• Title/Summary/Keyword: 고온혐기성소화

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Characteristics of Food Waste Leachate Treatment in Thermophilic two Stage Anaerobic Digestion Combined UF Membrane (막결합형 고온 이상 혐기성 소화공정에서 음폐수 처리 특성)

  • Kim, Young-O;Jun, Duk-Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.20 no.3
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    • pp.21-24
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    • 2012
  • In this study, Anaerobic Membrane Bioreactor(AnMBR) treating food waste leachate was operated to investigate treatment efficiency of anaerobic process, operational parameters and production of biogas. AnMBR was operated under the condition of filtration type of inside-out mode. AnMBR was operated under the condition that range of permeate flux was from 15 to 20 LMH and range of transmembrane pressure was from 1 to $3 kgf/cm^2$. It was not good that AnMBR was performed under direct connection between anaerobic reactor and external UF module. so, this connection method changed to indirect connection using buffer tank was placed between anaerobic reactor and UF external module. TCOD and SCOD values were that influent were about 113 g/L, 62 g/L and effluent were 25 g/L, 12 g/L, respectively. also TCOD and SCOD removal efficiency were 77% and 81%, respectively. but after added UF process, COD and SCOD removal efficiency was increased to 93% and 86%, respectively.

Waste Activated Sludge Digestion with Thermophilic Attached Films (친열성(親熱性) 생물막공법(生物膜工法)을 이용(利用)한 폐활성(廢活性) 슬러지의 혐기성(嫌氣性) 소화(消化))

  • Han, Ung Jun;Kabribk, R.M.;Jewell, W.J.
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.5 no.4
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    • pp.31-44
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    • 1985
  • The application of anaerobic attached microbial films in the expanded bed process has recently been examined at high temperatures ($55^{\circ}C$) and with particulate matter. Extrapolation of the kinetics suggested that waste activated sludge (WAS) could be efficiently digested at hydraulic retention times as short as six hours in the expanded bed process. This would represent a 99 percent digester reactor volume reduction and would introduce interesting solids management alternatives if such a high rate process were developed. This paper presents a summary of a 1.5 year study of the feasibility of such a process. Three continuously fed $55^{\circ}C$ laboratory reactor systems were used to define the kinetics and the site of reactions-control completely mixed reactors were compared to the expanded beds (AAFEB) with and without a hydrolysis unit preceding the attached film unit. Well defined laboratory-generated WAS was compared to actual WAS from a domestic sewage treatment facility. Sixty percent of the biodegradable organics were converted in an AAFEB at a 15-hour hydraulic retention time without hydrolysis, whereas greater than 95 perccent of the biodegradable organics were stabilized in a two-stage system consisting of a 3-day HRT hydrolysis reactor followed by a 15-hour HRT AAFEB. The limitations of this high rate process and its potential application are discussed.

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In situ Analysis of Methanogenic Bacteria in the Anaerobic Mesophilic and Thermophilic Sludge Digestion (중온 및 고온 혐기성 소화에서 메탄생성균 군집 분석에 관한 연구)

  • Hwang, Sun-Jin;Jang, Hyun-Sup;Eom, Hyoung-Choon;Jang, Kwang-Un
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.4
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    • pp.515-521
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    • 2004
  • Anaerobic digestion has many advantages over the more conventional aerobic treatment processes such as low levels of excess sludge production, low space (area) requirements, and the production of valuable biogas. The purpose of this study was to evaluate the effect of organic loading rate of anaerobic digestion on thermophilic($55^{\circ}C$) and mesophilic($35^{\circ}C$) conditions. Fluorescent in situ hybridization (FISH) method was also used to study the microbial community in the reactors. The stabilizing time in mesophilic anaerobic reactors was shorter as approximately 20 days than 40 days in the thermophilic anaerobic reactors. The amount of methane production rate in anaerobic reactors was independent of the concentrations of supplied substrates and the amount of methanogens. When the microbial diversity in the mesophilic and thermophilic reactors, which had been treated with acetate-based artificial wastewater, were compared, it was found that methanogenesis was carried out by microbial consortia consisting of bacteria and archaea such as methanogens. To investigate the activity of bacterial and archaeal populations in all anaerobic reactors, the amount of acetate was measured. Archaea were predominant in all reactors. Interestingly, Methanothrix-like methanogens appeared in mesophilic anaerobic reactors with high feed substrate concentrations, whereas it was not observed in thermophilic anaerobic reactors.

Effects of High Molecular Hardwood Lignin on Anaerobic Digestion at Different Temperatures and Sludge Concentrations (혐기성 소화에 미치는 온도와 슬러지의 농도별 고분자 활엽수 리그닌의 영향)

  • Yin, Cheng-Ri;Seo, Dong-Il;Lee, Sung-Taik;Jin, Yin-Shu
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.12
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    • pp.2197-2204
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    • 2000
  • Lignin is a major component of wastewater generated in the chemical processing of wood. Because it is recalcitrant, it inhibits biological treatment of wastewater of pulp manufacturing, especially high concentration of lignin may inhibit the anaerobic digestion. The objective of this study was to evaluate the toxicity of high molecular hardwood lignin (lignosulfonate, MW $\geq$ 20,000) on aceticlastic methanogens in the batch reactors at different temperatures with different sludge concentrations, using anaerobic serum bottles. The hardwood lignin was found to inhibit anaerobic conversion of acetate to methane and carbon dioxide, shown with a long lag-phase before methanogenesis started. The methanogens assumed not to be able to acclimate to the lignin were found to be acclimated slowly in the batch experiments, finally reaching non-toxic levels in which methane production could start. The hardwood lignin was found not to be bacteriocidal but bacteriostatic to aceticlastic methanogens. Hardwood lignin(lignosulfonate) at 1.3, 2.6, and 3.9%(w/w) inhibited the acetateutilizing methanogens of anaerobic digester sludge by 14.5, 17.8, 21.1 days(in noninhibitory condition it took 10 days) to produce the same amount of methane. The inhibitory effect of lignin was examined at temperature ranges of $30^{\circ}C$ to $50^{\circ}C$. When 2.6% of lignin was contained in wastewater, methane production was highest at $30^{\circ}C$ during initial 8 days. At $4^{\circ}C$, methane production rapidly increased after 12 days of digestion, the value became higher than that at $30^{\circ}C$ after 14 days. However, the methane production was completely inhibited during whole digestion period at $50^{\circ}C$. High ratio of lignin concentration to initial anaerobic sludge concentration gave tolerance to the inhibition. In this experiment, high molecular hardwood lignin was not degraded and decolorized.

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Nightsoil Treatment: Temperature Effects on Anaerobic Digestion (분뇨처리(糞尿處理) : 혐기성소화(嫌氣性消化) 온도영향(溫度影響))

  • Choi, Eui So;Lee, Byung Hun;Lee, Chan Ki
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.2 no.3
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    • pp.23-32
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    • 1982
  • This study was conducted to evaluate the temperature effects on the nightsoil, anaerobic digestion, whether it could be operated with a higher organic loading rate at a higher temperature during summer months, or with a lower organic loading rate at a lower temperature during winter months. A laboratory completely mixed digester was continuously operated at 11 different temperatures from $18.5^{\circ}$ to $60^{\circ}C$ with 30 days of HRT. The study results indicated that the best efficiency occurred at a temperature range of $35^{\circ}$ to $40^{\circ}C$, at which BOD and VS removal efficiencies were respectively 71 and 53 percent, and gas production rate was $0.6m^3/kg$ VS fed or $16m^3/m^3$ fed. BOD removal efficiency would be increased to 78 percent if the digester effluent settled for 24 hours. Since the digester efficiency decreased beyond this temperature range, this suggested the digester need not to operate a higher temperature even during the summer months. The laboratory results were in good agreement with those of the existing digester operated at a temperature range of $32^{\circ}$ to $40^{\circ}C$. Application of septage or cow manure to the digester with nights oil at a rate of 1 to 1 did not greatly affect the digester performances. In addition, the digester effluent could be treated aerobically without any dillution water. BOD and SS removal efficiencies were greater than 90 percent in this case.

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The Process Efficiency Evaluation of the Food Supernatant Using A/G (Acid/Gas) Phased Anaerobic Digestion (산/가스 분리 혐기소화공정을 이용한 음식물 탈리액의 처리효율 평가)

  • Bae, Jong-Hun;Park, Noh-Back;Tian, Dong-Jin;Jun, Hang-Bae;Yang, Seok-Jun
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.3
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    • pp.214-222
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    • 2012
  • Several acidogenesis batch tests, and BMP (Biochemical Methane Potential) with food waste leachate was tested at various organic loading rates (OLRs) on the mesophilic ($35^{\circ}C$) and thermophilic ($55^{\circ}C$) conditions. In acidogenesis batch test, VS removal efficiencies were 27.3% and 30.6% at $35^{\circ}C$ and $55^{\circ}C$, respectively. Removal efficiency of VS at $55^{\circ}C$ was higher than that at $35^{\circ}C$. With decrease in VS, SCOD increased as reaction time increased. Solubilization efficiency of VS were 27.4% and 33.4% at each reaction temperature within 4 days acid fermentation. Methane yield were 461 and 413 $mLCH_4/gVS$ at mesophilic and thermophilic BMP test, respectively. SCOD solubilizations in the themophilic acid fermenter showed 8~17% higher than those in the mesophilic fermenter. COD removal efficiency showed higher in the mesophilic acid fermenter at low organic loading rate. While at high organic loading rate, it was higher in the thermophilic acid fermenter. VS removal efficiency was higher at the mesophilic temperature, however, it decreased at OLR higher than 6 kg $COD/m^3{\cdot}day$. On the contrary, VS removal efficiency did not decrease but maintain at thermophilic temperature. The amount of methane gas generated from mesophilic methanogenesis digester was 12.6, 21.6, 27.4 L/day at OLR of 4, 5, 6 $COD/m^3{\cdot}day$, respectively. The amount of methane gas generated from themophilic methanogenesis digester was 14.3, 20.6, 25.2 L/day at each OLR, respectively, which is about 15~20 L/day lower than those generated at mesophilic digester.

Study of Biodegradable Ability of Biodegradable Plastic in Anaerobic Digestion (혐기성소화에 의한 생분해성 플라스틱의 생분해능 검토)

  • Park, Jeong-Soo;Joo, Hung-Soo;Ryu, Jae-Young;Phae, Chae-Gun;Jeon, Young-Seung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.1
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    • pp.109-119
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    • 2002
  • This study is to estimate that food waste bags with biodegradable plastic are really decomposed by microorganism in composting with food waste and to examinate how biodegradable plastic affects composting. 6 kinds of 30%, 4 kinds of 100% and 2 kinds of none biodegradable plastics were used in d1is study. In 30% biodegradable plastics the highest Degradation rare is 6% in meso-condition and 10% in thermal-condition. Srain at auto break decreased to 150% in meso-condition and 120% in thermal-condition. Stress at max load were also reduced to $180kgf/cm^2$ in mesocondition and $200kgf/cm^2$ in thermal-condition. Usually, LLDPE decreased larger than HDPE in physical characreristics but HDPE is higher in degradation rate. 1n stain at auto break and stress ar max load 100% biodegradable plastic declined to 230% and to $380kgf/cm^2$ in meso-condition and to 440% and to $400/cm^2$ in thermal-condition respectively. 100% biodegradable plastics showed higher biodegradation and decomposition then 30%. They appeared clearly through SEM observation. As a result, it was not appropriate to use 30% biodegradable plastics as food waste bag because they were not decomposed perfectly. It is possible to use 100% biodegradable plastic as it but cost is too high. So development of technique is needed.

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Treatment of Garbage Leachate with Two-phase Anaerobic Digestion Coupled with Ultra Filtration (막결합형 2상 혐기성 소화 공정을 이용한 음식물 탈리액 처리)

  • Lee, Eun-Young;Kim, Hyung-Kuk;Giang, Luu Thi Thuy;Bae, Jae-Ho;Bae, Young-Shin;Won, Jong-Choul;Lee, Jae-Hoon;Park, Seung-Kyun;Cho, Yong-Wan
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.11
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    • pp.997-1006
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    • 2009
  • Organic removal efficiency and methane production rate, a feasibility of power generation from biogas, and the optimum conditions for membrane operation were evaluated for the pilot scale (5 tons/day) two-phase anaerobic digestion coupled with ultra filtration (TPADUF) system fed with garbage leachate. The TPADUF system is consisted of a thermophilic acidogenic reactor, a mesophilic methanogenic reactor, and an UF membrane. When garbage leachate with 150 g/L of TCOD was fed to the TPADUF up to organic loading rate (OLR) of 11.1 g COD/L/d, the effluent TCOD was lower than 6 g/L and the average removal efficiencies of TCOD and SCOD were higher than 95%. The methane composition of the gas was 65%, and the methane yield was 39 $m^3/m^3$ garbage leachatefed, 260 $m^3$/tons $COD_{added}$, or 270 $m^3$/tons $COD_{removed}$, even there was some gas leak. The power production per consumed gas was 0.96 kWh/$m^3$ gas or 1.49 kWh/$m^3$ methane. This lower power production efficiency mainly due to the small capacity of gas engine (15 kW class). The membrane was operated at the average flux of 10 L/$m^2$/hr. When the flux decreased, washing with water and chemical (NaOCl) was conducted to restore the flux. In the TPADUF system, optimum pH could be maintained without alkali addition by recycling the membrane concentrate or mixed liquor of the methanogenic digester to the acidogenic reactor. Also, partial production of methane in the acidogenic reactor had a positive effect on lowering the OLR of the methanogenic reactor.

Influence of Food Wastewater Loading Rate on the Reactor Performance and Stability in the Thermophilic Aerobic Process (음폐수 부하량에 따른 고온호기성 공정의 처리 양상)

  • Jang, Hyun Min;Choi, Suk Soon;Ha, Jeong Hyub;Park, Jong Moon
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.279-284
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    • 2013
  • In this study, the feasibility of a single-stage thermophilic aerobic process for the treatment of high-strength food wastewater produced from the recycling process of food wastes was examined to substitute anaerobic digestion process. Also, the removal and stability of thermophilic aerobic process were assessed according to the changes of hydraulic retention times (HRTs) and organic loading rates (OLRs). When the OLR increased from 9.2 to $37.2kgCOD/m^3d$, a pH value in R1 (HRT : 5 d) significantly decreased to 5.0, due to the organic acid accumulation. On the other hand, the pH value in R2 (HRT : 10 d) was stable and R2 showed the high removal of COD, organic acid and lipid, even though the OLR increased from 4.6 to $18.6kgCOD/m^3d$. In R1, the COD loading rates for COD removal was suddenly dropped, as the COD loading rate increased from 18.6 to $28.4kgCOD/m^3d$. In contrast, R2 showed that the COD loading rates for COD removal increased with regard to increment in the loading rates of 3.61, 7.05, 9.43 and $12.2kgCOD/m^3d$, indicative of the high COD removal efficiency. Therefore, the results demonstrated that over 10-d HRT, the high concentration of raw food wastewater was efficiently treated in the single-stage thermophilic aerobic process.

Thermophilic Anaerobic Digestion of Polyhydroxybutyrate with and without Thermo-alkaline Pretreatment (열적-알칼리성 전처리 유무에 따른 폴리하이드록시부티레이트의 고온 혐기성 소화 영향 연구)

  • Jihyeon Lee;Joonyeob Lee
    • Journal of Environmental Science International
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    • v.33 no.2
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    • pp.121-129
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    • 2024
  • The study investigated the effect of thermo-alkaline pretreatment on the solubilization of polyhydroxybutyrate (PHB) and its potential to enhance of thermophilic anaerobic digestion, focusing on biochemical methane potential (BMP) and methane production rate, using two different particle sizes of PHB (1500 ㎛ and 400 ㎛). Thermo-alkaline pretreatment tests were conducted at 90 ℃ for 24 hours with varying NaOH dosages from 0-80% (w/w). BMP tests with untreated PHB exhibited methane production ranging from 150.4~225.4 mL CH4/g COD and 21.5~24.2 mL CH4/g VSS/d, indicating higher methane production for smaller particle sizes of PHB, 400 ㎛. Thermo-alkaline pretreatment tests achieved a 95.3% PHB solubilization efficiency when 400 ㎛ PHB particles were treated with 80% NaOH dosage at 90 ℃ for 24 hours. BMP tests with pretreated PHB showed substantial improvement in thermophilic anaerobic digestion, with an increase of up to 112% in BMP and up to 168% in methane production rate. The results suggest that a combined pretreatment process, including physical (400 ㎛ PHB particles) and thermo-alkaline (90 ℃, 40-80% NaOH dosage, and 24 hours reaction time), is required for high-rate thermophilic anaerobic digestion of PHB with enhanced methane production.