• Title/Summary/Keyword: 고온조건

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수소 제조용 치밀질 세라믹 멤브레인 제조기술 개발

  • Hwang, Gwang-Taek
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.11a
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    • pp.51-59
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    • 2005
  • 수소 분리막의 적용 분야는 석탄가스, 천연가스, 메탄가스 혼합기체이며, 고온/고압 및 수소농도가 낮은 혼합기체에서 고순도의 수소를 제조하는 곳이다. 특히 치밀질 세라믹 멤브레인은 고온에서 가스화한 석탄가스나 차세대의 쓰레기 처리 기술인 가스화 용융처리에서 생긴 고온가스로부터 고순도의 수소를 분리할 수 있다. 분리한 수소는 고온을 유지하기 때문에 연료전지 발전에 최적이다. 종래의 연료전지는 발전을 위해서 수소의 가열이 필요했으나 이것이 불필요하게 되어 발전 전체의 효율이 향상된다. 석유화학 산업에서 발생하는 혼합기체에서 수소를 분리하여 사용하고 남은 기체는 연료로 재사용할 수 있다. 분리막의 재질로는 고분자계가 개발되고 있으며 고분자 지지체에 백금이나 로듐과 같은 촉매를 코팅하는 방법이다. 이는 기공의 제어가 용이하고 대량생산이 가능한 장점이 있지만 고온에서 사용이 불가능하고 입자상 물질에 의해 분리막의 손상이 문제가 되고 있다. 이에 비해 치밀질 세라믹 멤브레인은 세라믹의 특성에 의해 고온 및 고압에서도 적용이 가능하며, 실온이나 저압의 조건에서도 적용이 가능한 특징을 가진다. $900^{\circ}C$의 고온에서 적용시 세라믹 멤브레인에는 특성열화가 없어 수명이 긴 장점을 가지게 된다. 수소가 포함되어 있는 기체에서 수소 만을 분리하는 방법은 흡착이나 분리막을 이용하는 방법이 일반적이며 흡착에 의한 방법은 일부 실용화가 진행되고 있다. 고효율의 수소를 분리하는 방법으로 분리막을 이용하는 방법이 있다. 현재 치밀질 수소 분리막의 연구는 외국(미국, 일본 등)에서도 초기 연구 단계이다. 국내에서도 이런 연구가 선행되어 외국과의 기술 격차를 줄이고 에너지 자원에 대한 확보가 필요하기 때문에 이 연구가 수행되었다. 치밀질 멤브레인의 소재로는 proton 및 전자전도가 가능한 소재로서 Ba-Ce-Y계를 기본조성으로 하여 내구성과 전기전도도를 향상시키기 위해 Ca, La, In, Yb를 치환하였다. 제조한 재료의 물리화학적 특성을 평가하였고, 수소여과 장치를 이용하여 여과 효율을 평가하였다.

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Experimental Study on the Dependence of Variation in Performance of a High-Temperature Generator on Its Operating Conditions (운전조건 변화가 고온재생기의 성능에 미치는 영향에 관한 실험적 연구)

  • Bae, Kyungjin;Kwak, Myoungseok;Cho, Honghyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.5
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    • pp.389-397
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    • 2014
  • An absorption chiller-heater using only a natural refrigerant hardly causes any environmental pollution. In an absorption chiller-heater, the performance of its high-temperature generator, which uses exhaust gases, is essential to achieving superior system performance. To investigate the performance of such a high-temperature generator, a laboratory-scale high-temperature generator working with exhaust gases was designed and tested. Changes in the performance of the high-temperature generator as a function of inlet conditions of the absorbing solution, such as air inlet temperature and mass flow, were investigated. It was observed that when the air mass flow rate ratio was increased from 80% to 120%, the heat capacity was increased by 30%, 33%, 34%, and 37%, respectively. Additionally, when the air inlet temperature was elevated from $170^{\circ}C$ to $210^{\circ}C$ for absorption solution concentrations of 56%, 55%, 545, and 53%, the heat capacity increased by 140%, 160%, 220%, and 224%, respectively.

Changes in Physicochemical Properties of Rice Starch from Rice Stored at Different Conditions (저장조건에 따른 쌀전분의 이화학적 성질 변화)

  • Ko, Yong-Duck;Choi, Ok-Ja;Park, Seok-Kyu;Ha, Hee-Suk;Sung, Nack-Kie
    • Korean Journal of Food Science and Technology
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    • v.27 no.3
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    • pp.306-312
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    • 1995
  • In order to know properties in rice starch during storage of rice, rice starch from stored rice(stored at $5^{\circ}C$, R.H. 65% and $30^{\circ}C$, R.H. 85%, for 16 weeks) used in this experiment. Water binding capacity of rice starch increased for 8 weeks, and then it decreased. As the storage period took longer, swelling power and solubility, optical transmittance, blue value, total amylose content and soluble amylose content decreased. For the same periods, changes in rice starch from stored rice$(30^{\circ}C$, R.H. 85%) were made more than those in rice starch at $5^{\circ}C$, R.H. 65%. The granule shape of rice starch, irrespective of storage periods and conditions, didn't make a significant difference. The relative crystallinity of the rice starch by X-ray diffraction didn't distinctly changed till the second week. But, at the fourth week, that by X-ray diffraction significantly decreased, and then slightly decreased. As the storage period took longer, gelatinization temperature, melting temperature and melting enthalpy measured by DSC got higher, but gelatinization enthalpy got lower. For the same storage period, gelatinization temperature, melting temperature, gelatinization enthalpy and melting enthalpy of rice starch stored at $30^{\circ}C$, R.H. 85% made changes more than those of rice starch stored at $5^{\circ}C$, R.H. 65% did.

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Effect of Curing Conditions on the Strength of Fly-Ash Based Geopolymer (양생조건이 플라이애쉬 기반 지오폴리머 강도에 미치는 영향)

  • Cho, Young-Keun;Moon, Gyu-Don;La, Jung-Min;Jung, Sang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.26 no.4
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    • pp.449-456
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    • 2014
  • Material properties of geopolymer, whose the reaction is very complicated, have been influenced by chemical compositions and particle size distributions of fly ash, concentrations and types of alkali-activators and curing conditions such as temperatures and time. In this research, experiments with several variables such as curing temperatures, preset prior to the high temperature curing and high temperatures have been conducted in order to evaluate to investigate effects on the compressive strengths of geopolymer caused by curing condition. Experiment results were evaluated with compressive strengths and micro-structures such as SEM and MIP of geopolymer pastes. As a result, as higher curing temperature or longer preset time were applied to the pastes, higher compressive strengths were observed. However, compressive strengths of geopolymer pastes declined due to increases in macropores (>50 nm) under high temperatures elapsed after 24 hours. In this sense, it can be considered that strengths and microstructures of geopolymers depends on curing temperature and time.

An Experimental Study of Evaporative Heat Exchangers with Mini-channels (물의 증발잠열을 이용하는 미니채널 열교환기의 실험적 연구)

  • Lee, Hyung-Ju;Yoo, Young-June;Min, Seong-Ki
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.245-253
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    • 2010
  • The present study shows some results of developing evaporative heat exchangers with mini-channels. Heat exchangers with three different water paths were manufactured and tested to compare performances of cooling and pressure drop. Among the three types of heat exchangers, Type 2 with full-etching was proved to be the best in the cooling performances for considered operating conditions, and thus it is recommended to adopt Type 2 for its simplicity of production and outstanding performance. However, Type 1 was shown to be better when it is operated at a high air inlet temperature condition. The developed evaporative heat exchanger will be installed in Environmental Control Systems(ECSs) for aerial vehicles, and it can be used effectively in case an ECS is not only limited in its weight and volume but also required to absorb heats without supplying water (or a coolant) for a certain period of time.

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Effect of Filled Hole on Strength Behavior of CFRP Composites at Cold Temperature Dry and Elevated Temperature Wet (저온건조($-55^{\circ}C$) 및 고온다습 조건($108.3^{\circ}C$)의 기계적 체결 홀이 탄소섬유강화 복합재의 강도 특성에 미치는 영향 연구)

  • Kim, Hyo-Jin
    • Composites Research
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    • v.22 no.3
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    • pp.82-88
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    • 2009
  • The effect of open and filled holes on the strength behavior of carbon fiber reinforced polymeric (CFRP) composites was investigated. The strength was measured at room temperature dry, cold temperature dry, $-55^{\circ}C$, and elevated temperature wet, $108.3^{\circ}C$ on several different laminate configurations. Based on the experimental data presented, it is shown that the filled hole tensile strength is larger than that of open hole by reducing damage around the hole due to the constraint imposed by the fastener. The tensile strength at cold temperature dry, $-55^{\circ}C$ is increased with the brittleness by the thermal expansion coefficient of fiber and matrix. The compressive strength at elevated temperature wet, $108.3^{\circ}C$ is decreased by the cause of interfacial deterioration between fiber and matrix with moisture absorption.

A Study on the Establishment of Environmental Test Procedures for the UAV (무인항공기 운용 환경조건 시험절차 수립)

  • Yun, Sanguk
    • Journal of Aerospace System Engineering
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    • v.13 no.3
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    • pp.87-94
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    • 2019
  • In this paper, we test procedures to demonstrate operating environmental conditions that can be exposed to UAV during its life-cycle are proposed. They are set up to be used in a large-sized climate chamber, one of the facilities of the Agency for Defense Development corresponding with the system requirements. The test steps and profile details were more specifically suggested for rainfall, humidity, and temperature (low-temperature storage and operation, high-temperature operation and solar radiation), and MIL-STD-810G w/Change-1-based.