• Title/Summary/Keyword: 고온 수전해

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Basic Studies for the Breeding of High Protein Rice IV. Effect of Short-day and High-temperature Treatment on the Amylose and Crude Protein Content of Rice (수도 고단백계통 육성을 위한 기초적연구 IV. 단일 및 고온처리가 쌀의 Amylose 및 조단백질 함량에 미치는 영향)

  • Mun-Hue Heu;Huhn-Pal Moon
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.15
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    • pp.129-133
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    • 1974
  • In order to obtain the fundamental informations on the protein and amylose content in rice grain, 4 varieties were subjected to the 4 different shortday treatments in 2 kinds temperature. Results can be summarized as follows; 1). By warmer temperature amylose content in the rice dropped by 2 to 3%, but no significant changes in protein content. 2). Short-day treatment caused decreases in amylose content by 2 to 5% and increases in protein content by 2 to 6%. 3). Interactions among varieties, temperature and shortday was significant for both the amylose content and protein content.

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Current Collector Effects on High Temperature Electrolysis by NI-YSZ Cermet Supported Solid Oxide Cells (집전체에 따른 NI-YSZ Cermet 기반의 가역적 고체산화물 연료전지를 이용한 고온 수증기 전기분해 특성)

  • Shin, Eui-Chol;Ahn, Pyung-An;Seo, Hyun-Ho;Lee, Jong-Sook;Yu, Ji-Haeng;Woo, Sang-Kuk
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.6
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    • pp.533-539
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    • 2010
  • Ni-YSZ supported button cells were prepared by spray-coating YSZ and screen-printing YSZ-LSM powder as an electrolyte and oxygen electrode on Ni-YSZ cermet disks. In order to identify the polarization loss mechanism in high temperature electrolysis current-voltage characteristics coupled with electrochemical impedance spectroscopy were investigated as a function of temperature, current load, and the humidity. The effects of the different current collectors of platinum and silver for oxygen electrodes were compared. With Ag current collector two polarization losses were distinguished. The high frequency component was attributed to the Ni-YSZ cermet which was less susceptible to temperature variation but increasing in loss with humidity. The lower frequency component was attributed to the LSM electrode. Platinum current collector led to a much lower polarization loss.

Microstructural Characteristics of Ni/YSZ Cermet for High Temperature Electrolysis by Mechanical Alloying (기계적 합금화법으로 제조된 고온 수전해용 Ni/YSZ 전극의 미세구조 특성)

  • Park Keun-Man;Chae Ui-Seok;Hong Hyun Seon;Choo Soo-Tae
    • Korean Journal of Materials Research
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    • v.14 no.10
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    • pp.743-748
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    • 2004
  • Modified Ni/YSZ cermets for high temperature electrolysis were synthesized by the direct ball milling of Ni and YSZ powder. The ball milling was carried out in dry process and in ethanol with varying milling time. While the dry-milling decreased the average size from 65 to $80{\mu}m$, the wet-milling decreased the average size down to $10{\mu}m$. In addition, very fine particles less than $0.1{\mu}m$ were observed in the wet-milling condition. The subsequent process of cold-pressing and sintering at $900^{\circ}C$ for 2 h did not affect the particle size of dry-milled powder. The electrical conductivity of the dry-milled Ni/YSZ cermet showed the value of $5{\times}10^{2}\;S/cm$ and this value was increased to $1.4{\times}10^{4}\;S/cm$ after the sintering at $900^{\circ}C$ for 2 h.

Comparison of Microstructure and Electrical Conductivity of Ni/YSZ and Cu/YSZ Cathode for High Temperature Electrolysis (고온수전해용 Ni/YSZ와 Cu/YSZ 환원극의 미세구조 및 전기전도도 비교)

  • Kim, Jong-Min;Shin, Seock-Jae;Woo, Sang-Kook;Kang, Kae-Myung;Hong, Hyun-Seon
    • Korean Journal of Materials Research
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    • v.18 no.7
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    • pp.384-388
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    • 2008
  • Hydrogen production via high high-temperature steam electrolysis consumes less electrical energy than compared to conventional low low-temperature water electrolysis, mainly due to the improved thermodynamics and kinetics at elevated temperaturetemperatures. The elementalElemental powders of Cu, Ni, and YSZ are were used to synthesize high high-temperature electrolysis cathodecathodes, of Ni/YSZ and Cu/YSZ composites, by mechanical alloying. The metallic particles of the composites were uniformly covered with finer YSZ particles. Sub-micron sized pores are were homogeneously dispersed in the Ni/YSZ and Cu/YSZ composites. In this study, The cathode materials were synthesized and their Characterizations properties were evaluated in this study: It was found that the better electric conductivity of the Cu/YSZ composite was measured improved compared tothan that of the Ni/YSZ composite. Slight A slight increase in the resistance can be produced for in a Cu/YSZ cathode by oxidation, but it this is compensated offset for by a favorable thermal expansion coefficient. Therefore, Cu/YSZ cermet can be adequately used as a suitable cathode material of in high high-temperature electrolysis.

Effect of Seeding Seasons of Rice Varieties on the Occurence of Sheath Blight (수도품종(水稻品種)의 파종기(播種期) 이동(移動)이 문고병(紋枯病) 발생(發生) 소장(消長)에 미치는 영향(影響))

  • Yu, Seung-Hun;Park, Jong-Seong
    • Korean Journal of Agricultural Science
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    • v.3 no.1
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    • pp.23-30
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    • 1976
  • This study was done to find out the effect of seeding seasons of rice varieties on the occurence of sheath blight caused by Corticium sasakii. The results obtained are summarized as follows; 1. The percentage of infected stems and susceptibilities to sheath blight wered ecreased as the transplanting dates were delayed. 2. The susceptibilities to sheath blight of early maturing varieties were high, medium maturing varieties were intermediate and late maturing varieties were least. 3. The percentages of infected stems of Indica X Japonica varieties checked on 28th July were lower than those of Japonica varieties, but the susceptibilities were not significant between them. 4. At all varieties, highly significant correlation was recognized between the susceptibilities and the heading dates. Also relatively high correlation was appeared between the susceptibilities and the accumulated temperatures from 10 days before heading date to 30 days after it. This indicates that the susceptibility was much influenced by high temperature of the latter part of the rice plants growth.

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A CFD Analysis on Heat Transfer of High Temperature Steam through Interface with Superheater and SOEC for Hydrogen Production (SOEC에 과열기의 고온 스팀을 공급하는 Interface의 열전달에 관한 전산해석)

  • BYUN, HYUN SEUNG;HAN, DANBEE;PARK, SEONGRYONG;CHO, CHONGPYO;BAEK, YOUNGSOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.2
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    • pp.169-176
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    • 2020
  • There is a growing interest in hydrogen energy utilization since an alternative energy development has been demanded due to the depletion of fossil fuels. Hydrogen is produced by the reforming reaction of natural gas and biogas, and the electrolysis of water. An solid oxide electrolyte cell (SOEC) is reversible system that generates hydrogen by electrolyzing the superheated steam or producing the electricity from a fuel cell by hydrogen. If the water can be converted into steam by waste heat from other processes it is more efficient for high-temperature electrolysis to convert steam directly. The reasons are based upon the more favorable thermodynamic and electrochemical kinetic conditions for the reaction. In the present study, steam at over 180℃ and 3.4 bars generated from a boiler were converted into superheated steam at over 700℃ and 3 bars using a cylindrical steam superheater as well as the waste heat of the exhaust gas at 900℃ from a solid refuse fuel combustor. Superheated steam at over 700℃ was then supplied to a high-temperature SOEC to increase the hydrogen production efficiency of water electrolysis. Computational fluid dynamics (CFD) analysis was conducted on the effects of the number of 90° elbow connector for piping, insulation types and insulation layers of pipe on the exit temperature using a commercial Fluent simulator. For two pre-heater injection method of steam inlet and ceramic wool insulation of 100 mm thickness, the highest inlet temperature of SOEC was 744℃ at 5.9 bar.

Effect of shading and air temperature on the productivity of Jinheung and IR667 rice (진흥(振興)과 IR667의 생산력에 대(對)한 차광(遮光) 및 기온(氣溫)의 영향(影響))

  • Park, Hoon;Kwon, Hang Gwang
    • Korean Journal of Soil Science and Fertilizer
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    • v.8 no.4
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    • pp.183-188
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    • 1975
  • Effects of air temperature and 50% shading for 20 days at each growth stages (from 33days before heading, from heading and from 20days after heading) on the productivity of Tongil (IR667-Suweon 214) and Jinheung rice (Oriza sativa.) were as follows. 1. Shading decreased yield by 48, 98 and 18% for Tongil and 73.71 and 12% for Jinheung during ear formation, heading and milky stage, respectively. 2. Shading most severely affected filled-grain ratio in both varieties except shading during milky stage of Jinheung that more affected grain weight. 3. Optimum mean air temperature for maximum crop growth rate appears to be $25^{\circ}C$ and clitical temperature $22^{\circ}C$ for Tongil but these for Jinheung seem to be lower. Solar radiation greater than $300cal/cm^2$ day appears to be enough. 4. Maximum crop growth rate of Tongil always advanced that of Jinheung. 5. Tropical Tongil variety appeared to be more tolerant to high temperature and low solar radiation before heading than temperate Jinheung. Thus Tongil will be more productively adapted to the high temperature-low solar radiation period in rice season which mostly overlaps with ear formation stage.

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The Effect of Phosphorus, Potassium and Calcium Application on Root Activity and Grain Yield of Paddy Rice on Different Soil Conditions (토양 조건별 인산, 가리 및 석회 시용이 수도의 근활력 및 수량에 미치는 영향)

  • Si-Yung Ahn
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.22 no.1
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    • pp.110-134
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    • 1977
  • Effects of phosphorus, potassium and calcium applications on root activity and agronomic characters of paddy rice were studied in submerged paddy soil on which starch was applied to accelerate soil reduction and production of toxic substance during 1971~1973. Root activity at heading date was decreased in reduction accelerated soil by starch application. Effect of calcium application on root activity was differed along soil conditions, phosphorus or potassium levels. Single effects of phosphorus or potassium application were not significant on every observed characters. Calcium application when phosphorus or potassium was not used as basal but used as top dressing increased yield and yield components, especially filled grain ratio. Effect of calcium application along soil conditions was differed on agronomic characters, but calcium application with phosphorus or potassium was more effective to increase yield components and grain yield. Sufficient application of phosphorus, potassium and calcium could improve the nutritional situation of rice plant for panicle development and grain maturity in reduction accelerated paddy soil in which poor growing of rice plant after panicle formation is anticipated by the production of toxic substance from soil.

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Study on the Meteological Effects on the Plant Growth and Yield of Rice (기상요인(氣象要因)이 수도(水稻)의 생육(生育) 및 수량(收量)에 미치는 영향(影響))

  • Jo, Jai Seong;Lee, Jong Cheol
    • Korean Journal of Agricultural Science
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    • v.2 no.1
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    • pp.111-123
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    • 1975
  • 6 years data on the plant growth and grain yield of 13 rice varieties were investigated to define the relations between meteological conditions and plant growth of rice including grain yield. The results obtained are summarized as follows; 1. Variation of average temperature by years showed great number at early and middle July, middle August and early November, however smallest figure at late June and late July. And that of sunshine hours by years were least at late June and late July, and largest at middle July. 2. Among rice yield components variation of panicle number per hill by years was biggest and that of 1000 grain weight least. Rate of variation of plant growth and rice yield was different by rice varieties. 3. Direct effects on rice yield was greatest at maturing ratio and next at 1000 grain weight. The effects of yield factor on the rice yield wers different by years. 4. Higher temperature and longer sunshine delayed the miaxmum tillering stage but shortened the days from seeding to heading. 5. A significant negative correlation was recognized between the number of panicles per hill and average temperature of 11 to 40 days after transplanting, and number of grains per panicle was correlated with the average temperature of 11 to 70 days after transplanting. High temperature before heading time showed atime decreased maturing ratio. 6. Accumulated temperature was highly correlated with 1000 grain weight in all season. Highest positive correltaion was recognized between grain yield of rice and average temperature of 61 to 70 days after transplanting but correlations between rice yield and average temperature after heading stage were negative. 7. Highly significant correlations were confirmed between maturing ratio and sunshine hours of 31 to 50 days as well as 61 to 70 days after transplanting, and maturing ratio was highly correlated with accumulated hours of sunshine. Correlation between rice yield and hours of sunshine was significant at 51 to 60 days after transplanting.

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Studies on the Varietal Difference in the Physiology of Ripening in Rice with Special Reference to Raising the Percentage of Ripened Grains (수도 등숙의 품종간차이와 그 향상에 관한 연구)

  • Su-Bong Ahn
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.14
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    • pp.1-40
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    • 1973
  • There is a general tendency to increase nitrogen level in rice production to insure an increased yield. On the other hand, percentage of ripened grains is getting decreased with such an increased fertilizer level. Decreasing of the percentage is one of the important yield limiting factors. Especially the newly developed rice variety, 'Tongil' is characterized by a relatively low percentage of ripened grains as compared with the other leading varieties. Therefore, these studies were aimed to finding out of some measures for the improvement of ripening in rice. The studies had been carried out in the field and in the phytotron during the period of three years from 1970 to 1972 at the Crop Experiment Station in Suwon. The results obtained from the experiments could be summarized as follows: 1. The spikelet of Tongil was longer in length, more narrow in width, thinner in thickness, smaller in the volume of grains and lighter in grain weight than those of Jinheung. The specific gravity of grain was closely correlated with grain weight and the relationship with thickness, width and length was getting smaller in Jinheung. On the other hand, Tongil showed a different pattern from Jinheung. The relationship of the specific gravity with grain weight was the greatest and followed by that with the width, thickness and length, in order. 2. The distribution of grain weight selected by specific gravity was different from one variety to another. Most of grains of Jinheung were distributed over the specific gravity of 1.12 with its peak at 1.18, but many of grains of Tongil were distributed below 1.12 with its peak at 1.16. The brown/rough rice ratio was sharply declined below the specific gravity of 1.06 in Jinheung, but that of Tongil was not declined from the 1.20 to the 0.96. Accordingly, it seemed to be unfair to make the specific gravity criterion for ripened grains at 1.06 in the Tongil variety. 3. The increasing tendency of grain weight after flowering was different depending on varieties. Generally speaking, rice varieties originated from cold area showed a slow grain weight increase while Tongil was rapid except at lower temperature in late ripening stage. 4. In the late-tillered culms or weak culms, the number of spikelets was small and the percentage of ripened grains was low. Tongil produced more late-tillered culms and had a longer flowering duration especially at lower temperature, resulting in a lower percentage of ripened grains. 5. The leaf blade of Tongil was short, broad and errect, having light receiving status for photosynthesis was better. The photosynthetic activity of Tongil per unit leaf area was higher than that of Jinheung at higher temperature, but lower at lower temperature. 6. Tongil was highly resistant to lodging because of short culm length, and thick lower-internodes. Before flowering, Tongil had a relatively higher amount of sugars, phosphate, silicate, calcium, manganese and magnesium. 7. The number of spikelets of Tongil was much more than that of Jinheung. The negative correlation was observed between the number of spikelets and percentage of ripened grains in Jinheung, but no correlation was found in Tongil grown at higher temperature. Therefore, grain yield was increased with increased number of spikelets in Tongil. Anthesis was not occurred below 21$^{\circ}C$ in Tongil, so sterile spikelets were increased at lower temperature during flowering stage. 8. The root distribution of Jinheung was deeper than that of Tongil. The root activity of Tongil evaluated by $\alpha$-naphthylamine oxidation method, was higher than that of Jinheung at higher temperature, but lower at lower temperature. It is seemed to be related with discoloration of leaf blades. 9. Tongil had a better light receiving status for photosynthesis and a better productive structure with balance between photosynthesis and respiration, so it is seemed that tongil has more ideal plant type for getting of a higher grain yield as compared with Jinheung. 10. Solar radiation during the 10 days before to 30 days after flowering seemed enough for ripening in suwon, but the air temperature dropped down below 22$^{\circ}C$ beyond August 25. Therefore, it was believed that air temperature is one of ripening limiting factors in this case. 11. The optimum temperature for ripening in Jinheung was relatively lower than that of Tongil requriing more than $25^{\circ}C$. Air temperature below 21$^{\circ}C$ was one of limiting factors for ripening in Tongil. 12. It seemed that Jinheung has relatively high photosensitivity and moderate thermosensitivity, while Tongil has a low photosensitivity, high thermosensitivity and longer basic vegetative phase. 13. Under a condition of higher nitrogen application at late growing stage, the grain yield of Jinheung was increased with improvement of percentage of ripened grains, while grain yield of Tongil decreased due to decreasing the number of spikelets although photosynthetic activity after flowering was. increased. 14. The grain yield of Jinheung was decreased slightly in the late transplanting culture since its photosynthetic activity was relatively high at lower temperature, but that of Tonil was decreased due to its inactive photosynthetic activity at lower temperature. The highest yield of Tongil was obtained in the early transplanting culture. 15. Tongil was adapted to a higher fertilizer and dense transplanting, and the percentage of ripened grains was improved by shortening of the flowering duration with increased number of seedlings per hill. 16. The percentage of vigorous tillers was increased with a denser transplanting and increasing in number of seedlings per hill. 17. The possibility to improve percentage of ripened grains was shown with phosphate application at lower temperature. The above mentioned results are again summarized below. The Japonica type leading varieties should be flowered before August 20 to insure a satisfactory ripening of grains. Nitrogen applied should not be more than 7.5kg/10a as the basal-dressing and the remained nitrogen should be applied at the later growing stage to increase their photosynthetic activity. The morphological and physiological characteristics of Tongil, a semi-dwarf, Indica $\times$ Japonica hybrid variety, are very different from those of other leading rice varieties, requring changes in seed selection by specific gravity method, in milling and in the cultural practices. Considering the peculiar distribution of grains selected by the method and the brown/rough rice ratio, the specific gravity criterion for seed selection should be changed from the currently employed 1.06 to about 0.96 for Tongil. In milling process, it would be advisable to bear in mind the specific traits of Tongil grain appearance. Tongil is a variety with many weak tillers and under lower temperature condition flowering is delayed. Such characteristics result in inactivation of roots and leaf blades which affects substantially lowering of the percentage of ripened grains due to increased unfertilized spikelets. In addition, Tongil is adapted well to higher nitrogen application. Therefore, it would be recommended to transplant Tongil variety earlier in season under the condition of higer nitrogen, phosphate and silicate. A dense planting-space with three vigorous seedlings per hill should be practiced in this case. In order to manifest fully the capability of Tongil, several aspects such as the varietal improvement, culural practices and milling process should be more intensively considered in the future.he future.

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