonite colloid is closely related with aqueous species of uranium depending upon geochemical parameters such as pH, ionic strength, and carbonate concentration. As a consequence, the bentonite colloids generated from a bentonite buffer can mobilize the uranium(VI) as a colloidal form through geological media due to their high sorption capacity.

• Journal of the Korean Geotechnical Society
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• v.36 no.10
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• pp.33-39
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• 2020

A geological repository has been considered as an option for the disposal of high-level radioactive waste (HLW). The HLW is disposed in a host rock at a depth of 500~1,000 meters below the ground surface based on the concept of engineered barrier system (EBS). The EBS is composed of a disposal canister, buffer material, backfill material, and gap-filling material. The compacted bentonite buffer is very important since it can restrain the release of radionuclide and protect the canister from the inflow of ground water. The saturation of the buffer decreases because high temperature in a disposal canister is released into the surrounding buffer material, but saturation of the buffer increases because of the inflow of ground water. The unsaturated properties of the buffer are critical input parameters for the entire safety assessment of the engineered barrier system. In Korea, Gyeongju bentonite can be considered as a candidate buffer material, but there are few test results of the unsaturated properties considering temperature variation. Therefore, this paper conducted experiment of soil-water characteristic curve for the Gyeongju compacted bentonite considering temperature variation under a constant water content condition. The relative error showed approximately 2% between test results and modified van-Genuchten model values.

• Journal of the Korean Geotechnical Society
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• v.33 no.7
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• pp.55-64
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• 2017

A geological repository has been considered one of the most adequate options for the disposal of high-level radioactive waste. A geological repository will be constructed in a host rock at a depth of 500~1,000 meters below the ground surface. The geological repository system consists of a disposal canister with packed spent fuel, buffer material, backfill material, and intact rock. The buffer is very important to assure the disposal safety of high-level radioactive waste. It can restrain the release of radionuclide and protect the canister from the inflow of groundwater. High temperature in a disposal canister is released into the surrounding buffer material, and thus the thermal transfer behavior of the buffer material is very important to analyze the entire disposal safety. Therefore, this paper presents a thermal conductivity prediction model for the Kyungju compacted bentonite buffer material which is the only bentonite produced in Korea. Thermal conductivity of Kyungju bentonite was measured using a hot wire method according to various water contents and dry densities. With 39 data obtained by the hot wire method, a regression model to predict the thermal conductivity of Kyungju bentonite was suggested.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.15 no.4
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• pp.391-402
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• 2017

The Korea Radioactive Waste Agency (KORAD) has developed a concrete cask for the dry storage of spent nuclear fuel that has been generated by domestic light-water reactors. During long-term storage of spent nuclear fuel in concrete casks kept in dry conditions, the integrity of the concrete cask and spent nuclear fuel must be maintained. In addition, the radiation dose rate must not exceed the storage facility's design standards. A suitable shielding design for radiation protection must be in place for the dry storage facilities of spent nuclear fuel under normal and accident conditions. Evaluation results show that the appropriate distance to the annual dose rate of 0.25 mSv for ordinary citizens is approximately 230 m. For a $2{\times}10$ arrangement within storage facilities, rollover accidents are assumed to have occurred while transferring one additional storage cask, with the bottom of the cask facing the controlled area boundary. The dose rates of 12.81 and 1.28 mSv were calculated at 100 m and 230 m from the outermost cask in the $2{\times}10$ arrangement. Therefore, a spent nuclear fuel concrete cask and storage facilities maintain radiological safety if the distance to the appropriately assessed controlled area boundary is ensured. In the future, the results of this study will be useful for the design and operation of nuclear power plant on-site storage or intermediate storage facilities based on the spent fuel management strategy.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.15 no.3
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• pp.199-206
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• 2017

A geological repository for the disposal of high-level radioactive waste is generally constructed in host rock at depths of 500~1,000 meters below the ground surface. A geological repository system consists of a disposal canister with packed spent fuel, buffer material, backfill material, and intact rock. The buffer is indispensable to assure the disposal safety of high-level radioactive waste, and it can restrain the release of radionuclides and protect the canister from the inflow of groundwater. Since high temperature in a disposal canister is released to the surrounding buffer material, the thermal properties of the buffer material are very important in determining the entire disposal safety. Even though there have been many studies on thermal conductivity, there have been only few studies that have investigates the specific heat capacity of the bentonite buffer. Therefore, this paper presents a specific heat capacity prediction model for compacted Gyeongju bentonite buffer material, which is a Ca-bentonite produced in Korea. Specific heat capacity of the compacted bentonite buffer was measured using a dual probe method according to various degrees of saturation and dry density. A regression model to predict the specific heat capacity of the compacted bentonite buffer was suggested and fitted using 33 sets of data obtained by the dual probe method.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.4 no.1
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• pp.87-93
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• 2006

Inventories, and characteristics such as dimension, fuel rod array, weight, $^{235}U$ enrichment, and discharge burnup of spent nuclear fuel (SNF) generated from existing and planed nuclear power plants based on National 2nd Basic Plan for Electric Power Demand and Supply were investigated and projected to support geological disposal system design. The historical and projected inventory by the end 2057 is expected to be 20,500 and 14,800MTU for PWR and CANDU spent nuclear fuel, respectively. The quantity of SNF with initial $^{235}U$ enrichment of 4.5 wt.% and below was shown to be 96.5% in total. Average burnup of SNF revealed $\sim36$ GWD/MTU and $\sim40$ GWD/MTU for the period of 1994-1999 and 2000-2003, respectively. It is expected that the average burnup of SNF will be $\sim45$ GWD/MTU at the end of 2000's. From the comprehensive study, it was concluded that the imaginary SNF with $16\times16$ Korean Standard Fuel Assembly, cross section of $21.4cm\times21.4cm$, length of 453cm, mass of 672 kg, initial $^{235}U$ enrichment of 4.5 wt.%, discharge burnup of 55 GWD/MTU could cover almost all SNFs to be produced by 2057.

• Journal of the Mineralogical Society of Korea
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• v.26 no.2
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• pp.119-127
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• 2013

Borosilicate glass dissolution is an important chemical process that impacts the glass durability as nuclear waste form that may be used for high-level radioactive waste disposal. Experiments reported that the glass dissolution rates are strongly dependent on the bulk composition. Because some relationship exists between glass composition and molecular-structure distribution (e.g., non-bridging oxygen content of $SiO_4$ unit and averaged coordination number of B), the composition-dependent dissolution rates are attributed to the bulk structural changes corresponding to the compositional variation. We examined Na borosilicate glass structures by performing classical molecular dynamics (MD) simulations for four different chemical compositions ($xNa_2O{\cdot}B_2O_3{\cdot}ySiO_2$). Our MD simulations demonstrate that glass surfaces have significantly different chemical compositions and structures from the bulk glasses. Because glass surfaces forming an interface with solution are most likely the first dissolution-reaction occurring areas, the current MD result simply that composition-dependent glass dissolution behaviors should be understood by surface structural change upon the chemical composition change.