• Magazine of the Korea Concrete Institute
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• v.5 no.2
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• pp.121-128
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• 1993

나프탈렌 또는 나프톨을 황산화하고 포름알데히드와 축합 반응시켜 나프탈렌 축합물 및 나프톨 축합물을 합성하였다. 또한, 나프탈렌과 나프톨을 모두 함유하는 공축합물도 합성하였다. 이들 축합물의 확인은 핵자기공명스텍트럼, 적외분광스펙트럼, 자외분광스펙트럼으로 행하였다. 한편 이들 축합물들의 시멘트에 대한 분산성을 예측하기 위하여 시멘트 표면에의 흡착실험을 행하였다. 그 결과 수산기를 함유하는 나프톨 축합물(TSC)>나프탈렌-나프톨공축합물(NSS)의 순으로 시멘트에 대한 흡착율이 증가했다. 위의 결과들로부터 주쇄(main chain)에 나프톨을 함유하는 합성축합물(TCS, NT5)은 시멘트분산제로서의 가능성이 시사되었다.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.200-203
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• 2004

In this study, it is examined the properties of flow and early strength of concrete according to superplasticizer. For this experiment, it is analyzed that the flow and strength properties according to the mixture factors, compared with naphthalene superplasticizer(normal & delay type) focused on polycarboxylate superplasticizer. (1) The slump loss of concrete used polycarboxylate superplasticizer showed $4\~8cm$, it is judged that slump loss according to the time lapse can be minimized. (2) The performance of polycarboxylate superplasticizer is about $70\%$ level of the normal naphthalene type, it is superior to the delay type, but the performance showed so lowly. The 28days, early strength didn't differ according to the kind of superplasticizer.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.11a
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• pp.265-268
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• 2003

This study discusses the fundamental properties of high performance concrete and autogenous drying shrinkage with the kinds and the adding amount of superplasticizer. According to results, drying shrinkage hardly shows differences by the kinds of superplasticizer, and is reduced with an increase of the adding ratio. Autogenous shrinkage is reduced in order of HP>HN>HM, but does not make a big difference. As the adding amount of superplasticizer increases, autogenous shrinkage is reduced due to a decrease of cement content which influences on autogenous shrinkage seriously.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.671-674
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• 2005

In this study, it is examined the properties of early strength of concrete mixed with polycarboxylate superplasticizer. For this experiment, it is analyzed that the slump and strength properties according to the mixture factors, compared with cements and superplasticizers of each company and curing temperature($15,\;20^{\circ}C$). (1) The slump loss of concrete used polycarboxylate superplasticizer(rapid strength type) showed $0.5\~1.5cm$, it is judged that slump loss according to the time lapse can be minimized. (2) The performance of polycarboxylate superplasticizer kept up consistency and accelerated strength development. it is possible to reveal 12MPa within $18\~20$hours at $20^{\circ}C$ curing, but impossible within 24hours at $15^{\circ}C$. (3) It is necessary to studies about rapid strength development in the low temperature.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.10a
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• pp.321-326
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• 1997

Recently, High Range Water Reducing Admixture be used increasingly in other to improve the demanded properties (fluidity, strength, durability etc.) and workability in concrete. These kinds of agent govern quality characteristics (air content, setting time, slump, bleeding etc) by the difference of its dispersing mechanism and performance in manufacture of flowed concrete. Accordingly, in this study, for the purpose of high quality construction in site, the comparative experiment of dispersing ability due to commercially available three types of agent were carried out in paste, mortar and concrete using tow types of cement (I, V). In conclusion, the bleeding reduction by the dispersing ability of agents was verified in the fresh properties of flowed concrete with sea water resistance.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.277-280
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• 2004

Recently, as structure is more higher and bigger, we need high strength and high performance concrete. Therefore it is necessary superplasticizer for high strength and high performance concrete. In this study, it is examined the properties of flow, air content and strength of concrete with polycarboxylate superplasticizer in comparison with existing superplasticizer. First, The slump loss of concrete used polycarboxylate superplasticizer showed 2cm until 120 minutes. Second, The air content loss of concrete used polycarboxylate superplasticizer showed $1\%$ until 120 minutes. Third, It is possible to manufacture $1000kgf/cm^2$ strength concrete using polycarboxylate superplasticizer with $806kg/m^3$ cement content, $18\%$ water-binder ratio, $15\%$ silica fume, $10\%$ fly-ash content.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.05a
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• pp.55-56
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• 2011

This paper is to compare and analyze the properties of ultra high strength concrete depending on the use of SF aiming for applicability of superplasticizer containing CASB as a functional agent for strength improvement. As experimental results, in case superplasticizer containing CASB is used, regardless of W/B, settiing time was more accelerated than N, and both compressive strength and tensile strength showed an increase in their strength minutely.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.11a
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• pp.81-82
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• 2020

Cement paste is the basic material constituting concrete and the most basic data of workability. This study quantitatively evaluated the measured data using a ring flow and a rotary viscometer to estimate the flow of cement paste, and also evaluated the flow and rheology over time. For this, the current work has studied admixtures that affect the fluidity of cement paste. As a result of the experiment, since fluidity and plastic viscosity are inversely proportional to each other, more experimental studies are needed to obtain high fluidity and high viscosity at the same time.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.14 no.5
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• pp.1069-1080
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• 1994

For complying with the demand of developing high strength concrete, the high strength concrete with higher cement contents and lower water-cement ratio using high range water reducing admixture has been manufactured. In this study, for the purpose of improving the strength of concrete, concrete with silica fume and gypsum was produced so that it was acquired to high compressive strength of $1,058kg/cm^2$, $1,170kg/cm^2$ at age 28 and 91 days, respectively. But neither tensile strength nor modulus of elasticity were highly improved although the compressive strength of the concrete increased. And it was concluded that a higher slump loss of fresh high strength concrete and interior temperature increment of concrete in according to elapsed time than convential concrete should be solved.

• Journal of the Korea Concrete Institute
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• v.15 no.2
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• pp.254-262
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• 2003

In this study, the results of applying cold weather concreting mixed with Accelerator for Freeze Protection(AFP) to full scale structures are presented. Since the determination of W/C and amount of AFP significantly have an effect on strength gain and protection of frost damage in early, a full investigation is needed to determine these values at stage of nux design. The flowability of fresh cold weather concreting with AFP was similar to the same W/C. Lower loss of workability and initial slump flow of concrete using superplasticizer of polycarboxylic ester than that of melamine sulphonate showed that polycarboxylic ester was more effective on elapsed time. Temperature histories of specimens located in insulation boxes at the site was similar to that of structures. Thus, it is cleared that simple adiabatic curing method is effective for evaluating in-place concrete strength than specimens cured by sealing method. The investigation results of development of compressive strength of cold weather concreting included AFP with curing methods by logistic curves indicated that AFP can be effective to gain strength at lower temperature than normal curing temperature. In field testing, vinyl sheets were placed over the concrete sections and AFP enabled concrete to gain $5N/{mm}^2$ to protect frost damage in early ages and specified compressive strength of concrete at 28 days under average temperature of $-2^{\circ}C$ (lowest temperature was $-12^{\circ}C$) during site application.